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991.
Current understanding of ultra-high cycle fatigue 总被引:1,自引:0,他引:1
The fatigue life of numerous aerospace, locomotive, automotive and biomedical structures may go beyond 108 cycles. Determination of long life fatigue behavior becomes extremely important for better understanding and design of the components and structures. Initially, before the invention of ultrasonic fatigue testing, most of the engineering materials were supposed to exhibit fatigue life up to 107 cycles or less. This paper reviews current understanding of some fundamental aspects on the development of accelerated fatigue testing method and its application in ultra-high cycle fatigue, crack initiation and growth mechanisms of internal fracture, S-N diagram, fatigue limit and life prediction, etc. 相似文献
992.
993.
Lemonnier JF Floquet S Marrot J Terazzi E Piguet C Lesot P Pinto A Cadot E 《Chemistry (Weinheim an der Bergstrasse, Germany)》2007,13(12):3548-3557
The influence of rigid or semirigid dicarboxylate anions, terephtalate (TerP(2-)), isophtalate (IsoP(2-)), and phenylenediacetate (PDA(2-)) on the self-condensation process of the [Mo(2)O(2)S(2)](2+) dioxothio cation has been investigated. Three new molybdenum rings, [Mo(12)O(12)S(12)(OH)(12)(TerP)](2-) ([Mo(12)TerP](2-)), [Mo(16)O(16)S(16)(OH)(16)(H(2)O)(4)(PDA)(2)](4-) ([Mo(16)(PDA)(2)](4-)), and [Mo(16)O(16)S(16)(OH)(16)(H(2)O)(2)(IsoP)(2)](4-) ([Mo(16)(IsoP)(2)](4-)) have been isolated and unambiguously characterized in the solid state by single-crystal X-ray studies and in solution by various NMR methods and especially by diffusion-correlated NMR ((1)H DOSY) spectroscopy, which was shown to be a powerful tool for the characterization and speciation of templated molybdenum ring systems in solution. Characterization by FT-IR and elemental analysis are also reported. The dynamic and thermodynamic properties of both the sixteen-membered rings were studied in aqueous medium. Specific and distinct behaviors were revealed for each system. The IsoP(2-)/[Mo(2)O(2)S(2)](2+) system gave rise to equilibrium, involving mono-templated [Mo(12)IsoP](2-) and bis-templated [Mo(16)(IsoP)(2)](4-) ions. Thermodynamic parameters have been determined and showed that the driving-force for the formation of the [Mo(16)(IsoP)(2)](4-) is entropically governed. However, whatever the conditions (temperature, proportion of reactants), the PDA(2-)/[Mo(2)O(2)S(2)](2+) system led only to a single compound, the [Mo(16)(PDA)(2)](4-) ion. The latter exhibits dynamic behavior, consistent with the gliding of both the stacked aromatic groups. Stability and dynamics of both Mo(16) rings was related to weak hydrophobic or pi-pi stacking inter-template interactions and inner hydrogen-bond network occurring within the [Mo(16)(IsoP)(2)](4-) and [Mo(16)(PDA)(2)](4-) ions. 相似文献
994.
Escande A Guénée L Nozary H Bernardinelli G Gumy F Aebischer A Bünzli JC Donnio B Guillon D Piguet C 《Chemistry (Weinheim an der Bergstrasse, Germany)》2007,13(31):8696-8713
The connection of twelve peripheral and divergent dodecyloxy chains to a central tridentate aromatic binding unit provides the dodecacatenar ligand L11, for which room-temperature mesomorphism is detected. An enthalpically unbalanced large melting entropy (DeltaSmL11=226 J mol(-1) K(-1)) results from the programmed microsegregation induced in the crystalline phase, a phenomenon which is maintained in the associated lanthanide complexes [Ln(L11)(NO3)3] and [Ln(L11)(CF3CO2)3]2. Low-temperature melting processes (-43相似文献
995.
Jean‐Claude Rayez Robert Lesclaux 《Angewandte Chemie (International ed. in English)》2009,48(28):5075-5075
Oxford University Press, Oxford 2008. 992 pp., hardcover $ 295.00.—ISBN 978–0195365818
996.
The syntheses of barium, cadmium, calcium, lead, and strontium apatites were performed in anhydrous polar organic solvents such as DMSO, anisole, pyridine, glacial acetic acid, ethanol, methanol, and DMF. Reactions took place under anhydrous conditions at temperatures ranging from 80 to 120 °C and for durations of 1–6 days. Ten apatites were synthesized in nonaqueous solvents and three (PbApF, PbApCl, SrApCl) were obtained using trimethylphosphate as the phosphate source. The use of nonaqueous solvents alleviates the formation of hydrogen phosphates which occurs in aqueous solution for some divalent cations. The limited solubility of even alkali metal salts in many of the solvents also produces nonapatitic double salts such as NaPb4(PO4)3, NaPbPO4, KPb4(PO4)3, Cd(OH)NO3, and NaBaPO4. 相似文献
997.
998.
Olive Recombinant Hydroperoxide Lyase,an Efficient Biocatalyst for Synthesis of Green Leaf Volatiles
999.