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Chemical and electronic properties of scrapecleaned YBa2Cu3O7–(YBCO) ceramics, which were also annealed in vacuum or exposed to H atoms or O2 molecules, were studied at room temperature by applying Auger electron (AES) and low-energy electron energy-loss spectroscopy (LEELS). Scanning electron micrographs showed such scraped surfaces to consist mainly of small, fractured YBCO crystallites, i.e. of clean YBCO surfaces. With only one exception, all low-energy AES lines were found to be shifted in energy compared to data recorded with surfaces of metallic Cu and Y. The analysis of the high-energy AES lines indicated the existence of non-stoichiometric material in grain boundaries. At least 25 different LEELS features were recorded. The 24.9-eV energy loss, which is due to the excitation of bulk valence-electron plasmons, indicates an enhanced oxygen deficit s 0.8 at scrape-cleaned YBCO surfaces. Annealing of scraped YBCO samples at approximately 700 K in vacuum and also their exposure to hydrogen atoms resulted in an additional oxygen depletion within a few atomic layers near to the surfaces. These oxygen deficiencies were found to increase the intensity ratios of low-and high-energy AES lines of Cu, Ba, and Y and to intensify the energy-loss peak at 4.4 eV which has been attributed to O–Cu–O dumbbells. 相似文献
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Birck C Cha JY Cross J Schulze-Briese C Meroueh SO Schlegel HB Mobashery S Samama JP 《Journal of the American Chemical Society》2004,126(43):13945-13947
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Clemens D Vosberg V Hobbs W Breuer U Quadakkers WJ Nickel H 《Analytical and bioanalytical chemistry》1996,355(5-6):703-706
The effect of Si addition on the oxidation behaviour of NiCrAlY alloys in the temperature range 950 bis 1100 degrees C has been investigated. During isothermal oxidation oxide growth rates were practically independent of the Si-content. However during cyclic oxidation Si additions were beneficial. Si additions of 1-2(m)/(0) appeared to shift the onset for spallation to longer times. It was found that Si stabilizes the beta-phase and probably it suppresses the formation of metastable Al(2)O(3) modifications. 相似文献
17.
Hofmann C Boll R Heitmann B Hauser G Dürr C Frerich A Weitnauer G Glaser SJ Bechthold A 《Chemistry & biology》2005,12(10):1137-1143
The oligosaccharide antibiotic avilamycin A is composed of a polyketide-derived dichloroisoeverninic acid moiety attached to a heptasaccharide chain consisting of six hexoses and one unusual pentose moiety. We describe the generation of mutant strains of the avilamycin producer defective in different sugar biosynthetic genes. Inactivation of two genes (aviD and aviE2) resulted in the breakdown of the avilamycin biosynthesis. In contrast, avilamycin production was not influenced in an aviP mutant. Inactivation of aviGT4 resulted in a mutant that accumulated a novel avilamycin derivative lacking the terminal eurekanate residue. Finally, AviE2 was expressed in Escherichia coli and the gene product was characterized biochemically. AviE2 was shown to convert UDP-D-glucuronic acid to UDP-D-xylose, indicating that the pentose residue of avilamycin A is derived from D-glucose and not from D-ribose. Here we report a UDP-D-glucuronic acid decarboxylase in actinomycetes. 相似文献
18.
Miral Dizdaroglu Dieter Henneberg Clemens Von Sonntag 《Journal of mass spectrometry : JMS》1974,8(1):335-345
Aldoses, ketoses, deoxy-aldoses, deoxy-keto-aldoses, lactones, deoxy-lactones and other similar compounds are readily reduced by NaBD4 to the corresponding polyalcohol. Their trimethylsilyl ethers show characteristic mass spectra which allow firm assignments of the position of deuteration and hence of the nature of the starting sugar compound. The g.c./m.s. coupling technique even allows trace analysis since full information can be derived from the most intense fragments of the mass spectra. 相似文献
19.
T. L. Clemens L. J. Fraher J. L. H. O'Riordan C. J. Little A. Dale 《Chromatographia》1980,13(3):141-144
Summary A simple, reproducible method for the biological synthesis of tritiated 24,25-dihydroxycholecalciferol, 25,26-dihydroxycholecalciferol and 1,25-dihydroxycholecalciferol is described. Kidney homogenates from both vitamin D deficient and replete chicks were usedin vitro to generate these dihydroxylated metabolites using 25 (23,24-3H) hydroxycholecalciferol as the substrate. Tritiated products were purified by Sephadex LH 20 chromatography followed by high-performance liquid chromatography; the identity of each metabolite was established by chromatography with authentic crystalline preparations.Presented at the Symposium organised by the Chromatography Discussion Group, held at Hatfield Lodge on 29 November 1979. 相似文献
20.
Reaction of trimethylsilyl-protected cytosine with methyl iodide afforded N1-methylated product. Subsequent treatment with ethanol resulted in cleavage of the protection group forming [(MeCyt)2H]I (4). Identity of was confirmed by microanalysis, mass spectrometry, 1H and 13C NMR spectroscopy and by single-crystal X-ray diffraction analysis. Crystals of consist of dimeric [(MeCyt)2H]+ cations and I- anions. These ions are arranged in the crystal such that there is a strong base stacking (mean stacking distance 3,467 angstroms) and, furthermore, pi interactions between I- and cytosine rings (mean distance 3,737 angstroms). The dimeric [(MeCyt)2H]+ cations are centrosymmetric having three strong hydrogen bonds, namely two terminal N4-H...O' ones (N4...O' 2.815(4) angstroms) and a central N3-H...N3' (N3...N3' 2.813(4) angstroms) one. Quantum chemical calculations on the DFT level of theory show that the gas phase structure of the dimeric cation exhibits two different terminal N-HO hydrogen bonds, a stronger (N4...O' 2.722 angstroms) and a weaker one (N4'...O 2.960 angstroms). The central N3-HN3[prime or minute] hydrogen bond (N3...N3' 2.852 angstroms) was characterized to have an unsymmetrically located proton and a typical double minimum potential with a very low activation barrier. The interaction energy between [(MeCyt)H]+ and MeCyt yielding [(MeCyt)2H]+ was calculated to be -42.4 kcal mol(-1)(ZPE and BSSE corrected). Comparison with the interaction energy (calculated on the same level of the theory) between cytosine and guanine yielding the triply hydrogen-bonded Watson-Crick dimer (-24.2 kcal mol(-1)) revealed a much higher stability of the hydrogen bonds in [(MeCyt)2H]+. 相似文献