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191.
The 5-hexyl (I) and the 5-heptyl (II) analogs of 2,4-diamino-6-methylpyrimidine both crystallize in the space groupP21/c withZ=4. Unit cell parameters of I are C11H20N4·H2O,a=17.204(3),b=4.609(9),c=16.765(2)Å,= 91.53(2)°; those of II are C12H23N4
+·C2H5SO3
–,a=12.489(1),b=16.702(2),c=8.9558(7)Å,=99.208(8)°. The molecular packing of I contains one water, while II forms a salt with ethanesulfonic acid. The alkyl chain of I adopts an alltrans conformation; in contrast, II has onegauche orientation between carbons 2 and 3 of heptyl. These are the first structural data on two alkyl lipophilic antifolates with antineoplastic activity. 相似文献
192.
193.
194.
M. Kato H. Sugai T. Hayashi M. Nishi M. Tanase T. Matsuzaki K. Ishida K. Nagamine 《Hyperfine Interactions》2001,138(1-4):397-401
JAERI has been developing an improved compact tritium gas enrichment/recycling system for efficient research and development
work using tritium. A proton conductor has been investigated and a compact enrichment system was designed with a hydrogen
pump employing a proton conductor. The pump can separate hydrogen directly from the helium gas carrier and minimize the size
of the system. A prototype hydrogen pump was developed and its performance test was started.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
195.
Takahiro Yamazaki Atsuhito Kuboki Hiromichi Ohta Thomas M. Mitzel Leo A. Paquette Takeshi Sugai 《合成通讯》2013,43(16):3061-3072
(R)-4,4-Dimethoxy-2-butanol was prepared with the action of Yamadazyma farinosa IFO 10896 on 4,4-dimethoxy-2-butanone, and subsequently converted to (2R,4R)- and (2R,4S)-isomers of 6-hepten-2,4-diol by the treatment with allyl bromide and indium in aqueous solution. 相似文献
196.
197.
Matthew E. Curtis Patrick R. Jones O. David Sparkman Robert B. Cody 《Journal of the American Society for Mass Spectrometry》2009,20(11):2082-2086
Based on the concern about the presence of sulfur materials being in drywall (wallboard), a quick and reliable test to confirm
the presence or absence of these materials using direct analysis in real time (DART) mass spectrometry in conjunction with
an accurate-mass time-of-flight (TOF) mass spectrometer has been developed and is described here. 相似文献
198.
199.
H. Ohtsuka K. Hojou H. Maeta H. Otsu H. Sugai H. Yamamoto 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2001,16(1):309-311
We investigated defect formation within nanostructured materials using a transmission electron microscope (TEM) and ion accelerators.
Controlling diffusion coefficient of the defects we have first observed changes in pattern of defect clusters, namely, the
diffusion-limited reaction of defects in nanocrystals.
Received 30 November 2000 相似文献
200.
Y. Zhao H. Nakano H. Murakami T. Sugai H. Shinohara Y. Saito 《Applied Physics A: Materials Science & Processing》2006,85(2):103-107
Discrete Co catalytic nanoparticles with small diameters are obtained by pulsed vacuum arc evaporation on Si/SiO2 substrates, which are used for the growth of isolated single-walled carbon nanotubes (SWNTs) by an ethanol chemical vapor deposition approach (CVD). The distributions of catalytic nanoparticles change with the number of arc pulses, which allows control of the nanotubes formation. We find that an increase of ethanol pressure during CVD growth can change SWNTs from isolated ones into bundles. A new growth mechanism which combines a tip and base model for SWNT growth has been tentatively proposed. It is suggested that the small size catalytic particles prepared by pulsed arc evaporation have a potential advantage for small diameter SWNT growth. PACS 78.67.Ch; 78.67.Bf; 78.67.-n; 81.07.De; 61.46.-w 相似文献