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71.
A. Wallace Cordes Robert C. Haddon Richard T. Oakley 《Phosphorus, sulfur, and silicon and the related elements》2013,188(4-5):673-684
The use of neutral π-radicals as building blocks for molecular conductors holds both appeal and challenge. Such systems obviate the need for counterions, as charge transfer is not required to generate charge carriers. Essentially an array of π-radicals should function like atoms in an elemental metal, e.g., sodium, affording a half-filled energy band. Most radicals, however, tend to dimerize, and even when association can be suppressed the resulting low bandwidth W, coupled with a high on-site Coulomb repulsion U, leads to a Mott insulating state. We are pursuing the design and synthesis of stable heterocyclic thiazyl radicals, with a view to generating stable, crystalline materials with a high W/U ratio. The search for these new radicals, the molecular analogues of sodium, is the subject of this presentation. 相似文献
72.
73.
Claudia Schremmer Dr. Claudia Cordes Dr. Iris Klawitter Dr. Marie Bergner Dr. Christine E. Schiewer Dr. Sebastian Dechert Dr. Serhiy Demeshko Dr. Michael John Prof. Dr. Franc Meyer 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(15):3918-3929
Starting from their six-coordinate iron(II) precursor complexes [L8RFe(MeCN)]2+, a series of iron(III) complexes of the known macrocyclic tetracarbene ligand L8H and its new octamethylated derivative L8Me, both providing four imidazol-2-yliden donors, were synthesized. Several five- and six-coordinate iron(III) complexes with different axial ligands (Cl−, OTf−, MeCN) were structurally characterized by X-ray diffraction and analyzed in detail with respect to their spin state variations, using a bouquet of spectroscopic methods (NMR, UV/Vis, EPR, and 57Fe Mößbauer). Depending on the axial ligands, either low-spin (S=1/2) or intermediate-spin (S=3/2) states were observed, whereas high-spin (S=5/2) states were inaccessible because of the extremely strong in-plane σ-donor character of the macrocyclic tetracarbene ligands. These findings are reminiscent of the spin state patterns of topologically related ferric porphyrin complexes. The ring conformations and dynamics of the macrocyclic tetracarbene ligands in their iron(II), iron(III) and μ-oxo diiron(III) complexes were also studied. 相似文献
74.
75.
Nenov A Cordes T Herzog TT Zinth W de Vivie-Riedle R 《The journal of physical chemistry. A》2010,114(50):13016-13030
A combined experimental and theoretical investigation of photoinduced Z/E isomerizations is presented. Unsubstituted Hemithioindigo is selected as a representative minimal model to unravel the reaction mechanism in the presence of heteroatoms on an atomic level. Time-resolved spectroscopy reveals multiexponential reaction dynamics on the few picoseconds time scale, which are interpreted by quantum chemical calculations at the CASSCF/CASPT2 level of theory. Detailed insight into the processes governing the ultrafast decay from the first excited state, mediated by a number of conical intersections, is provided. Charge separation and charge balance recovery on the reaction pathway play the leading role and are controlled by the electron-donating or -withdrawing character of the heteroatoms. The electronic and geometric structures of the individual minimum energy conical intersections governing the reaction are rationalized, and an extended energetically low lying conical intersection seam is extracted. Comparison to the experimental results permits linking the observed time constants to molecular intermediates and pathways. An explanation is provided for the pronounced differences of Z → E and the E → Z photoreactions upon excitation to the first excited singlet state. 相似文献
76.
Aggregation and Contingent Metal/Surface Reactivity of 1,3,8,10‐Tetraazaperopyrene (TAPP) on Cu(111)
Manfred Matena Meike Stöhr Dr. Till Riehm Dr. Jonas Björk Susanne Martens Matthew S. Dyer Dr. Mats Persson Prof. Jorge Lobo‐Checa Dr. Kathrin Müller Dr. Mihaela Enache Hubert Wadepohl Prof. Jörg Zegenhagen Dr. Thomas A. Jung Dr. Lutz H. Gade Prof. Dr. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(7):2079-2091
77.
X Chi M E Itkis K Kirschbaum A A Pinkerton R T Oakley A W Cordes R C Haddon 《Journal of the American Chemical Society》2001,123(17):4041-4048
We report the preparation, crystallization, and solid-state characterization of ethyl (3)- and butyl (4)-substituted spiro-biphenalenyl radicals. Both of these compounds are found to be conducting face-to-face pi-dimers in the solid state but with different room-temperature magnetic ground states. At room temperature, 4 exists as a diamagnetic pi-dimer (interplanar separation of approximately 3.1 A), whereas 3 is a paramagnetic pi-dimer (interplanar separation of approximately 3.3 A), and both compounds show phase transitions between the paramagnetic and diamagnetic forms. Electrical resistivity measurements of single crystals of 3 and 4 show that the transition from the high-temperature paramagnetic pi-dimer form to the low-temperature diamagnetic pi-dimer structure is accompanied by an increase in conductivity by about 2 orders of magnitude. This behavior is unprecedented and is very difficult to reconcile with the usual understanding of a Peierls dimerization, which inevitably leads to an insulating ground state. We tentatively assign the enhancement in the conductivity to a decrease in the on-site Coulombic correlation energy (U), as the dimers form a super-molecule with twice the amount of conjugation. 相似文献
78.
H. O. Cordes 《Integral Equations and Operator Theory》1999,34(1):9-27
The Dirac equation, as a 4×4-hyperbolic system on 3, possesses an invariant algebra of global pseudodifferential operators-in the sense that conjugation with the Dirac time propagator leaves the algebra invariatn (cf. [CX]. Chapter 10). In this paper we examine the relation between the two invariant algebras att=0 and att'=0 when (t,x) and (t',x') are coordinates of Minkowsky space related by a (proper) Lorentz transform. For vanishing electromagnetic potentials these algebras are transforms of each other by the implied change of dependent and independent variables. In the general case such a space-time transform will make the potentials time dependent, hence also the algebra dependent on the initial plane. 相似文献
79.
Desrochers PJ LeLievre S Johnson RJ Lamb BT Phelps AL Cordes AW Gu W Cramer SP 《Inorganic chemistry》2003,42(24):7945-7950
A stable discrete nickel borohydride complex (Tp*NiBH(4) or Tp*NiBD(4)) was prepared using the nitrogen-donor ligand hydrotris(3,5-dimethylpyrazolyl)borate (Tp*-). This complex represents one of the best characterized nickel(II) borohydrides to date. Tp*NiBH(4) and Tp*NiBD(4) are stable toward air, boiling water, and high temperatures (mp > 230 degrees C dec). X-ray crystallographic measurements for Tp*NiBH(4) showed a six-coordinate geometry for the complex, with the nickel(II) center facially coordinated by three bridging hydrogen atoms from borohydride and a tridentate Tp(-) ligand. For Tp*NiBH(4), the empirical formula is C(15)H(26)B(2)N(6)Ni, a = 13.469(9) A, b = 7.740(1) A, c = 18.851(2) A, beta = 107.605(9) degrees, the space group is monoclinic P2(1)/c, and Z = 4. Infrared measurements confirmed the presence of bridging hydrogen atoms; both nu(B[bond]H)(terminal) and nu(B[bond]H)(bridging) are assignable and shifted relative to nu(B-D) of Tp*NiBD(4) by amounts in agreement with theory. Despite their hydrolytic stability, Tp*NiBH(4) and Tp*NiBD(4) readily reduce halocarbon substrates, leading to the complete series of Tp*NiX complexes (X = Cl, Br, I). These reactions showed a pronounced hydrogen/deuterium rate dependence (k(H)/k(D) approximately 3) and sharp isosbestic points in progressive electronic spectra. Nickel K-edge X-ray absorption spectroscopy (XAS) measurements of a hydride-rich nickel center were obtained for Tp*NiBH(4), Tp*NiBD(4), and Tp*NiCl. X-ray absorption near-edge spectroscopy results confirmed the similar six-coordinate geometries for Tp*NiBH(4) and Tp*NiBD(4). These contrasted with XAS results for the crystallographically characterized pseudotetrahedral Tp*NiCl complex. The stability of Tp*Ni-coordinated borohydride is significant given this ion's accelerated decomposition and hydrolysis in the presence of transition metals and simple metal salts. 相似文献
80.