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61.
Majumder G Abe K Abe K Adachi I Aihara H Asano Y Aulchenko V Aushev T Bahinipati S Bakich AM Banerjee S Bedny I Bitenc U Bizjak I Blyth S Bondar A Bozek A Bracko M Brodzicka J Browder TE Chang MC Chang P Chao Y Chen A Chen KF Chen WT Cheon BG Chistov R Choi Y Chuvikov A Cole S Dalseno J Danilov M Dash M Drutskoy A Eidelman S Enari Y Fratina S Gabyshev N Gershon T Go A Gokhroo G Golob B Gorisek A Haba J Hara T Hastings NC Hayasaka K Hayashii H Hazumi M Hinz L Hokuue T Hoshi Y Hou S Hou WS 《Physical review letters》2005,95(4):041803
We report evidence for B(0) --> D(0)D(-) and the first observation of the decay modes B(-) --> D(0)D(-) and B(-) --> D(0)D(*-) based on a sample of 152 x 10(6) BB events collected by the Belle detector at KEKB. The branching fractions for B(0) --> D(+) D(-), B--->D(0)D(-), and B--> D(0)D(*-) are found to be (1.91 +/- 0.51 +/- 0.30) x10(-4), (4.83 +/- 0.78 +/- 0.58) x 10(-4), and (4.57 +/- 0.71 +/- 0.56) x 10(-4), respectively. Charge asymmetries in the B---> D(0)D(-) and B(-) --> D(0)D(*-) channels are consistent with zero. 相似文献
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64.
Melissa McHugh John Parnell Ian B. Hutchinson Hannah N. Lerman Howell G.M. Edwards Mark J. Burchell Mike J. Cole Andoni Moral Guillermo Lopez-Reyes Carlos Perez Aurelio Arranz Marco Veneranda José Antonio Manrique Fernando Rull 《Journal of Raman spectroscopy : JRS》2021,52(12):2166-2177
The scientific aims of the ExoMars Raman laser spectrometer (RLS) include identifying biological signatures and evidence of mineralogical processes associated with life. The RLS instrument was optimised to identify carbonaceous material, including reduced carbon. Previous studies suggest that reduced carbon on the Martian surface (perhaps originating from past meteoric bombardment) could provide a feedstock for microbial life. Therefore, its origin, form, and thermal history could greatly inform our understanding of Mars' past habitability. Here, we report on the Raman analysis of a Nakhla meteorite analogue (containing carbonaceous material) that was subjected to shock through projectile impact to simulate the effect of meteorite impact. The characterisation was performed using the RLS Simulator, in an equivalent manner to that planned for ExoMars operations. The spectra obtained verify that the flight-representative system can detect reduced carbon in the basaltic sample, discerning between materials that have experienced different levels of thermal processing due to impact shock levels. Furthermore, carbon signatures acquired from the cratered material show an increase in molecular disorder (and we note that this effect will be more evident at higher levels of thermal maturity). This is likely to result from intense shearing forces, suggesting that shock forces within basaltic material may produce more reactive carbon. This result has implications for potential (past) Martian habitability because impacted, reduced carbon may become more biologically accessible. The data presented suggest the RLS instrument will be able to characterise the contribution of impact shock within the landing site region, enhancing our ability to assess habitability. 相似文献
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Adsorption within pores and on surfaces occurs because of the attractive potential provided by the adsorbent. If the attraction is too weak, however, adsorption does not occur to any significant extent. This paper evaluates the criterion for such adsorption, at zero temperature, of the quantum gases 4He and H2. This criterion is expressed as a relationship between a threshold value of the well-depth (D) of the adsorption potential (on a semi-infinite planar surface) and the hard-core diameter (sigma) of the gas-surface pair potential. Six geometries are considered, of which two result in two-dimensional (2D) adsorbed phases, two result in one-dimensional (1D) phases, and two result in zero-dimensional phases. These are monolayer films on semi-infinite substrates or within a slit pore, linear or axial phases within cylindrical pores (within bulk solids) or cylindrical tubes, and single-particle adsorption within spherical pores or hollow spherical cavities, respectively. The criteria for film adsorption are consistent with analogous criteria for film wetting to occur, evaluated with a simple thermodynamic model. 相似文献
67.
Dr. Jacorien Coetzee Dr. Deborah L. Dodds Prof. Jürgen Klankermayer Sandra Brosinski Prof. Walter Leitner Prof. Alexandra M. Z. Slawin Prof. David J. Cole‐Hamilton 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(33):11039-11050
Hydrogenation of amides in the presence of [Ru(acac)3] (acacH=2,4‐pentanedione), triphos [1,1,1‐tris‐ (diphenylphosphinomethyl)ethane] and methanesulfonic acid (MSA) produces secondary and tertiary amines with selectivities as high as 93 % provided that there is at least one aromatic ring on N. The system is also active for the synthesis of primary amines. In an attempt to probe the role of MSA and the mechanism of the reaction, a range of methanesulfonato complexes has been prepared from [Ru(acac)3], triphos and MSA, or from reactions of [RuX(OAc)(triphos)] (X=H or OAc) or [RuH2(CO)(triphos)] with MSA. Crystallographically characterised complexes include: [Ru(OAc‐κ1O)2(H2O)(triphos)], [Ru(OAc‐κ2O,O′)(CH3SO3‐κ1O)(triphos)], [Ru(CH3SO3‐κ1O)2(H2O)(triphos)] and [Ru2(μ‐CH3SO3)3(triphos)2][CH3SO3], whereas other complexes, such as [Ru(OAc‐κ1O)(OAc‐κ2O,O′)(triphos)], [Ru(CH3SO3‐κ1O)(CH3SO3‐κ2O,O′)(triphos)], H[Ru(CH3SO3‐κ1O)3(triphos)], [RuH(CH3SO3‐κ1O)(CO)(triphos)] and [RuH(CH3SO3‐κ2O,O′)(triphos)] have been characterised spectroscopically. The interactions between these various complexes and their relevance to the catalytic reactions are discussed. 相似文献
68.
A C60-centered dendritic adduct with 12 symmetrically attached pyrene species was synthesized and found to have relatively simple fluorescence emission kinetics, in particular, the mono-exponential decay of the significant pyrene excimer emission. 相似文献
69.
Lakshmi N. Roy Rabindra N. Roy Cole E. Denton Sean R. LeNoue Chandra N. Roy Shahaf Ashkenazi Thomas B. Williams Daniel R. Church Michael S. Fuge Kartik N. Sreepada 《Journal of solution chemistry》2006,35(4):605-624
The values of the second dissociation constant, K
2, and related thermodynamic quantities of the ampholyte bis[(2-hydroxyethyl)amino]acetic acid (BICINE) have been determined at temperatures from 5 to 55 ∘C. The pH values of six equimolal buffer solutions, and four buffer solutions having ionic strengths (I = 0.16 mol⋅kg−1) similar to those in blood plasma, have been evaluated at 12 temperatures from 5 to 55 ∘C using the Bates–Guggenheim convention. The liquid junction potentials (E
j
) between the buffer solutions of BICINE and saturated KCl solution of the calomel electrode at 25 and 37 ∘C have been estimated by measurement with a flowing junction cell. These values of E
j
have been used to ascertain the operational pH values at 25 and 37 ∘C. The pK
2 values at 25 and 37 ∘C are 8.333 and 8.156, respectively. The thermodynamic quantities associated with the second acid dissociation have been calculated from the values of pK
2 as a function of temperature. The zwitterionic buffer BICINE was shown to be useful as a pH standard in the region close to that of blood serum. 相似文献
70.
R. Aryaeinejad E. L. Reber J. K. Jewell J. D. Cole M. W. Drigert 《Journal of Radioanalytical and Nuclear Chemistry》2005,264(1):155-162
Summary In this work, prompt gamma-rays emitted by thermal neutron-induced fission decay using fast coincidence techniques are used to identify both light and heavy fragments and obtain gamma-ray signatures and radiation multiplicity. The measurements were carried out with 235U and 239Pu targets using the Intense Pulsed Neutron Source (IPNS) at Argonne National Laboratory. This study reports the recent results of a preliminary analysis of experimental data collected from the induced fission of 235U and 239Pu. In this paper, we discuss how these results could be used to characterize an unknown sample of fissile material. 相似文献