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491.
492.
Zheng X Aniol K Armstrong DS Averett TD Bertozzi W Binet S Burtin E Busato E Butuceanu C Calarco J Camsonne A Cates GD Chai Z Chen JP Choi S Chudakov E Cusanno F Leo RD Deur A Dieterich S Dutta D Finn JM Frullani S Gao H Gao J Garibaldi F Gilad S Gilman R Gomez J Hansen JO Higinbotham DW Hinton W Horn T De Jager CW Jiang X Kaufman L Kelly J Korsch W Kramer K LeRose J Lhuillier D Liyanage N Margaziotis DJ Marie F Markowitz P McCormick K Meziani ZE Michaels R Moffit B Nanda S Neyret D Phillips SK 《Physical review letters》2004,92(1):012004
We have measured the neutron spin asymmetry A(n)(1) with high precision at three kinematics in the deep inelastic region at x=0.33, 0.47, and 0.60, and Q(2)=2.7, 3.5, and 4.8 (GeV/c)(2), respectively. Our results unambiguously show, for the first time, that A(n)(1) crosses zero around x=0.47 and becomes significantly positive at x=0.60. Combined with the world proton data, polarized quark distributions were extracted. Our results, in general, agree with relativistic constituent quark models and with perturbative quantum chromodynamics (PQCD) analyses based on the earlier data. However they deviate from PQCD predictions based on hadron helicity conservation. 相似文献
493.
David O Calvet S Chau F Vanucci-Bacqué C Fargeau-Bellassoued MC Lhommet G 《The Journal of organic chemistry》2004,69(8):2888-2891
We report the results of a study aimed at the diastereoselective synthesis of chiral 2-alkoxy-5-/6-methoxycarbonylmethylidenepyrrolidines/-piperidines by condensation of chiral amines onto omega-oxo alkynoates and omega-oxo beta-keto esters. 相似文献
494.
From a thermodynamic model of associated solution, the molar extinction coefficients for the spectroscopically discernable ν(OH) vibrations of associated species of cyclohexanol in isooctane solutions at 25°C and 45°C are obtained. It is found that the molar extinction coefficients for the end hydroxyl group of open species and for the monomer band are very near (57 M?1 cm?1 at 25°C). For the hydrogen bonded hydroxyl groups, molar extinction coefficients at 25°C are found to be, in M?1 cm?1 units : 93 for the open dimer ( = 3515 cm?1), 90 for the open trimer ( = 3440 cm?1), 126 for the other i-mers ( = 3340 cm?1). 相似文献
495.
Ions binding to solid organic matter was investigated in this study. A simple surface complexation model, the diffuse double-layer model, was used to describe Pb(II), Cd(II), Zn(II), and Ni(II) binding to a lignocellulosic substrate extracted from wheat bran. The lignocellulosic substrate was represented by two acid sites: a low-pH ("carboxylic") site and a high-pH ("phenolic") site, the phenolic-type sites contributing significantly to the binding behavior, even at relatively low pH. By using the previously determined concentrations of sites and acidity constants, the surface complexation model was applied to Pb, Cd, Zn, and Ni binding as a function of pH in a 0.1 M NaNO(3) medium. The model fits were good over a wide range of pH (2相似文献
496.
Lepère M Chevallard C Hernandez JF Mitraki A Guenoun P 《Langmuir : the ACS journal of surfaces and colloids》2007,23(15):8150-8155
We present the 2D self-assembly properties of an amyloid-like peptide (LSFDNSGAITIG-NH2) (i.e., LSFD) over a whole range of spatial scales. This peptide is known to adopt an amyloid-like behavior in water where it aggregates into fibrils. Monolayers of this 12 amino acid peptide were built by direct spreading and compression of an organic unstructured LSFD solution at the air/water interface. Investigation by infrared spectroscopy of the peptide secondary structure reveals beta-sheet formation at the water surface. As evidenced by Brewster angle microscopy, compression of the peptidic film results in the formation of large condensed domains. We used atomic force microscopy to show that these domains are made of rather monodisperse, elongated domains of monomolecular thickness, which are about 1 microm long and hundred of nanometers wide. These nanodomains can be compacted up to the formation of a homogeneous monolayer on the micrometer scale. These bidimensional structures appear as a surface-induced counterpart of the bulk amyloid fibrils that do not form at the air/water interface. These self-assembled peptide nanostructures are also very promising for building organized nanomaterials. 相似文献
497.
Geny A Leboeuf D Rouquié G Vollhardt KP Malacria M Gandon V Aubert C 《Chemistry (Weinheim an der Bergstrasse, Germany)》2007,13(19):5408-5425
A series of 1,3- and 1,4-diboryl-1,3-cyclohexadienes have been prepared by intermolecular CoCp-mediated [2+2+2] cocyclizations of alkynylboronic pinacolate esters with alkenes, followed by oxidative demetallation with iron(III) chloride. The effect of substitution at the borylated alkyne on chemo- and regioselectivities has been studied, suggesting steric control. The proper choice of substituents allowed the preparation of 1,3-diborylated cyclohexadienes in a highly selective manner. Alternatively, 1,4-diborylated cyclohexadienes could be prepared from diborylated diynes. The scope of this reaction has been examined and found to include electron-poor, electron-rich, linear, and cyclic alkenes. The diborylated cyclohexadienes were submitted to single or double Suzuki-Miyaura cross-coupling reactions with haloarenes to afford polyarylated systems. The mechanism of the title reaction, including the regioselectivity of the cycloaddition steps, has been analyzed by means of DFT computations. 相似文献
498.
Claudel S Gosmini C Paris JM Périchon J 《Chemical communications (Cambridge, England)》2007,(35):3667-3669
A variety of functionalized arylboronates are obtained in moderate to excellent yield by a one-step chemical procedure from the corresponding halides and a haloboronic ester via an intermediate arylzinc species. 相似文献
499.
500.