Respiratory function in singers: Medical assessment, diagnoses, and treatments

A healthy voice depends upon healthy respiration. An understanding of respiratory function is essential in evaluating disorders that affect the voice. This review addresses the assessment of respiratory complaints by history, physical examination, laboratory testing, and endoscopic procedures. Allergy testing and pulmonary function testing are covered in detail. Special problems that confront the professional voice user, such as the need to optimize respiratory function even in mild disease states, exposure to environmental irritants, and the athletic demands of performance, are related specifically to respiratory function. The discussion of diagnosis and treatment of common ailments such as allergic rhinitis and bronchitis is directed toward treatment of the active singer.     

On a physical interpretation of the Schwarzschild metric

A method is devised for giving a physical interpretation to the customary Schwarzschild coordinates in the vicinity of a charged or uncharged isolated mass. The construction is accomplished by introducing systems that are allowed to freely fall in toward the mass from infinity (drift-systems). It is demonstrated that the Schwarzschild spatial coordinates and their increments have a full physical significance in terms of rod and clock measurements performed in the drift-systems. The time coordinate and its increment are not so amenable to treatment and cannot be considered as having been given such physical significance. In the discussion the Schwarzschild metric about an uncharged and charged mass is derived, in part, by heuristic classical arguments employing conservation of energy. The arguments are then shown to be valid by consulting the Field Equations. In the derivation the gravitational singularity (at 2GM/C ²) takes on the significance of being the location at which a drift-system achieves the speed of light relative to a proper system at the same point.     

Tuning the potentials of "extra" electrons in colloidal n-type ZnO nanocrystals via Mg2+ substitution

Colloidal reduced ZnO nanocrystals are potent reductants for one-electron or multielectron redox chemistry, with reduction potentials tunable via the quantum confinement effect. Other methods for tuning the redox potentials of these unusual reagents are desired. Here, we describe synthesis and characterization of a series of colloidal Zn(1-x)Mg(x)O and Zn(0.98-x)Mg(x)Mn(0.02)O nanocrystals in which Mg(2+) substitution is used to tune the nanocrystal reduction potential. The effect of Mg(2+) doping on the band-edge potentials of ZnO was investigated using electronic absorption, photoluminescence, and magnetic circular dichroism spectroscopies. Mg(2+) incorporation widens the ZnO gap by raising the conduction-band potential and lowering the valence-band potential at a ratio of 0.68:0.32. Mg(2+) substitution is far more effective than Zn(2+) removal in raising the conduction-band potential and allows better reductants to be prepared from Zn(1-x)Mg(x)O nanocrystals than can be achieved via quantum confinement of ZnO nanocrystals. The increased conduction-band potentials of Zn(1-x)Mg(x)O nanocrystals compared to ZnO nanocrystals are confirmed by demonstration of spontaneous electron transfer from n-type Zn(1-x)Mg(x)O nanocrystals to smaller (more strongly quantum confined) ZnO nanocrystals.     

Giant Nernst effect and bipolarity in the quasi-one-dimensional metal Li0.9Mo6O17

The Nernst coefficient for the quasi-one-dimensional metal, Li{0.9}Mo{6}O{17}, is found to be among the largest known for metals (ν?500 μV/KT at T～20 K), and is enhanced in a broad range of temperature by orders of magnitude over the value expected from Boltzmann theory for carrier diffusion. A comparatively small Seebeck coefficient implies that Li{0.9}Mo{6}O{17} is bipolar with large, partial Seebeck coefficients of opposite sign. A very large thermomagnetic figure of merit, ZT～0.5, is found at high field in the range T≈35-50 K.