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991.
Reduction of Carbon Dioxide to Formate at Low Overpotential Using a Superbase Ionic Liquid 下载免费PDF全文
Dr. Nathan Hollingsworth Dr. S. F. Rebecca Taylor Miguel T. Galante Dr. Johan Jacquemin Dr. Claudia Longo Dr. Katherine B. Holt Prof. Nora H. de Leeuw Prof. Christopher Hardacre 《Angewandte Chemie (International ed. in English)》2015,54(47):14164-14168
A new low‐energy pathway is reported for the electrochemical reduction of CO2 to formate and syngas at low overpotentials, utilizing a reactive ionic liquid as the solvent. The superbasic tetraalkyl phosphonium ionic liquid [P66614][124Triz] is able to chemisorb CO2 through equimolar binding of CO2 with the 1,2,4‐triazole anion. This chemisorbed CO2 can be reduced at silver electrodes at overpotentials as low as 0.17 V, forming formate. In contrast, physically absorbed CO2 within the same ionic liquid or in ionic liquids where chemisorption is impossible (such as [P66614][NTf2]) undergoes reduction at significantly increased overpotentials, producing only CO as the product. 相似文献
992.
Huayna Terraschke Matthias Franzreb Claudia Wickleder 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(30):6833-6838
Afterglow–magnetic nanoparticles (NPs) offer enormous potential for bioimaging applications, as they can be manipulated by a magnetic field, as well as emitting light after irradiation with an excitation source, thus distinguishing themselves from fluorescent living cells. In this work, a novel double core–shell strategy is presented, uniting co-precipitation with combustion synthesis routes to combine an Fe3O4 magnetic core (≈15 nm) with an afterglow SrAl2O4:Eu2+,Dy3+ outer coat (≈10 nm), and applying a SiO2 protective middle layer (≈16 nm) to reduce the luminescence quenching caused by the Fe core ions. The resulting Fe3O4@SiO2@SrAl2O4:Eu2+,Dy3+ NPs emit green light attributed to the 4f65d1→4f7(8S7/2) transition of Eu2+ under UV radiation and for a few seconds afterwards. This bifunctional nanocomposite can potentially be applied for the detection and separation of cells or diagnostically relevant molecules. 相似文献
993.
Lisa-Lou Gracia Luisa Luci Cecilia Bruschi Prof. Dr. Letizia Sambri Dr. Patrick Weis Dr. Olaf Fuhr Dr. Claudia Bizzarri 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(44):9929-9937
Earth-abundant metal complexes have been attracting increasing attention in the field of photo(redox)catalysis. In this work, the synthesis and full characterisation of four new heteroleptic CuI complexes are reported, which can work as photosensitizers. The complexes bear a bulky diphosphine (DPEPhos=bis[(2-diphenylphosphino)phenyl] ether) and a diimine chelating ligand based on 1-benzyl-4-(quinol-2′yl)-1,2,3-triazole. Their absorption has a relative maximum in the visible-light region, up to 450 nm. Thus, their use in photocatalytic systems for the reduction of CO2 with blue light in combination with the known catalyst [NiII(cyclam)]Cl2 was tested. This system produced CO as the main product through visible light (λ=420 nm) with a TON up to 8 after 4 hours. This value is in line with other photocatalytic systems using the same catalyst. Nevertheless, this system is entirely noble-metal free. 相似文献
994.
Berencie Yahuaca-Juárez Gerardo González Marco A. Ramírez-Morales Calara Alba-Betancourt Martha A. Deveze-Álvarez Claudia L. Mendoza-Macías 《合成通讯》2020,50(4):539-548
AbstractThe first iodine(III)-based procedure for the benzylic oxidation of different arenes is described by using the (PhIO)n/Al(NO3)3 system under catalytic conditions leading to the formation of the corresponding carbonyl derivatives. The method proceeds under mild, operationally simple, room temperature, short reaction times, and open flask conditions. In light of the organocatalysis relevance and the novelty of our protocol, we wish to communicate our initial results of this novel oxidation. 相似文献
995.
Wonmin Choi Dr. Hao Sun Dr. Claudia Battistella Dr. Or Berger Maria A. Vratsanos Max M. Wang Prof. Dr. Nathan C. Gianneschi 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(45):19930-19940
In this Minireview, we describe synthetic polymers densely functionalized with sequence-defined biomolecular sidechains. We focus on synthetic brush polymers of oligonucleotides, oligosaccharides, and oligopeptides, prepared via graft-through polymerization from biomolecule functionalized monomers. The resulting structures are brush polymers wherein a biomolecular graft is positioned at each monomer backbone unit. We describe key synthetic milestones, identify synthetic opportunities, and highlight recent advances in the field, including biological applications. 相似文献
996.
M.C. Arenas L. Fernando Rodríguez-Núnez Domingo Rangel Omar Martínez-Álvarez Claudia Martínez-Alonso V.M. Castaño 《Ultrasonics sonochemistry》2013,20(2):777-784
In this work, hybrid nanocomposites based on anatase titania:polypyrrole (TiO2:PPy) were directly obtained from a simple, one-step, ultrasonic (UT)-assisted synthesis. The properties of these crystalline nanocomposites were compared with those of others fabricated using cold (Cold)-assisted synthesis without any UT assistance, which required a hydrothermal treatment (HT) to yield crystalline anatase titania in the nanocomposite (TiO2:PPy) at low temperature (130 °C) and in a short time (3 h). The SEM results demonstrated that the UT-assisted synthesis is a feasible method to obtain anatase TiO2:PPy nanocomposites with controlled morphology using low energy. The Fourier transform infrared (FT-IR) bands of the crystalline nanocomposites exhibited a shift with respect to neat components, which was attributed to the strong interaction between the secondary amine groups (N–H) of PPy and the oxygen from TiO2. The acceptable absorption in the visible region (λmax = 670 nm) indicates that these nanocomposites are good candidates for harvesting energy in solar cells. Devices based on these nanocomposites were built to evaluate their electrical properties. An increase in the photocurrent was observed for the devices prepared with the nanocomposites from the UT-assisted synthesis. 相似文献
997.
998.
Claudia Heidel Marion Tichomirowa Jörg Matschullat 《Isotopes in environmental and health studies》2013,49(4):339-354
To pinpoint the origin and mixing processes of mine waters, different mine water types from the polymetallic sulphide ore deposit ‘Himmelfahrt Fundgrube’ (Freiberg, Germany) were analysed by thermal ionisation mass spectrometry using lead and strontium isotope ratios. Results show that the lead isotope composition of different mine waters results from a mixture of at least two sources: released lead from oxidised sulphide ores (mainly galena) and anthropogenic lead from groundwater. Furthermore, there are indications for an additional lead source. Strontium isotopes in mine waters identify at least three different sources: released strontium from weathered host rock (Grey Gneisses), released strontium from weathered gangue carbonates, and probably strontium from anthropogenic inputs. Contrary to former oxygen and sulphur isotope studies, strontium isotope compositions as well as hydrochemical parameters show the important role of gangue carbonates as an element source in mine waters. 相似文献
999.
For nonautonomous linear equations in a Banach space admitting a nonuniform version of exponential contraction, we give an optimal characterization of the exponential behavior in terms of strict Lyapunov sequences. In particular, we construct explicitly strict Lyapunov sequences for each exponential contraction. We also consider the particular case of quadratic Lyapunov functions, and we use the corresponding characterization of the exponential behavior in terms of these functions to show that the stability of an exponential contraction persists under sufficiently small perturbations. 相似文献
1000.
We propose a parametric model for a bivariate stable Lévy process based on a Lévy copula as a dependence model. We estimate the parameters of the full bivariate model by maximum likelihood estimation. As an observation scheme we assume that we observe all jumps larger than some ε>0 and base our statistical analysis on the resulting compound Poisson process. We derive the Fisher information matrix and prove asymptotic normality of all estimates when the truncation point ε→0. A simulation study investigates the loss of efficiency because of the truncation. 相似文献