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51.
The title compound is the first stable structural analogue for the monobridged isomer of a heavier group 14 alkene analogue. 相似文献
52.
Hadzibabic Z Gupta S Stan CA Schunck CH Zwierlein MW Dieckmann K Ketterle W 《Physical review letters》2003,91(16):160401
We have produced a quantum degenerate 6Li Fermi gas with up to 7 x 10(7) atoms, an improvement by a factor of 50 over all previous experiments with degenerate Fermi gases. This was achieved by sympathetic cooling with bosonic 23Na in the F=2, upper hyperfine ground state. We have also achieved Bose-Einstein condensation of F=2 sodium atoms by direct evaporation. 相似文献
53.
R. Stanoeva V. Bradnova S. Vokál P. I. Zarubin I. G. Zarubina N. A. Kachalova A. D. Kovalenko A. I. Malakhov G. I. Orlova N. G. Peresadko P. A. Rukoyatkin V. V. Rusakova E. Stan M. Haiduc S. P. Kharlamov I. Tsakov T. V. Shchedrina 《Physics of Atomic Nuclei》2007,70(7):1216-1221
The results obtained by studying the charge topology of fragments produced in the peripheral dissociation of relativistic 8B nuclei in emulsion are presented. Fifty-five events of the peripheral dissociation of a 8B nucleus in events where there was no production of target-nucleus fragments and mesons (“white stars”) were selected. A leading contribution of the 8B → 7Be + p mode, which has the lowest energy threshold, was revealed on the basis of these events. Information about the branching ratios for dissociation modes characterized by a higher multiplicity was obtained. The dissociation of the 7Be core in 8B bears resemblance to the dissociation of a free 7Be nucleus. The transverse-momentum distributions of fragments originating from the 8B → 7Be + p dissociation mode were obtained. For these distributions, a small mean value of 〈P*T〉 = 52 ± 5 MeV/c in the c.m. frame suggests a low binding energy of the outer proton in the 8B nucleus. An indication of a strong azimuthal correlation of the fragments 7Be and p was found. 相似文献
54.
Kuijpers BH Groothuys S Keereweer AB Quaedflieg PJ Blaauw RH van Delft FL Rutjes FP 《Organic letters》2004,6(18):3123-3126
[structure: see text] An expedient, high-yielding synthesis of two types of triazole-linked glycopeptides is described. These novel and stable glycopeptide mimics were prepared via Cu(I)-catalyzed [3 + 2] cycloaddition of either azide-functionalized glycosides and acetylenic amino acids or acetylenic glycosides and azide-containing amino acids. 相似文献
55.
Denisa Dumitrescu Sergiu Shova Constantin Draghici Marcel Mirel Popa Florea Dumitrascu 《Molecules (Basel, Switzerland)》2021,26(12)
3-Arylsydnones bearing fluorine and bromine atoms on the benzene ring were synthesized from N-nitroso-2-fluorophenylglycines and characterized by NMR spectroscopy. These were employed further in synthesis of the corresponding 1-(2-fluorophenyl)pyrazoles by 1,3-dipolar cycloaddition reaction with dimethyl acetylenedicarboxylate (DMAD) as activated dipolarophile. The sydnones as reaction intermediates were characterized by single crystal X-ray diffraction analysis showing interesting features such as halogen bonding as an important interaction in modeling the crystal structure. 相似文献
56.
Costes JP Shova S Wernsdorfer W 《Dalton transactions (Cambridge, England : 2003)》2008,(14):1843-1849
A trianionic ligand H3L (2-hydroxy-N-(2-[[(2-hydroxyphenyl)methylene]amino]-2-methylpropyl)benzamide) with an inner N2O2 coordination site and an oxygen atom coming from an amide function not involved in this site yields monoanionic LCu- complexes that react with Ln(hfa)3 x 2H2O (hfa = hexafluoroacetylacetonato ligand) to give dinuclear Cu-Ln complexes that self-assemble into tetranuclear species, as demonstrated by the structural determination of the [LCuDy(hfa)2(dmf)2]2 complex. High-spin species are then isolated for two ferromagnetic interactions are active in the [Cu-Gd]2 entities, through the double phenoxo bridge (J = 3.2 cm(-1)) and through the single amide bridge (j = 0.54 cm(-1)). These interactions are still present in the [Cu-Tb]2 and [Cu-Dy]2 complexes which behave as single molecule magnets (SMMs), due to the introduction of anisotropic Ln ions in place of Gd ions. 相似文献
57.
In this paper we consider the propagation of Rayleigh surface waves in an exponentially graded half-space made of an isotropic Kelvin-Voigt viscoelastic material. Here we take into account the effect of the viscoelastic dissipation energy upon the corresponding wave solutions. As a consequence we introduce the damped in time wave solutions and then we treat the Rayleigh surface wave problem in terms of such solutions. The explicit form of the secular equation is obtained in terms of the wave speed and the viscoelastic inhomogeneous profile. Furthermore, we use numerical methods and computations to solve the secular equation for some special homogeneous materials. The results sustain the idea, existent in literature on the argument, that there is possible to have more than one surface wave for the Rayleigh wave problem. 相似文献
58.
Sergiu Muncaci Carlos Mattea Siegfried Stapf Ioan Ardelean 《Magnetic resonance in chemistry : MRC》2013,51(2):123-128
Frequency‐dependent NMR relaxation studies have been carried out on water (polar) and cyclohexane (nonpolar) molecules confined inside porous ceramics containing variable amounts of iron oxide (III). The porous ceramics were prepared by compression of powders mixed with iron oxide followed by thermal treatment. The pore size distribution was estimated using a technique based on diffusion in internal fields that exposed a narrow distribution of macropore sizes with an average pore dimension independent of iron oxide content. The relaxation dispersion curves were obtained at room temperature using a fast field cycling NMR instrument. They display an increase of the relaxation rate proportional to the iron oxide concentration. This behavior is more prominent at low Larmor frequencies and is independent of the polar character of the confined molecules. The results reported here can be fitted well with a relaxation model considering exchange between molecules in the close vicinity of the paramagnetic centers located in the surface and bulk‐like molecules inside the pores. This model allows the extraction of the transverse diffusional correlation time that can be related to the polar character of the confined molecules. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
59.
60.
Corneliu Balan 《Continuum Mechanics and Thermodynamics》2001,13(6):399-414
Received March 25, 2001 / Published online November 15, 2001 相似文献