Investigating technical and ecological efficiencies in the electricity generation industry: are there win-win opportunities?

Using data from the EPA's EGRID and Clean Air Markets databases, we investigate the energy (technical) and emissions (ecological) efficiencies of 437 of the largest US electricity generators. We focus on fossil-fuel-based electricity generating plants because of their significant impact on industry environmental performance, especially with respect to air media emissions. Data envelopment analysis is used to determine the relative technical and environmental performance of these plants and whether win-win opportunities and end-of-pipe versus in-process (reactive versus proactive) practices relate to these efficiencies. The results show that win-win opportunities in terms of simultaneous technical (operational) efficiency and ecological efficiency do not appear to exist.     

Intensity curvature sensor based on photonic crystal fiber with three coupled cores

An intensity curvature sensor using a Photonic Crystal Fiber (PCF) with three coupled cores is proposed. The three cores were aligned and there was an air hole between each two consecutive cores. The fiber had a low air filling fraction, which means that the cores remain coupled in the wavelength region studied. Due to this coupling, interference is obtained in the fiber output even if just a single core is illuminated. A configuration using reflection interrogation, which used a section fiber with 0.13 m as the sensing head, was characterized for curvature sensing. When the fiber is bended along the plane of the cores, one of the lateral cores will be stretched and the other compressed. This changes the coupling coefficient between the three cores, changing the output optical power intensity. The sensitivity of the sensing head was strongly dependent on the direction of bending, having its maximum when the bending direction was along the plane of the cores. A maximum curvature sensitivity of 2.0 dB/m⁻¹ was demonstrated between 0 m and 2.8 m.     

A Two-Parameter Distribution Obtained by Compounding the Generalized Exponential and Exponential Distributions

We introduce a new two-parameter lifetime distribution obtained by compounding the generalized exponential and exponential distributions. We assume that the shape parameter of the generalized exponential distribution is a random variable having the exponential distribution. The shapes of the density and hazard rate functions are derived. The model parameters are estimated by maximum likelihood, and an application of the proposed distribution is presented.

     

Second- and third-order bias reduction for one-parameter family models

In this paper we derive second- and third-order bias-corrected maximum likelihood estimates in general uniparametric models. We compare the corrected estimates and the usual maximum likelihood estimate in terms of their mean squared errors. We also obtain closed-form expressions for bias-corrected estimates in one-parameter exponential family models. Our results cover many important and commonly used distributions. Simulation results are also given.     

Ecological modernization in the electrical utility industry: An application of a bads–goods DEA model of ecological and technical efficiency

Newly-developed data envelopment analysis techniques permit simultaneous consideration of ‘good and bad’ outputs in evaluating efficiency. We use these techniques to determine joint ecological and technical efficiencies of the 437 largest fossil-fueled electricity-generating plants in the United States. Utilizing the EPA’s E-Grid and Clean Air Markets databases and drawing on ecological modernization theory we evaluate whether innovations in organizational practices and technological solutions help achieve joint technical and environmental performance efficiencies.     

Solitary waves in an isotropic ferromagnetic chain

It is shown that due to high-order terms in the Holstein-Primakoff boson-like spin operator transformation we can have a solitary wave solution even in an isotropic ferromagnetic chain.     

Application of matrix-assisted laser desorption/ionization to on-line aerosol time-of-flight mass spectrometry

Matrix-assisted laser desorption/ionization (MALDI) mass spectra were obtained from single biological aerosol particles using an aerosol time-of-flight mass spectrometer (ATOFMS). The inlet to the ATOFMS was coupled with an evaporation/condensation flow cell that allowed the aerosol to be coated with matrix material as the sampled stream entered the spectrometer. Mass spectra were generated from aerosol composed either of gramicidin-S or erythromycin, two small biological molecules, or from aerosolised spores of Bacillus subtilis var niger. Three different matrices were used: 3-nitrobenzyl alcohol, picolinic acid and sinapinic acid. A spectrum of gramicidin-S was generated from approximately 250 attomoles of material using a molar ratio of 3-nitrobenzyl alcohol to analyte of approximately 20:1. A single peak, located at 1224 Da, was obtained from the bacterial spores. The washing liquid and extract solution from the spores were analyzed using electrospray mass spectrometry and subsequent MS/MS product ion experiments. This independent analysis suggests that the measured species represents part of the B. subtilis peptidoglycan. The on-line addition of matrix allows quasi-real-time chemical analysis of individual, aerodynamically sized particles, with an overall system residence time of less than 5 seconds. These results suggest that a MALDI-ATOFMS can provide nearly real-time identification of biological aerosols. Copyright 2000 John Wiley & Sons, Ltd.     

1,3,4-Oxadiazole-containing hybrids as potential anticancer agents: Recent developments,mechanism of action and structure-activity relationships

Chemotherapy is an important therapeutic approach for the treatment of cancer. Currently, many anticancer drugs are available in the market that plays an important role in cancer treatment, but concerns such as, drug resistance and side effects create an urgent need for the development of new anti-tumor drugs with high potency and less side effects. Heterocycles are of great interest due to their fascinating anticancer activity. Among them, 1,3,4-oxadiazoles showed attracting anti-tumor activity and its derivatives are under clinical trials for the treatment of cancer. Hybridization of 1,3,4-oxadiazole moiety with other heterocyclic pharmacophoresis a promising approach to overcome various disadvantages of current anticancer drugs such as drug resistance, toxicity, and other side effects. Thus, 1,3,4-oxadiazole-heterocycle hybrids occupy a significant position in the discovery of anti-tumor drugs. Among the reported oxadiazole-based hybrids reviewed here, compounds 45i, 59j, and 62x showed the highest anticancer activity with IC₅₀ values in the nanomolar range. This review summarizes the recent developments in the anticancer potential, structure–activity relationships, and mechanisms of actions of 1,3,4-oxadiazole-heterocycle hybrids.     

Determination of dissolved bromate in drinking water by ion chromatography and post column reaction: interlaboratory study

A collaborative study, International Evaluation Measurement Programme-25a, was conducted in accordance with international protocols to determine the performance characteristics of an analytical method for the determination of dissolved bromate in drinking water. The method should fulfill the analytical requirements of Council Directive 98/83/EC (referred to in this work as the Drinking Water Directive; DWD). The new draft standard method under investigation is based on ion chromatography followed by post-column reaction and UV detection. The collaborating laboratories used the Draft International Organization for Standardization (ISO)/Draft International Standard (DIS) 11206 document. The existing standard method (ISO 15061:2001) is based on ion chromatography using suppressed conductivity detection, in which a preconcentration step may be required for the determination of bromate concentrations as low as 3 to 5 microg/L. The new method includes a dilution step that reduces the matrix effects, thus allowing the determination of bromate concentrations down to 0.5 microg/L. Furthermore, the method aims to minimize any potential interference of chlorite ions. The collaborative study investigated different types of drinking water, such as soft, hard, and mineral water. Other types of water, such as raw water (untreated), swimming pool water, a blank (named river water), and a bromate standard solution, were included as test samples. All test matrixes except the swimming pool water were spiked with high-purity potassium bromate to obtain bromate concentrations ranging from 1.67 to 10.0 microg/L. Swimming pool water was not spiked, as this water was incurred with bromate. Test samples were dispatched to 17 laboratories from nine different countries. Sixteen participants reported results. The repeatability RSD (RSD(r)) ranged from 1.2 to 4.1%, while the reproducibility RSD (RSDR) ranged from 2.3 to 5.9%. These precision characteristics compare favorably with those of ISO 15601. A thorough comparison of the performance characteristics is presented in this report. All method performance characteristics obtained in the frame of this collaborative study indicate that the draft ISO/DIS 11206 standard method meets the requirements set down by the DWD. It can, therefore, be considered to fit its intended analytical purpose.