全文获取类型
收费全文 | 449篇 |
免费 | 39篇 |
国内免费 | 38篇 |
专业分类
化学 | 364篇 |
晶体学 | 12篇 |
力学 | 6篇 |
综合类 | 12篇 |
数学 | 34篇 |
物理学 | 98篇 |
出版年
2023年 | 4篇 |
2022年 | 6篇 |
2021年 | 8篇 |
2020年 | 18篇 |
2019年 | 9篇 |
2018年 | 9篇 |
2017年 | 11篇 |
2016年 | 6篇 |
2015年 | 11篇 |
2014年 | 9篇 |
2013年 | 44篇 |
2012年 | 27篇 |
2011年 | 24篇 |
2010年 | 16篇 |
2009年 | 17篇 |
2008年 | 24篇 |
2007年 | 31篇 |
2006年 | 21篇 |
2005年 | 33篇 |
2004年 | 27篇 |
2003年 | 18篇 |
2002年 | 20篇 |
2001年 | 10篇 |
2000年 | 23篇 |
1999年 | 13篇 |
1998年 | 4篇 |
1997年 | 4篇 |
1996年 | 3篇 |
1995年 | 8篇 |
1994年 | 4篇 |
1993年 | 11篇 |
1992年 | 2篇 |
1991年 | 5篇 |
1990年 | 3篇 |
1989年 | 2篇 |
1984年 | 3篇 |
1982年 | 4篇 |
1981年 | 2篇 |
1980年 | 8篇 |
1977年 | 3篇 |
1976年 | 3篇 |
1975年 | 1篇 |
1973年 | 3篇 |
1969年 | 2篇 |
1968年 | 3篇 |
1967年 | 1篇 |
1966年 | 1篇 |
1962年 | 1篇 |
1954年 | 1篇 |
1927年 | 1篇 |
排序方式: 共有526条查询结果,搜索用时 390 毫秒
91.
通过Monte Carlo模拟方法对抗体-抗原复合物在等活性和非等活性条件下生长的标度行为进行了研究. 模拟所用算法的有效性通过在等活性条件下的模拟结果与解析结果之间的一致性得以证明. 在模拟中, 主要考察了抗体-抗原复合物的数量分布函数、重均聚合度以及特征关联长度在临界点附近的标度行为, 给出相应的标度指数, 并以其检验溶胶-凝胶相变的广义标度律. 研究结果表明, 非等活性对抗体-抗原复合物的生长具有显著影响, 可为临床免疫分析提供相应的理论线索. 相似文献
92.
93.
A Study of the Probe Effect on the Apparent Image of Biological Atomic Force Microscopy 总被引:1,自引:0,他引:1
Xue Mei WANG * Lei QIN Long BA Zu Hong LU The State Key Lab of Coordination Chemistry Nanjing University Nanjing National Lab of Molecular Biomolecular Electronics Southeast University Nanjing 《中国化学快报》2001,(12)
The atomic force microscopy (AFM) possesses high spatial resolution and it is compatible with liquid environments. AFM can provide possibility to study a wide range of biological problems at the molecular level and acquire topological information at nanometre resolution under physiological conditions1,2. However, a major problem for image reconstruction of biological specimens is that structures of most biological molecules are very soft and delicate, which could be easily deformed and dama… 相似文献
94.
Simon J. Coles Michael B. Hursthouse 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(9):e405-e405
The molecular structure of the title compound, C14H14BrF3O2, adopts a bent conformation. Intramolecular O—H?F and intermolecular O—H?O interactions form a bifurcated hydrogen bond which produces a supramolecular assembly of head‐to‐tail dimers. 相似文献
95.
丙烯腈 (AN)聚合通常采用自由基和阴离子聚合两种 .它们存在催化剂活性低 ,用量大等缺点 .关于丙烯腈的配位聚合研究报道则较少 .最近 ,有报道发现二价稀土化合物可以催化丙烯腈聚合 ,但催化活性较低[1 ,2 ] .本文以二茚基钇 -铝双金属配合物 (C9H7) 2 Y(μ- Et) 2 Al Et2(以下以 Y- Al代表 )为 AN聚合催化剂 ,发现它单独可以催化 AN聚合 .当外加酚钠(Ph ONa)时 ,可以大大提高聚丙烯腈 (PAN)的产率及分子量 .研究了单体浓度、催化剂浓度、温度、时间等对 AN聚合的影响 ,并对其引发机理进行了研究 .Y- Al的合成及聚合方法见文献 [3… 相似文献
96.
非线性Af—Bg型自由基交替共聚反应的固化理论 总被引:1,自引:1,他引:0
利用高分子反应统计理论,给出了非线性Af-Bg型自由基交替共聚反应的溶胶-凝胶分配方程和反应体系的凝凝胶化条件,这些结果是进一步研究与凝胶网络性能相关的网络结构参数的基础。 相似文献
97.
98.
Frank Marken Yu-Chen Tsai Andrew J. Saterlay Barry A. Coles Daniel Tibbetts Katherine Holt Christiaan H. Goeting John S. Foord Richard G. Compton 《Journal of Solid State Electrochemistry》2001,5(5):313-318
Microwave activation of electrochemical processes has recently been introduced as a new technique for the enhancement and
control of processes at electrode|solution (electrolyte) interfaces. This methodology is extended to processes at glassy carbon
and boron-doped diamond electrodes. Deposition of both Pb metal and PbO2 from an aqueous solution of Pb2+ (0.1 M HNO3) are affected by microwave radiation. The formation of PbO2 on anodically pre-treated boron-doped diamond is demonstrated to change from kinetically sluggish and poorly defined at room
temperature to nearly diffusion controlled and well defined in the presence of microwave activation. Calibration of the temperature
at the electrode|solution (electrolyte) interface with the Fe3+/2+ (0.1 M HNO3) redox system allows the experimentally observed effects to be identified as predominantly thermal in nature and therefore
consistent with a localized heating effect at the electrode|solution interface. The microwave-activated deposition of PbO2 on boron-doped diamond remains facile in the presence of excess oxidizable organic compounds such as ethylene glycol. An
increase of the current for the electrocatalytic oxidation of ethylene glycol at PbO2/boron-doped diamond electrodes in the presence of microwave radiation is observed. Preliminary results suggest that the electrodissolution
of solid microparticles of PbO2 abrasively attached to the surface of a glassy carbon electrode is also enhanced in the presence of microwave radiation.
Electronic Publication 相似文献
99.
The dynamics of electric-field-induced lattice distortions and phase transitions in the BPI, BPII and BPIII (fog) phases of blue-phase mixtures, which include low-molar-mass and/or polymeric components, have been studied. Several electric-field-induced effects have been observed in the blue phases, and the electro-optic characteristics of the driven and non-driven responses of each are considered. Anomalous behaviour in BPIII, where driven response times were measured to be slower than the relaxation responses, is described and considered with respect to relaxation processes previously observed in BPII. Finally, we present data for a mixture containing 40 per cent by weight of a side-chain-polymer liquid crystal. In this case only BPI was observed, and it appears that the increased viscosity had little effect on the response times of the system. These data are discussed. 相似文献
100.