全文获取类型
收费全文 | 4085篇 |
免费 | 115篇 |
国内免费 | 22篇 |
专业分类
化学 | 2537篇 |
晶体学 | 29篇 |
力学 | 122篇 |
数学 | 602篇 |
物理学 | 932篇 |
出版年
2023年 | 22篇 |
2022年 | 45篇 |
2021年 | 82篇 |
2020年 | 66篇 |
2019年 | 54篇 |
2018年 | 52篇 |
2017年 | 49篇 |
2016年 | 129篇 |
2015年 | 113篇 |
2014年 | 102篇 |
2013年 | 221篇 |
2012年 | 225篇 |
2011年 | 260篇 |
2010年 | 161篇 |
2009年 | 165篇 |
2008年 | 239篇 |
2007年 | 229篇 |
2006年 | 239篇 |
2005年 | 221篇 |
2004年 | 200篇 |
2003年 | 159篇 |
2002年 | 146篇 |
2001年 | 80篇 |
2000年 | 67篇 |
1999年 | 52篇 |
1998年 | 46篇 |
1997年 | 41篇 |
1996年 | 54篇 |
1995年 | 33篇 |
1994年 | 34篇 |
1993年 | 33篇 |
1992年 | 23篇 |
1991年 | 17篇 |
1990年 | 31篇 |
1989年 | 19篇 |
1988年 | 21篇 |
1987年 | 13篇 |
1986年 | 23篇 |
1985年 | 52篇 |
1984年 | 47篇 |
1983年 | 26篇 |
1982年 | 38篇 |
1981年 | 29篇 |
1980年 | 37篇 |
1979年 | 40篇 |
1978年 | 15篇 |
1977年 | 22篇 |
1976年 | 20篇 |
1974年 | 14篇 |
1973年 | 16篇 |
排序方式: 共有4222条查询结果,搜索用时 15 毫秒
991.
992.
993.
Cinzia Forni Massimiliano Rossi Ilaria Borromeo Giordana Feriotto Giovambattista Platamone Claudio Tabolacci Carlo Mischiati Simone Beninati 《Molecules (Basel, Switzerland)》2021,26(12)
Nutraceuticals are biologically active molecules present in foods; they can have beneficial effects on health, but they are not available in large enough quantities to perform this function. Plant metabolites, such as polyphenols, are widely diffused in the plant kingdom, where they play fundamental roles in plant development and interactions with the environment. Among these, flavonoids are of particular interest as they have significant effects on human health. In vitro and/or in vivo studies described flavonoids as essential nutrients for preventing several diseases. They display broad and promising bioactivities to fight cancer, inflammation, bacterial infections, as well as to reduce the severity of neurodegenerative and cardiovascular diseases or diabetes. Therefore, it is not surprising that interest in flavonoids has sharply increased in recent years. More than 23,000 scientific publications on flavonoids have described the potential anticancer activity of these natural molecules in the last decade. Studies, in vitro and in vivo, show that flavonoids exhibit anticancer properties, and many epidemiological studies confirm that dietary intake of flavonoids leads to a reduced risk of cancer. This review provides a glimpse of the mechanisms of action of flavonoids on cancer cells. 相似文献
994.
Armando Bazzani Carlo Benedetti Sandro Rambaldi Luca Rossi Giorgio Turchetti 《Communications in Nonlinear Science & Numerical Simulation》2009,14(2):593-612
Chains of point masses and chains of rigid bodies are used to model biological polymers. To investigate their dynamics we propose a method which allows an efficient realization of the constraints jointly with a simple and accurate integration of the free rigid body motion. The method is quite effective to evolute the geodesic flow of a rigid body chain and the global performance depends on the computational complexity of the algorithms used to compute the interaction forces. Our approach is suitable to describe a chain of rigid bodies immersed in a thermal bath. In the method we propose, the constraints are realized by hard springs whose elastic constant is set to maximize the energy dissipation rate of a Runge–Kutta integrator scheme. Moreover the use of local Lagrangian coordinates is introduced using the possibility of a continuous change of chart, such that the distance from the coordinate singularities is the highest possible. For a chain of point masses the numerical results are checked with another method where the constraints are exactly realized by means of Lagrangian coordinates. When the chain is subject to regular interactions potentials plus a thermal bath the exact and approximate constraints realization provide comparable results. 相似文献
995.
Here we present a study of stochastic resonance (SR) in an extended FitzHugh–Nagumo system with a field dependent activator diffusion. We show that the system response (here measured through the output signal-to-noise ratio (SNR)) is enhanced due to the particular form of the non-homogeneous coupling. Such a result supports previous ones obtained in a simpler scalar reaction-diffusion system and shows that such an enhancement, induced by the field dependent diffusion -or selective coupling-, is a robust phenomenon. 相似文献
996.
Isabella Miglioli Luca Muccioli Silvia Orlandi Matteo Ricci Roberto Berardi Claudio Zannoni 《Theoretical chemistry accounts》2007,118(1):203-210
We set up a model for discotic liquid crystal dimers and study, by means of Monte Carlo simulations, their phase behaviour
and self–assembling properties, in comparison with the simpler monomeric case. Each discotic dimer is described by two oblate
Gay–Berne ellipsoids connected by a flexible spacer, modelled by a harmonic “spring” of three different lengths. We find that
dimerization in general yields produces a significant change on the phase behaviour, with an increase of the columnar–nematic
transition temperature, a widening of the nematic region and the apparent suppression of the crystalline phase in favour of
the columnar phase up to very low temperatures. Longer spacers prove to ease the formation of columns and to increase the
orientational order.
Contribution to the Fernando Bernardi memorial issue. 相似文献
997.
998.
999.
1000.
Claudio F. Meyer Sandrine M. Hell Antonio Misale Andrs A. Trabanco Vronique Gouverneur 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(26):8921-8925
A facile method for the regioselective hydrodifluoromethylation of alkenes is reported using difluoroacetic acid and phenyliodine(III) diacetate in tetrahydrofuran under visible‐light activation. This metal‐free approach stands out as it uses inexpensive reagents, does not require a photocatalyst, and displays broad functional group tolerance. The procedure is also operationally simple and scalable, and provides access in one step to high‐value building blocks for application in medicinal chemistry. 相似文献