Postfunctionalization of poly(propargyl methacrylate) using copper catalyzed 1,3‐dipolar Huisgen cycloaddition: An easy route to electro‐optic materials

A one‐pot synthetic route based on copper‐catalyzed Huisgen reaction has been developed to functionalize a methacrylate propargylic polymer with azido‐substituted moieties. This procedure was used for the preparation of electro‐optic materials containing well‐known Disperse Red One (DR1) chromophores along with bulky adamantyl moieties (Adam). The postfunctionalization of the propargylic polymer was successfully achieved using different molar ratios of DR1/Adam. These novel polymers exhibit high glass transition temperature owing to the rigid structure of adamantyl units. Moreover, the second harmonic generation measurements demonstrated the effectiveness of adamantyl groups to act as insulating shield limiting thus the electrostatic interactions between chromophores. Indeed, higher optimal chromophore concentration (50 mol %) than in conventional DR1‐containing polymers (30 mol %) allowed us to increase the d₃₃ coefficient up to 92 pm/V. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 5652–5660, 2009     

Measurement of the η production in proton-proton collisions with the COSY time-of-flight spectrometer

The reaction pp → ppη was measured at excess energies of 15 and 41 MeV at an external target of the Jülich Cooler Synchrotron COSY with the time-of-flight spectrometer. About 25000 events were measured for the excess energy of 15 MeV and about 8000 for 41 MeV. Both protons of the process ppη were detected with an acceptance of nearly 100% and the η was reconstructed by the missing-mass technique. For both excess energies the angular distributions are found to be nearly isotropic. In the invariant-mass distributions strong deviations from the pure phase space distributions are seen. Received: 24 May 2002 / Accepted: 20 September 2002 / Published online: 17 January 2003 RID="a" ID="a"e-mail: e.roderburg@fz-juelich.de Communicated by M. Gar?on     

Mixing of atmospheric gas concentrations

Atmospheric gas concentrations were measured at 1 s intervals in the upper troposphere during a flight through and near the anvil of a storm. The observed very high correlations between the concentrations of CO and CH4 are interpreted as arising from the mixing of two distinct air masses with differing concentrations of each species, and is due to the nearly identical diffusivities of CO and CH4 in air. We find that the correlations depend on the period over which each concentration measurement was made. Correlations in measurements made over short periods decay with time, while correlations over larger scales remain high. We interpret this using a simple mixing model.     

Multipole moments and spin-dependent sum rules and their applications to f72 and s-d shell nuclei

Matrix elements of multipole operators, defined separately for neutrons and protons, are related to spin-dependent sums of spectroscopic factors. A clarification of their relation to the matrix elements of single-particle operators enables the overlap representation to be formally extended to a stripping form for J ≠ 0 operators. Multipole moments obtained from $\text{f}{}_{\mathrm{<mtext>7</mtext><mtext>2</mtext>}}$ transfer data are found to be dominated by the quadrupole moments when the final nucleus is odd-odd.A previously found (2J + 1) rule for spectroscopic sums, which arises when the odd-J multipole moments vanish, is shown to lead to approximate sum rules which apply separately to stripping and pickup data. The sum rules are generally well satisfied for transfers leading to odd-odd nuclei in the s-d shell.     

Elastic and inelastic scattering of polarized protons from even n=82 nuclei near isobaric analog resonances

Excitation curves for the elastic and the inelastic scattering of polarized protons on the target nuclei ¹³⁸Ba, ¹⁴⁰Ce, ¹⁴²Nd and ¹⁴⁴Sm have been measured in the energy region of prominent isobaric analog resonances. A detailed analysis of the data is presented. Definite J^π assignments are given for a number of parent analog states. Spectroscopic factors and amplitudes for configurations with the core in the ground state or in the 2₁⁺ excited state are derived from the elastic and inelastic proton decay amplitudes. They show consistency with sum rules including orthogonality conditions. Different methods for the-calculation of single particle decay widths have been applied. The qualitative agreement with present unified model calculations is remarkable; an overestimattion of the weak coupling structure, however, becomes apparent.     

Hydrogen and deuterium total neutron cross sections in the MeV region

Total neutron cross sections, using a continuous-energy source of neutrons, were measured for hydrogen and deuterium. The neutron energy range covered was from less than 1 MeV, to about 30 MeV. No structure is observed for either isotope. The precision of the cross-section magnitudes appears to be within 1 % over much of the measured energy interval.     

(C_k \oplus G,k,\lambda ) Difference Families

Let G be an additive group and C _k be the additive group of the ring Z _k of residues modulo k. If there exist a (G, k, ) difference family and a (G, k, ) perfect Mendelsohn difference family, then there also exists a difference family. If the (G, k, ) difference family and the (G, k, ) perfect Mendelsohn difference family are further compatible, then the resultant difference family is elementary resolvable. By first constructing several series of perfect Mendelsohn difference families, many difference families and elementary resolvable difference families are thus obtained.     

Acoustic streaming induced by ultrasonic flexural vibrations and associated enhancement of convective heat transfer

Acoustic streaming induced by ultrasonic flexural vibrations and the associated convection enhancement are investigated. Acoustic streaming pattern, streaming velocity, and associated heat transfer characteristics are experimentally observed. Moreover, analytical analysis based on Nyborg's formulation is performed along with computational fluid dynamics (CFD) simulation using a numerical solver CFX 4.3. Two distinctive acoustic streaming patterns in half-wavelength of the flexural vibrations are observed, which agree well with the theory. However, acoustic streaming velocities obtained from CFD simulation, based on the incompressible flow assumption, exceed the theoretically estimated velocity by a factor ranging from 10 to 100, depending upon the location along the beam. Both CFD simulation and analytical analysis reveal that the acoustic streaming velocity is proportional to the square of the vibration amplitude and the wavelength of the vibrating beam that decreases with the excitation frequency. It is observed that the streaming velocity decreases with the excitation frequency. Also, with an open-ended channel, a substantial increase in streaming velocity is observed from CFD simulations. Using acoustic streaming, a temperature drop of 40 degrees C with a vibration amplitude of 25 microm at 28.4 kHz is experimentally achieved.