全文获取类型
收费全文 | 108篇 |
免费 | 2篇 |
专业分类
化学 | 33篇 |
晶体学 | 8篇 |
力学 | 1篇 |
数学 | 4篇 |
物理学 | 64篇 |
出版年
2023年 | 1篇 |
2021年 | 1篇 |
2019年 | 1篇 |
2018年 | 1篇 |
2016年 | 3篇 |
2014年 | 1篇 |
2013年 | 5篇 |
2012年 | 2篇 |
2011年 | 4篇 |
2010年 | 4篇 |
2009年 | 5篇 |
2008年 | 8篇 |
2007年 | 7篇 |
2006年 | 5篇 |
2005年 | 8篇 |
2004年 | 8篇 |
2003年 | 6篇 |
2002年 | 5篇 |
2001年 | 7篇 |
2000年 | 3篇 |
1999年 | 1篇 |
1998年 | 1篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1994年 | 1篇 |
1993年 | 4篇 |
1991年 | 3篇 |
1990年 | 1篇 |
1985年 | 2篇 |
1980年 | 3篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1969年 | 1篇 |
1967年 | 1篇 |
1966年 | 1篇 |
排序方式: 共有110条查询结果,搜索用时 812 毫秒
81.
Adler C Ahammed Z Allgower C Amonett J Anderson BD Anderson M Averichev GS Balewski J Barannikova O Barnby LS Baudot J Bekele S Belaga VV Bellwied R Berger J Bichsel H Bland LC Blyth CO Bonner BE Boucham A Brandin A Bravar A Cadman RV Caines H Calderón de la Barca Sánchez M Cardenas A Carroll J Castillo J Castro M Cebra D Chaloupka P Chattopadhyay S Chen Y Chernenko SP Cherney M Chikanian A Choi B Christie W Coffin JP Cormier TM Cramer JG Crawford HJ Deng WS Derevschikov AA Didenko L Dietel T 《Physical review letters》2002,89(27):272302
The STAR Collaboration reports the first observation of exclusive rho(0) photoproduction, AuAu-->AuAurho(0), and rho(0) production accompanied by mutual nuclear Coulomb excitation, AuAu-->Au*Au*rho(0), in ultraperipheral heavy-ion collisions. The rho(0) have low transverse momenta, consistent with coherent coupling to both nuclei. The cross sections at sqrt[s(NN)]=130 GeV agree with theoretical predictions treating rho(0) production and Coulomb excitation as independent processes. 相似文献
82.
The stability of Ni nanodomains observed in low alkali borate glasses (10 mol% alkali oxide) has been investigated at higher alkali contents using Ni K-edge extended X-ray absorption fine structure (EXAFS) spectroscopy. EXAFS data indicate that the Ni nanodomains disappear progressively when adding alkali oxide, whatever the nature of the alkali. This medium range reorganization around Ni is associated with a change of the local site from 6- to 5-fold coordination at 27-30 mol% alkali oxide and 4-fold coordination at higher alkali oxide content. Ni-Ni connections are still present for [5]Ni but no second neighbors are observed for [4]Ni in the EXAFS signal. The changes at both the local and medium range around Ni are likely associated to the disappearance of the large, rigid borate groups with the addition of alkali oxide. 相似文献
83.
Phillips M Cormier J Ferrence J Dowd C Kiss R Lutz H Carter J 《Journal of chromatography. A》2005,1078(1-2):74-82
Membrane adsorbers provide an attractive alternative to traditional bead-based chromatography columns used to remove trace impurities in downstream applications. A linearly scalable novel membrane adsorber family designed for the efficient removal of trace impurities from biotherapeutics, are capable of reproducibly achieving greater than 4 log removal of mammalian viruses, 3 log removal of endotoxin and DNA, and greater than 1 log removal of host cell protein. Single use, disposable membrane adsorbers eliminate the need for costly and time consuming column packing and cleaning validation associated with bead-based chromatography systems, and minimize the required number and volume of buffers. A membrane adsorber step reduces process time, floor space, buffer usage, labor cost, and improves manufacturing flexibility. This "process compression" effect is commonly associated with reducing the number of processing steps. The rigid microporous structure of the membrane layers allows for high process flux operation and uniform bed consistency at all processing scales. 相似文献
84.
Barrette J Bellwied R Braun-Munzinger P Cleland WE Cormier T Dadusc G David G Dee J Diebold GE Dietzsch O Duek E Fatyga M Fox D Greene SV Germani JV Hall JR Hemmick TK Herrmann N Hogue RW Hong B Jayananda K Kraus D Kumar BS Lacasse R Lissauer D Llope WJ Ludlam TW Majka R Makowiecki D Mark SK Mitchell JT Muthuswamy M O'Brien E Pruneau C Rotondo FS Sandweiss J da Silva NC Simon-Gillo J Slaughter J Sonnadara U Stachel J Takai H Takagui EM Throwe TG Waters L Winter C Wolf K Wolfe D Woody CL Xu N 《Physical review letters》1993,70(12):1763-1766
85.
Anne Roly Obah Kosso Nicolas Sellet Alexandre Baralle Morgan Cormier Jean-Philippe Goddard 《Chemical science》2021,12(20):6964
Direct metal-free near infra-red photoredox catalysis is applied to organic oxidation, photosensitization and reduction, involving cyanines as photocatalysts. This photocatalyst is competitive with conventional reactions catalyzed under visible light. Kinetic and quenching experiments are also reported. Interestingly, these systems are compatible with water media, opening perspective for various applications.Direct metal-free near infra-red photoredox catalysis is applied to oxidation, reduction and photosensitization, involving cyanines as photocatalysts. Mechanistic insights through kinetic and quenching experiments are also reported. 相似文献
86.
Armstrong TA Barish KN Batsouli S Bennett SJ Bertaina M Chikanian A Coe SD Cormier TM Davies R Dover CB Fachini P Fadem B Finch LE George NK Greene SV Haridas P Hill JC Hirsch AS Hoversten R Huang HZ Jaradat H Kumar BS Lainis T Lajoie JG Li Q Libby B 《Physical review letters》2000,85(13):2685-2688
We present Experiment 864's measurement of invariant antideuteron yields in 11.5A GeV/c Au+Pt collisions. The analysis includes 250x10(6) triggers representing 14x10(9) 10% central interactions sampled for events with high mass candidates. We find (1/2pip(t))d(2)N/dydp(t) = 3.5+/-1.5(stat)+0.9-0.5(syst)x10(-8) GeV-2 c(2) for 1.8 = 0.35 GeV/c ( y(c.m.) = 1.6) and 3.7+/-2.7(stat)+1.4-1.5(syst)x10(-8) GeV-2 c(2) for 1.4 = 0.26 GeV/c, and a coalescence parameter B2; of 4.1+/-2. 9(stat)+2.3-2.4(syst)x10(-3) GeV2 c(-3). Implications for coalescence and antimatter annihilation are discussed. 相似文献
87.
Lauzon JM Arseneau DJ Brodovitch JC Clyburne JA Cormier P McCollum B Ghandi K 《Physical chemistry chemical physics : PCCP》2008,10(39):5957-5962
The formation of the cyclohexadienyl radical, C(6)H(6)Mu, in ionic and molecular solvents has been compared. This is the first time that a muoniated free radical is reported in an ionic liquid. In marked contrast to molecular liquids, free radical generation in ionic liquids is significantly enhanced. Comparison of the hyperfine interactions in the ionic liquid and in molecular solvents and with theoretical calculations, suggests significant and unforeseen solvent interaction with the cyclohexadienyl radical. 相似文献
88.
Francis H. Barnes Aaron D. Nicholas Henry Melzer Kaleb P. Cormier Matthew D. Kessler Howard H. Patterson Robert D. Pike 《无机化学与普通化学杂志》2019,645(16):1043-1051
trans‐[Ln(NO3)2(Ph3AsO)4](NO3)2 ( 1 ) and mer‐[Ln(NO3)3(Ph3AsO)3] ( 2 ) complexes were prepared from Ln(NO3)3 · xH2O and Ph3AsO in chloroform (Ln = Y, Sm, Eu, Tb, and Dy). Production of complexes 1 vs. 2 and solvent content was found to be highly dependent on crystallization solvent choice. Tb and Eu produced only 1 , while the other Ln metals produced both 1 and 2 . Solvent‐free, acetone‐, and methanol‐containing polymorph series were identified for complexes 1 . Acetone/ether‐ and CH2Cl2‐containing polymorph series were identified for complexes 2 . Luminescence measurements were performed on solvent‐free 1 (Ln = Y, Eu, Tb, and Dy) and 2 (Ln = Sm) at 78 K. Sensitized lanthanide emission bands via resonance energy transfer were observed in all cases, except the control (Ln = Y). The efficiency of this energy transfer process varies amongst the lanthanide metals studied and was rationalized using Latva's empirical rule and Density Functional Theory calculations. 相似文献
89.
Previous work in our group on the cation binding of substituted cyclopentadienyl anions (Cp) showed the curious result that Cp traceless electric quadrupole moments (Θ(zz)) are almost all positive. Probing this issue further here we show that substituted Cp Θ(zz) values are always significantly more positive than the analogous substituted benzenes. Given the nature of aromatic Θ(zz) values, this is the opposite of what would be predicted. Furthermore, we show that the quadrupole moments of Cp anions do not behave as one would expect based on Cp substitutions. Unlike the quadrupole moments of substituted benzenes, which generally become more negative with the addition of electron-donating groups and more positive with the addition of electron-withdrawing groups, Cp quadrupole moments become more positive when any substituent is added, regardless of the electron-donating/withdrawing nature of the substituent. To explain these results we propose a model where the anionic Cp π-electron density repels the substituent electron density toward the molecular periphery and AIM calculations support this view. 相似文献
90.
Barrette J Bellwied R Bennett S Braun-Munzinger P Cleland WE Clemen M Cole J Cormier TM David G Dee J Dietzsch O Drigert M Gilbert S Hall JR Hemmick TK Herrmann N Hong B Jiang CL Kwon Y Lacasse R Lukaszew A Li Q Ludlam TW McCorkle S Mark SK Matheus R O'Brien E Panitkin S Piazza T Pruneau C Rao MN Rosati M daSilva NC Sedykh S Sonnadara U Stachel J Takai H Takagui EM Voloshin S Wang G Wessels JP Woody CL Xu N Zhang Y Zhang Z Zou C 《Physical review letters》1994,73(19):2532-2535