Laser surface-melting of metals studied by PAC

High purity Pt, Ni, Cu, Fe and Al metal foils were electroplated with carrier-free¹¹¹In probe atoms and melted at 293 K using 32 ns ruby laser pulses with energy densities in the range 1–10 J cm⁻². Three distinct lattice locations of the probe atoms were detected in the melted surface layers using perturbed γ-γ angular correlation spectroscopy: (i) defect-free substitutional sites, (ii) non-unique sites with broad distributions of quadrupole interactions, and (iii) a probemonovacancy complex (for Pt only). The defect-free fraction was found to approach 100% when Pt is irradiated at 9 J cm⁻². The fraction of probes on defect-free sites was found to increase with the energy density of the pulse and with the solubility of In in the metals. The data are consistent with the idea that laser surface-melting produces high concentrations of vacancies and lattice sinks, although no thermal trapping of point defects was detected. Supported in part by National Science Foundation grant DMR 86-19688 (Metallurgy Program).     

Eine kolorimetrische Methode zur Bestimmung von freiem Formaldehyd und Hexamethylenamin

Ohne Zusammenfassung     

Arsen

Ohne Zusammenfassung     

Vibrational spectroscopy differentiates between multipotent and pluripotent stem cells

Over the last few years, there has been an increased interest in the study of stem cells in biomedicine for therapeutic use and as a source for healing diseased or injured organs/tissues. More recently, vibrational spectroscopy has been applied to study stem cell differentiation. In this study, we have used both synchrotron based FTIR and Raman microspectroscopies to assess possible differences between human pluripotent (embryonic) and multipotent (adult mesenchymal) stem cells, and how O(2) concentration in cell culture could affect the spectral signatures of these cells. Our work shows that infrared spectroscopy of embryonic (pluripotent) and adult mesenchymal (multipotent) stem cells have different spectral signatures based on the amount of lipids in their cytoplasm (confirmed with cytological staining). Furthermore, O(2) concentration in cell culture causes changes in both the FTIR and Raman spectra of embryonic stem cells. These results show that embryonic stem cells might be more sensitive to O(2) concentration when compared to mesenchymal stem cells. While vibrational spectroscopy could therefore be of potential use in identifying different populations of stem cells further work is required to better understand these differences.     

A radiofrequency coil configuration for imaging the human vertebral column at 7 T

We describe the design and testing of a quadrature transmit, eight-channel receive array RF coil configuration for the acquisition of images of the entire human spinal column at 7 T. Imaging parameters were selected to enable data acquisition in a clinically relevant scan time. Large field-of-view (FOV) scanning enabled sagittal imaging of the spine in two or three-stations, depending upon the height of the volunteer, with a total scan time of between 10 and 15 min. A total of 10 volunteers have been scanned, with results presented for the three subjects spanning the range of heights and weights, namely one female (1.6 m, 50 kg), one average male (1.8 m, 70 kg), and one large male (1.9 m, 100 kg).     

Anomalous spreading behaviour of polyethyleneglycoldistearate monolayers at air/water interface

Spreading behaviour of the dimeric surfactant polyethylene-glycoldistearate (PEGDS) monolayer at air/water interface has been studied using surface pressure-area (π-A) isotherms as a function of temperature. The isotherms show a plateau suggesting a transition between a liquid expanded (LE) and a condensed state. The condensed state possibly arises due to nucleation and growth of multilayers from the monolayer. Isobaric measurements of bothA-T and π-T at constant area show transitions atT = 295 K. These plots suggest a melting followed by formation of condensed microcrystallites. Structure optimization carried out using various angles of orientation of the alkyl tails with respect to the backbone in PEGDS reveals tilt transitions of the tails in different states which can be related to the packing behaviour seen in the isotherms. Optical microscopy has been used to confirm the structures in these states.     

Progress in the pumping of gamma-ray laser

A gamma-ray laser would stimulate coherent emission of radiation at wavelengths below 1 Å from excited states of nuclei. However, the difficulties in realizing such a device were considered insurmountable when the first cycle of study ended in1981. Since then, research on the feasibility of a gamma-ray laser has taken on a completely new character. A nuclear analog of the ruby laser has been proposed and many of the component steps for pumping the nuclei have been demonstrated experimentally. A quantitative model based upon the new data and the concepts of this decade shows the gamma-ray laser to be feasible if some real isotope has its properties sufficiently close to the ideals. The greatest positive impact has come from the discovery of giant resonances for pumping nuclei with photons that greatly reduce the levels of input power needed. Most recently, attention has been focused upon efforts to demonstrate prelasing levels of fluorescence from simulation nuclides and actual gamma-ray laser candidates. Problems being addressed are the acquisition of macroscopic samples of the best nuclei for testing and the demonstration of appropriate instrumentation.     

John Leslie Britton

John Leslie Britton died in a climbing accident on the Isleof Skye on 13 June 1994 at the age of 66. He became a memberof the London Mathematical Society in 1957, served the societyas Meetings and Membership Secretary from 1973 to 1976, andat the same time was Editor of the Society's Newsletter.