天目铁木愈伤组织和芽苗诱导技术

以天目铁木嫩茎尖为外植体,应用均匀设计法筛选其基部愈伤组织诱导和愈伤组织再分化芽苗的最适合培养基.结果表明,最适合的嫩茎尖基部愈伤组织诱导培养基为1/2DR+TDZ 2.30 mg·L^-1+2,4-D 0.55 mg·L^-1,诱导率为93.5%;愈伤组织芽苗再分化培养基为1/2DR+TDZ 3.30 mg·L^-1+KT 0.70 mg·L^-1,分化率达99.8%以上. 成功建立了天目铁木嫩茎尖离体诱导愈伤组织和芽苗再分化体系,且再生芽苗与野生植株染色体数目相同.     

Hydroformylation by Pt-Sn compounds from N-heterocyclic stannylenes

[(Me(2)Si{NAr}(2))-κ(2)N,N']Sn, reacts with PtCl(2)(L(2)) and [PtCl(μ-Cl)(L)](2) to afford products containing Pt-Sn bonds. In the absence of supporting ligands L, coordination of the stannylene and rearrangement to a structurally unique PtSn(2)N(2)Si metallacycle occurs. The hydroformylation activity of a representative Pt-Sn compound is investigated.     

一维新型阶梯函数光子晶体透射特性

研究了阶梯型折射率n22、n11(阶梯分布高度)的大小、对应的分布厚度、不同入射角以及缺陷模对阶梯函数型光子晶体透射特性的影响.由费马原理给出光在函数光子晶体中的运动方程,再由电磁传播理论给出函数光子晶体的传输矩阵,进一步推导出函数光子晶体的透射率以及电场分布的表达式.研究表明,1)随n22,n11大小或者厚度改变,其禁带变宽;2)随光的入射角增加,其禁带变窄;3)当加入缺陷层时,随着缺陷层介质折射率增加,缺陷模强度减小且位置发生红移;4)在函数光子晶体中,缺陷层前电场分布保持不变,而在缺陷层处以及之后的电场强度都明显增强,这不同于常规光子晶体的电场分布仅在缺陷层处局域增强.     

Models for incomplete nucleophilic attack on a protonated carbonyl group and electron-deficient alkenes: salts and zwitterions from 1-dimethylamino-naphthalene-8-carbaldehyde

The X-ray crystal structures of salts and zwitterionic Knoevenagel products from 1-dimethylamino-naphthalene-8-carbaldehyde show long N-C bonds between peri-groups which provide models for incomplete nucleophilic attack on a protonated carbonyl group and electron-deficient alkenes respectively. For the salts the N-C bonds lie in the range 1.625-1.638 ? with C-OH bonds intermediate in length between single and double bonds, while for the zwitterions the N-C bonds lie in the range 1.612-1.660 ?. The structural assignment of the former is supported by solid state (13)C and (15)N NMR studies on doubly isotopically-labelled material. Several zwitterions were converted to naphtha[1,8-bc]azepines by a mechanism involving the tertiary amino effect.     

Group 14 Metal Terminal Phosphides: Correlating Structure with |J(MP)|

A series of heavier group 14 element, terminal phosphide complexes, M(BDI)(PR(2)) (M = Ge, Sn, Pb; BDI = CH{(CH(3))CN-2,6-iPr(2)C(6)H(3)}(2); R = Ph, Cy, SiMe(3)) have been synthesized. Two different conformations (endo and exo) are observed in the solid-state; the complexes with an endo conformation have a planar coordination geometry at phosphorus (M = Ge, Sn; R = SiMe(3)) whereas the complexes possessing an exo conformation have a pyramidal geometry at phosphorus. Solution-state NMR studies reveal through-space scalar coupling between the tin and the isopropyl groups on the N-aryl moiety of the BDI ligand, with endo and exo exhibiting different J(SnC) values. The magnitudes of the tin-phosphorus and lead-phosphorus coupling constants, |J(SnP)| and |J(PbP)|, differ significantly depending upon the hybridization of the phosphorus atom. For Sn(BDI)(P{SiMe(3)}(2)), |J(SnP)| is the largest reported in the literature, surpassing values attributed to compounds with tin-phosphorus multiple-bonds. Low temperature NMR studies of Pb(BDI)(P{SiMe(3)}(2)) show two species with vastly different |J(PbP)| values, interpreted as belonging to the endo and exo conformations, with sp(2)- and sp(3)-hybridized phosphorus, respectively.     

治疗胆石症蒙药苏斯—12中多种元素的ICP-AES法测定及分析

通过分析治疗胆囊炎、胆石症的蒙药苏斯—12中微量元素含量,探讨蒙药苏斯—12的药效与微量元素含量的关系。应用高压密封微波消解、电感耦合等离子体原子发射光谱法(ICP-AES)对蒙药苏斯—12进行微量元素含量分析。在蒙药的配制及整体研究工作中发现它们含有多种氨基酸和丰富的微量元素,实验结果表明：苏斯—12中含有丰富的微量元素,尤其Ca,Al,Mg,Fe,Sr,Mn,Zn,Cu等元素的含量比较高,而Pb,Cd,As等元素含量相对低,都低于国家限定值。加标回收率在94.63%～106.40% 之间,相对标准偏差RSD≤3.35 %,检出限在≤0.009 μg·L-1。蒙药苏斯—12有效控制和治疗胆囊炎、胆石症,总有效率达91.2%和100%,蒙药苏斯—12中的微量元素与药效之间有密切的关系。     

四川泸定县泥石流灾害成因、特征与防治建议

泸定县地处川西高原与四川盆地的过渡地带,地质环境条件复杂,分布泥石流沟127条,发育密度054条·10km-2。在遥感解译和地面调查基础上,论述了泸定县泥石流灾害成因、发生特征、危害和发展趋势,提出了相关防治建议。(1)成因表现为复杂的断裂构造导致流域内松散物源丰富,较大的相对高差提供了良好势能条件,而汛期集中强降雨则提供了动能条件,且雨量条件中当日雨量与前期有效降雨量之间具有幂函数关系; (2)发生特征表现出典型的空间群发性(包括2005-06-30群发性泥石流、2005-08-11群发性泥石流和2006-07-14群发性泥石流)与时间的夜发性; (3)危害方式主要包括淤埋、冲毁、侵蚀、堵河4种,泥石流已造成74人死亡; (4)发展趋势表现为泥石流沟多处于形成期和发展期(113条,占89%),发生的年际准周期由20a缩短至不足10a,且发生条(次)由4条(次)增加至44条次(2005年); (5)泸定县泥石流防治的突出问题表现为城镇泥石流问题、泥石流堵塞主河问题、风景区泥石流问题与冲沟泥石流问题,建议通过科学规划、风险防御体系构建、土木工程治理、监测预警等措施予以防御。     

Monte Carlo模拟研究抗体-抗原复合物生长的标度行为

通过Monte Carlo模拟方法对抗体-抗原复合物在等活性和非等活性条件下生长的标度行为进行了研究. 模拟所用算法的有效性通过在等活性条件下的模拟结果与解析结果之间的一致性得以证明. 在模拟中, 主要考察了抗体-抗原复合物的数量分布函数、重均聚合度以及特征关联长度在临界点附近的标度行为, 给出相应的标度指数, 并以其检验溶胶-凝胶相变的广义标度律. 研究结果表明, 非等活性对抗体-抗原复合物的生长具有显著影响, 可为临床免疫分析提供相应的理论线索.