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931.
Near-wall data for the strongly perturbed flow in a neutrally stable boundary layer encountering a steep, smooth, two-dimensional
hill are presented. Observations were made on the centerplane of a water channel at thirteen stations relative to the hill
by laser Doppler anemometry. The large reverse flow region that is formed on the lee of the hill was particularly scrutinized
through seven measuring stations. Results are presented for the mean and turbulent properties of the flow. Wall shear stress
was evaluated through fitting procedures that resorted to the near wall behavior of the velocity profile. Logarithmic fits
as well as predictions through the Reynolds stress profiles are also presented. 相似文献
932.
W. Silva 《Nonlinear dynamics》2005,39(1-2):25-62
The identification of nonlinear aeroelastic systems based on the Volterra theory of nonlinear systems is presented. Recent applications of the theory to problems in computational and experimental aeroelasticity are reviewed. Computational results include the development of computationally efficient reduced-order models (ROMs) using an Euler/Navier–Stokes flow solver and the analytical derivation of Volterra kernels for a nonlinear aeroelastic system. Experimental results include the identification of aerodynamic impulse responses, the application of higher-order spectra (HOS) to wind-tunnel flutter data, and the identification of nonlinear aeroelastic phenomena from flight flutter test data of the active aeroelastic wing (AAW) aircraft. 相似文献
933.
The non-linear differential equations of motion, and boundary conditions, for Euler-Bernoulli beams able to experience flexure along two principal directions (and, thus, flexure in any direction in space), torsion and extension are formulated. The beam's material is assumed to be Hookean but its properties may vary along its span. The nonlinearities present in the differential equations include contributions from the curvature expression and from inertia terms. A set of differential equations with polynomial nonlinearities to cubic order, suitable for a perturbation analysis of the motion, is also developed and the validity of the inextensional approximation is assessed. The equations developed here reduce to those for an inextensional beam. In Part II of this paper, a specific example of application is analyzed and the results obtained are compared with those available in the literature where several non-linear terms have been neglected a priori. 相似文献
934.
M. R. M. Crespo da Silva 《International Journal of Solids and Structures》1978,14(12):987-997
The non-linear response of a column with a follower force (Beck's column) subjected to a distributed periodic lateral excitation, or to a support excitation, is determined. An analytical solution for the response amplitude in terms of the loading and system parameters is obtained by a perturbation analysis of the differential equations of motion. Non-linear inertia and non-linear curvature terms are taken into account in the formulation of the differential equations. 相似文献
935.
José A. Ferreira Gonçalo Pena 《Numerical Methods for Partial Differential Equations》2015,31(5):1589-1602
Diffusion processes are usually simulated using the classical diffusion equation. In certain scenarios, such equation induces anomalous behavior and consequently several improvements were introduced in the literature to overcome them. One of the most popular was the replacement of the diffusion equation by an integro‐differential equation. Such equation can be established considering a modification of Fick's mass flux where a delay in time is introduced. In this article, we consider mathematical models for diffusion processes that take into account a memory effect in time and space. © 2015 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 31: 1589–1602, 2015 相似文献
936.
Lívia Riberti Rodrigues Diogo Noin de Oliveira Mônica Siqueira Ferreira Rodrigo Ramos Catharino 《Analytica chimica acta》2014
The analysis of impurities and degradation products in pharmaceutical preparations are usually performed by chromatographic techniques such as high-performance liquid chromatography (HPLC). This approach demands extensive analysis time, mostly due to extraction and separation phases. These steps must be carried out in samples in order to adapt them to the requirements of the analytical method of choice. In the present contribution, matrix-assisted laser desorption/ionization mass spectrometry imaging (MALDI-MSI) was employed to quantify an important degradation product in atorvastatin calcium 80 mg tablets: the atorvastatin lactone. Through the standard of the impurity, it was possible to perform quantitative analysis directly on the drug tablet, using a quick and novel approach, suitable for quality control processes in the pharmaceutical industry. 相似文献
937.
Thayana da C. Alves Mariele R. S. Gonçalves Francyne C. S. Correia Virgínia C. da Silva Paulo T. de Sousa Jr. Mário G. de Carvalho Raimundo Braz‐Filho Evandro L. Dall'Oglio 《Helvetica chimica acta》2014,97(11):1469-1474
From the hexane and MeOH extracts of Annona coriacea Mart . (Annonaceae) seeds, two novel acetogenins, coriapentocins A and B ( 1 and 2 , resp.) were isolated. The known acetogenin bullacin ( 3 ) was also isolated from the hexane extract. The structures of compounds 1 – 3 were elucidated by NMR and MS analysis, and relative configurations were established by comparison with literature data. 相似文献
938.
Hélio A. Stefani Mônica F.Z.J. AmaralFlávia Manarin Rômulo A. AndoNathália C.S. Silva Eusebio Juaristi 《Tetrahedron letters》2011,52(51):6883-6886
A series of 2-(S)-isopropyl-pyrimidinones functionalized at C5 with triazole rings, in which the substituents are found at N-1′ of the triazole ring, were synthesized. Through the azide-acetylene cycloaddition reaction, using CuI as a copper source and ultrasonic waves as an energy source it was possible to obtain products with yields ranging from 79% to 89% within 5 min or less. A preliminary study to gain further insight into the reaction was performed using in situ ReactIR technology. 相似文献
939.
This paper describes the automation of a fully electrochemical system for preconcentration, cleanup, separation and detection, comprising the hyphenation of a thin layer electrochemical flow cell with CE coupled with contactless conductivity detection (CE-C?D). Traces of heavy metal ions were extracted from the pulsed-flowing sample and accumulated on a glassy carbon working electrode by electroreduction for some minutes. Anodic stripping of the accumulated metals was synchronized with hydrodynamic injection into the capillary. The effect of the angle of the slant polished tip of the CE capillary and its orientation against the working electrode in the electrochemical preconcentration (EPC) flow cell and of the accumulation time were studied, aiming at maximum CE-C?D signal enhancement. After 6 min of EPC, enhancement factors close to 50 times were obtained for thallium, lead, cadmium and copper ions, and about 16 for zinc ions. Limits of detection below 25 nmol/L were estimated for all target analytes but zinc. A second separation dimension was added to the CE separation capabilities by staircase scanning of the potentiostatic deposition and/or stripping potentials of metal ions, as implemented with the EPC-CE-C?D flow system. A matrix exchange between the deposition and stripping steps, highly valuable for sample cleanup, can be straightforwardly programmed with the multi-pumping flow management system. The automated simultaneous determination of the traces of five accumulable heavy metals together with four non-accumulated alkaline and alkaline earth metals in a single run was demonstrated, to highlight the potentiality of the system. 相似文献
940.
Clovis Piovezan Fábio da Silva Lisboa Fábio Souza Nunes Sueli Maria Drechsel 《Transition Metal Chemistry》2011,36(1):79-85
We report the reactivity of three binuclear non-heme Fe(III) compounds, namely [Fe2(bbppnol)(μ-AcO)(H2O)2](ClO4)2 (1), [Fe2(bbppnol)(μ-AcO)2](PF6) (2), and [Fe2(bbppnol)(μ-OH)(Cl)2]·6H2O (3), where H3bbppnol = N,N′-bis(2-hydroxybenzyl)-N,N′-bis(2-methylpyridyl)–1,3-propanediamine-2-ol, toward the hydrolysis of bis-(2,4-dinitrophenyl)phosphate as models for phosphoesterase
activity. The synthesis and characterization of the new complexes 1 and 3 was also described. The reactivity differences observed for these complexes show that the accessibility of the substrate
to the reaction site is one of the key steps that determinate the hydrolysis efficiency. 相似文献