Radiation defects in nano-structured materials

We investigated defect formation within nanostructured materials using a transmission electron microscope (TEM) and ion accelerators. Controlling diffusion coefficient of the defects we have first observed changes in pattern of defect clusters, namely, the diffusion-limited reaction of defects in nanocrystals. Received 30 November 2000     

Controllable growth and characterization of isolated single-walled carbon nanotubes catalyzed by Co particles

Discrete Co catalytic nanoparticles with small diameters are obtained by pulsed vacuum arc evaporation on Si/SiO₂ substrates, which are used for the growth of isolated single-walled carbon nanotubes (SWNTs) by an ethanol chemical vapor deposition approach (CVD). The distributions of catalytic nanoparticles change with the number of arc pulses, which allows control of the nanotubes formation. We find that an increase of ethanol pressure during CVD growth can change SWNTs from isolated ones into bundles. A new growth mechanism which combines a tip and base model for SWNT growth has been tentatively proposed. It is suggested that the small size catalytic particles prepared by pulsed arc evaporation have a potential advantage for small diameter SWNT growth. PACS 78.67.Ch; 78.67.Bf; 78.67.-n; 81.07.De; 61.46.-w     

Soft Ionization of Saturated Hydrocarbons, Alcohols and Nonpolar Compounds by Negative-Ion Direct Analysis in Real-Time Mass Spectrometry

Large polarizable n-alkanes (approximately C18 and larger), alcohols, and other nonpolar compounds can be detected as negative ions when sample solutions are injected directly into the sampling orifice of the atmospheric pressure interface of the time-of-flight mass spectrometer with the direct analysis in real time (DART) ion source operating in negative-ion mode. The mass spectra are dominated by peaks corresponding to [M + O₂]￣^?. No fragmentation is observed, making this a very soft ionization technique for samples that are otherwise difficult to analyze by DART. Detection limits for cholesterol were determined to be in the low nanogram range.

金属纳米粒子再分散法测定二氧化铈稳定的单原子的位点数

单原子催化剂由于能最大限度地利用贵金属以及其独特的催化性能而引起了人们的兴趣.基于其表面原子性质,CeO2是稳定单金属原子最常用的载体之一.一旦金属含量超过其负载的载体容量,就会形成金属纳米粒子,因而许多单原子催化剂的金属含量受限.目前,还没有直接的测量方法来确定载体稳定单个原子的容量.本文开发了一种基于纳米颗粒的技术,即通过将Ru纳米颗粒重新分散成单个原子,并利用Ru单原子和纳米颗粒在CO2加氢反应中的不同催化性能,从而确定该容量.该方法避免了湿浸初期反离子对金属负载的影响,最终可应用于多种不同的金属.结果表明,该技术可跟踪氧空位浓度和表面氧含量的变化趋势,有望成为一种定量测定载体单原子稳定容量的新方法.     

Optical irradiation method for fiber coupler fabrications

An optical irradiation method for high-speed fiber coupler fabrications without contamination is proposed. In optical fiber taper fabrications we found an interesting effect that fiber elongation is self-arrested although laser irradiation is continued. This is a typical effect in the optical irradiation method, but is not seen in the flame method or the thermal heating method. The “self-controlled fiber taper shape effect” is theoretically explained by considering thermal energy flows, and optical fiber couplers are fabricated using this effect. From our experiments, we show that optical fiber coupler fabrications at high-speed without contamination are possible using the optical irradiation method.     

Singlet and triplet excitation management in a bichromophoric near-infrared-phosphorescent BODIPY-benzoporphyrin platinum complex

Multichromophoric arrays provide one strategy for assembling molecules with intense absorptions across the visible spectrum but are generally focused on systems that efficiently produce and manipulate singlet excitations and therefore are burdened by the restrictions of (a) unidirectional energy transfer and (b) limited tunability of the lowest molecular excited state. In contrast, we present here a multichromophoric array based on four boron dipyrrins (BODIPY) bound to a platinum benzoporphyrin scaffold that exhibits intense panchromatic absorption and efficiently generates triplets. The spectral complementarity of the BODIPY and porphryin units allows the direct observation of fast bidirectional singlet and triplet energy transfer processes (k(ST)((1)BDP→(1)Por) = 7.8 × 10(11) s(-1), k(TT)((3)Por→(3)BDP) = 1.0 × 10(10) s(-1), k(TT)((3)BDP→(3)Por) = 1.6 × 10(10) s(-1)), leading to a long-lived equilibrated [(3)BDP][Por]?[BDP][(3)Por] state. This equilibrated state contains approximately isoenergetic porphyrin and BODIPY triplets and exhibits efficient near-infrared phosphorescence (λ(em) = 772 nm, Φ = 0.26). Taken together, these studies show that appropriately designed triplet-utilizing arrays may overcome fundamental limitations typically associated with core-shell chromophores by tunable redistribution of energy from the core back onto the antennae.     

Easton’s theorem in the presence of Woodin cardinals

Under the assumption that δ is a Woodin cardinal and GCH holds, I show that if F is any class function from the regular cardinals to the cardinals such that (1) ${\kappa < {\rm cf}(F(\kappa))}$ , (2) ${\kappa < \lambda}$ implies ${F(\kappa) \leq F(\lambda)}$ , and (3) δ is closed under F, then there is a cofinality-preserving forcing extension in which 2 ^γ = F(γ) for each regular cardinal γ < δ, and in which δ remains Woodin. Unlike the analogous results for supercompact cardinals [Menas in Trans Am Math Soc 223:61–91, (1976)] and strong cardinals [Friedman and Honzik in Ann Pure Appl Logic 154(3):191–208, (2008)], there is no requirement that the function F be locally definable. I deduce a global version of the above result: Assuming GCH, if F is a function satisfying (1) and (2) above, and C is a class of Woodin cardinals, each of which is closed under F, then there is a cofinality-preserving forcing extension in which 2 ^γ = F(γ) for all regular cardinals γ and each cardinal in C remains Woodin.     

Relationship between side-chain branching and stoichiometry in β(3)-peptide bundles

The stability and stoichiometry of β(3)-peptide bundles is influenced by side-chain identity. β(3)-peptides containing β(3)-homoleucine on one helical face assemble into octamers, whereas those containing β(3)-homovaline form tetramers. From a structural perspective, the side chains of β(3)-homoleucine and β(3)-homovaline differ in terms of both side-chain length and γ-carbon branching. To evaluate the extent to which these two parameters control β(3)-peptide bundle stoichiometry, we synthesized the β(3)-peptide Acid-3Y, which contains β(3)-homoisoleucine in place of β(3)-homoleucine or β(3)-homovaline. Acid-3Y assembles into a stable tetramer whose stability resembles that of the previously characterized Acid-VY tetramer. These results suggest that β(3)-peptide bundle stoichiometry is dominated by the presence or absence of γ-carbon branching on core side chains.