全文获取类型
收费全文 | 357篇 |
免费 | 16篇 |
国内免费 | 1篇 |
专业分类
化学 | 249篇 |
晶体学 | 10篇 |
力学 | 4篇 |
综合类 | 1篇 |
数学 | 16篇 |
物理学 | 94篇 |
出版年
2023年 | 3篇 |
2022年 | 7篇 |
2021年 | 11篇 |
2020年 | 9篇 |
2019年 | 20篇 |
2018年 | 11篇 |
2017年 | 6篇 |
2016年 | 8篇 |
2015年 | 10篇 |
2014年 | 9篇 |
2013年 | 15篇 |
2012年 | 16篇 |
2011年 | 16篇 |
2010年 | 10篇 |
2009年 | 7篇 |
2008年 | 5篇 |
2007年 | 18篇 |
2006年 | 21篇 |
2005年 | 18篇 |
2004年 | 12篇 |
2003年 | 10篇 |
2002年 | 2篇 |
2001年 | 8篇 |
2000年 | 8篇 |
1999年 | 6篇 |
1997年 | 2篇 |
1996年 | 5篇 |
1995年 | 2篇 |
1994年 | 4篇 |
1993年 | 7篇 |
1992年 | 5篇 |
1991年 | 5篇 |
1990年 | 5篇 |
1989年 | 2篇 |
1988年 | 4篇 |
1987年 | 3篇 |
1986年 | 7篇 |
1985年 | 13篇 |
1984年 | 5篇 |
1983年 | 2篇 |
1982年 | 7篇 |
1981年 | 3篇 |
1980年 | 3篇 |
1979年 | 4篇 |
1978年 | 3篇 |
1977年 | 5篇 |
1974年 | 2篇 |
1973年 | 2篇 |
1968年 | 3篇 |
1966年 | 1篇 |
排序方式: 共有374条查询结果,搜索用时 46 毫秒
61.
The present systematic Raman scattering experiments reveal the phason and amplitudon of the charge density wave (CDW) mode in the charge stripes of La(2-x)Sr(x)CuO4. Only about 15% of the electronic density of states condenses into the CDW state. The symmetries of the CDW modes change by the rotation of the stripes at the insulator-metal transition. The energy of the phason is finite at 0.06 < or = x < or = 0.1 and zero at x = 0.035 and 0.115 < or = x < or = 0.135, which suggests that the CDW is commensurate at 0.06 < or = x < or = 0.1 and incommensurate otherwise. The zero-energy phason seems to reduce T(c) at x = 1/8. 相似文献
62.
Takesue I Haruyama J Kobayashi N Chiashi S Maruyama S Sugai T Shinohara H 《Physical review letters》2006,96(5):057001
We report that entirely end-bonded multiwalled carbon nanotubes (MWNTs) can exhibit superconductivity with a transition temperature (T(c)) as high as 12 K, which is approximately 30 times greater than T(c) reported for ropes of single-walled nanotubes. We find that the emergence of this superconductivity is highly sensitive to the junction structures of the Au electrode/MWNTs. This reveals that only MWNTs with optimal numbers of electrically activated shells, which are realized by end bonding, can allow superconductivity due to intershell effects. 相似文献
63.
64.
In this study, we investigate students’ ways of understanding graphing tasks involving quantitative relationships in which time functions as an implicit variable. Through task-based interviews of students ages 14–16 in a summer mathematics program, we observe a variety of ways of understanding, including thematic or visual association, pointwise thinking, and reasoning parametrically about changes in the two variables to be graphed. We argue that, rather than comprising a hierarchy, these ways of understanding complement one another in helping students discover an invariant relationship between two dynamically varying quantities, and develop a graph of the relationship that captures this invariance. From these ways of understanding, we conjecture several mathematical meanings for graphing that may account for students’ behavior when graphing quantitative relationships. 相似文献
65.
[reaction: see text] 3-Iodo allenoates were generated in situ and utilized, for the first time, in the ring opening of oxiranes in a regioselective fashion. This simple one-pot three-component reaction protocol provides easy access to highly functionalized homoallylic alcohols in good yields and moderate to very good (Z/E) selectivity. The two functional groups (ester and halogen) can be further subjected to many synthetic transformations. 相似文献
66.
Kozo Okazaki Masato Hibi Yoshitaka Teraoka Takuya Nakata Kouichi Yonetani Shunji Sugai 《Journal of Physics and Chemistry of Solids》2008,69(12):3078-3081
We have investigated electron-boson coupling in the optical conductivity of high-Tc superconductors through the optical self-energy. The real part of the self-energy (ReΣop(ω)) of YBa2Cu3Oy (YBCO) shows a characteristic doping dependence. In the optimally doped YBCO, ReΣop(ω) has a single peak around 65 meV, which corresponds to the kink structure of the band dispersion. On the other hand, in the under-doped YBCO, the peak structure of ReΣop(ω) splits into two parts. To evaluate contribution from the phonons in electron-boson coupling, we have measured oxygen-isotope effects by substituting 16O→18O for the optimally doped and under-doped YBCO. 相似文献
67.
68.
Kazuaki Kuwata Masashi SuzukiYoshikazu Inami Kengo HanayaTakeshi Sugai Mitsuru Shoji 《Tetrahedron letters》2014
A stereoselective synthesis of scyphostatin hydrophilic moiety was accomplished. Substrate- and reagent-controlled dihydroxylation of tri- and monosubstituted alkenes afforded desired diols, respectively. Chemo- and stereoselective allylation of α-(methoxycarbonyl)cyclohexanone provided allylcyclohexanol. Oxidative cleavage of glycol and subsequent β-elimination of siloxycyclohexanone furnished the desired epoxycyclohexenone. 相似文献
69.
Dr. Benjamin A. Chalmers Hui Xing Sevan Houston Dr. Charlotte Clark Dr. Sussan Ghassabian Dr. Andy Kuo Benjamin Cao Andrea Reitsma Cody‐Ellen P. Murray Dr. Jeanette E. Stok Dr. Glen M. Boyle Carly J. Pierce Stuart W. Littler Prof. David A. Winkler Prof. Paul V. Bernhardt Dr. Cielo Pasay Prof. James J. De Voss Prof. James McCarthy Prof. Peter G. Parsons Prof. Gimme H. Walter Prof. Maree T. Smith Prof. Helen M. Cooper Prof. Susan K. Nilsson Dr. John Tsanaktsidis Dr. G. Paul Savage Prof. Craig M. Williams 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2018,130(28):8491-8491
70.
Utilization of biocatalysts with high accessibility and availability, which have recently been applied in the preparation of enantiomerically enriched starting materials and synthetic intermediates for natural product syntheses (mainly 2013–2017) are summarized in this review. The main contents are as follows: 1) recruitment of biocatalysts for the transformation of organic compounds; 2) special precautions for preparative-scale biocatalytic synthetic experiments; 3) asymmetric reduction of carbonyl substrates; 4) kinetic resolution of alcohol and carboxylate enantiomers; 5) desymmetrization of multifunctional alcohol and carboxylate substrates; and 6) recognition of remote and non-central chirality. 相似文献