Surface and electrochemical analysis for the understanding of TiO2 nanopores/nanotubes changes in post‐elaboration treatment

The electrochemical stability of TiO₂ nanoarchitecture fabricated in fluoride electrolyte presented in this paper is related to 2D and 3D geometries that present a shift from nanopores toward nanotubes. The fabrication conditions involve a 60 V applied voltage for 2 hours of anodizing in order to create the ordered structures, in a mixture of low‐water glycerol electrolyte and fluoride. With the use of different ultrasonication times, a variety of nanotubes/nanopores were observed. The surface interfacial aspects were investigated mainly by surface microscopy and hydrophilic/hydrophobic balance for the grown structures ultrasonicated at various periods of time. The electrochemical behavior of the nanotube‐structured surface was performed by potentiodynamic evaluation and electrochemical impedance spectroscopy in a simulated body fluid solution. As a most important result, all surface analysis and electrochemical data interpretation permitted the proposition of a model for elaboration of different nanostructures from nanopores to nanotubes. These different surface nanoarchitectures were obtained as a result of ultrasonication at various periods of time. Copyright © 2010 John Wiley & Sons, Ltd.     

Ueber die Trennung und Bestimmung von Nickel und Kobalt

Ohne Zusammenfassung     

Block-Projections Algorithms with Blocks Containing Mutually Orthogonal Rows and Columns

In this paper we present an algorithm which, for a given (sparse) matrix, constructs a partition of its set of row-indices, such that each subset of this partition (except the last one obtained) contains indices which correspond to mutually orthogonal rows. We then use such decompositions in some classes of block-projections methods, previously extended by the author to general inconsistent linear least-squares problems. Numerical experiments on an inconsistent and rank-deficient least-squares model problem are described in the last section of the paper.     

Strong approximation of quadrics and representations of quadratic forms

Let V be an indefinite quadratic space over a number field F and U be a nondegenerate subspace of V. Suppose that M is a lattice on V, and that N is a lattice on U which is represented by M locally everywhere. The main result of this paper is a necessary and sufficient condition for which there exists a representation of N by M that approximates a given family of local representations. This is applied to determine when the variety of representations of U by V has strong approximation with respect to a finite set of primes of F that contains all the archimedean primes.     

Borel-Weil-Bott theory on the moduli stack of G-bundles over a curve

Let G be a semi-simple group and M the moduli stack of G-bundles over a smooth, complex, projective curve. Using representation-theoretic methods, I prove the pure-dimensionality of sheaf cohomology for certain “evaluation vector bundles” over M, twisted by powers of the fundamental line bundle. This result is used to prove a Borel-Weil-Bott theorem, conjectured by G. Segal, for certain generalized flag varieties of loop groups. Along the way, the homotopy type of the group of algebraic maps from an affine curve to G, and the homotopy type, the Hodge theory and the Picard group of M are described. One auxiliary result, in Appendix A, is the Alexander cohomology theorem conjectured in [Gro2]. A self-contained account of the “uniformization theorem” of [LS] for the stack M is given, including a proof of a key result of Drinfeld and Simpson (in characteristic 0). A basic survey of the simplicial theory of stacks is outlined in Appendix B. Oblatum 17-XII-1996 & 26 VI-1997     

Regularity and convergence of stochastic convolutions in duals of nuclear Fréchet spaces

Let Φ′ be the strong dual of a nuclear Fréchet space Φ. In this paper we present regularity properties, weak convergence, and convergence in probability and in mean square of Φ′-valued stochastic evolution equations and convolutions with respect to Φ′-valued cadlag martingales.     

Study of collision-induced decomposition of phenothiazine by ion trap mass spectrometry

The collision-induced decomposition pathways of phenothiazine were studied in detail by ion trap mass spectrometry. With this approach, different amounts of energy can be deposited into the fragment ions, thus favouring particular structures. Different relative abundances in the fragmentation patterns of selected ions are observed, depending on whether they are produced by electron impact or multiple mass spectrometry [(MS)ⁿ] methods.