Diffusion approximations for the scattering of resonance-line photons: Interior and boundary layer solutions

Resonance-line scattering in static low density media with large optical thickness has a diffusive behavior in both space and frequency because photons belonging to the Lorentzian wings of the line may be scattered almost monochromatically a very large number of times. This diffusive behavior holds on frequency scales and spatial scales, χ_c and τ_c, much larger than the scales associated with one elementary scattering of a wing-photon.A method developed for diffusion approximations in neutron transport theory, suitably generalized to handle diffusion in frequency space, is applied to the case of conservative scattering in a bounded medium with interior sources and zero incoming radiation. The method is to separate the line radiation field into an interior part and a boundary layer part which goes to zero in the interior. Each part is expanded in terms of a small parameter ?, which is the ratio of the mean free-path at frequency χ_c to the characteristic spatial scale τ_c.It is shown that the leading term in the interior asymptotic expansion is isotropic, zero on the boundary, and obeys a space and frequency diffusion equation. In the boundary-layer expansion, the leading term is of order ? and is a solution to a monochromatic transfer equation in a semi-infinite, plane-parallel medium. The emergent radiation field is shown to be of order ? and proportional to the gradient of the interior solution at the boundary. Its angular dependence, in the case of isotropic scattering in the atom frame, is given by the Ambartsoumian H-function. A comparison is presented between numerical solutions of the full transfer equation and asymptotic solutions. Non-conservative scattering and time-dependent problems are briefly discussed.     

A general ultrasound-assisted access to room-temperature ionic liquids

The replacement of common organic solvents by room-temperature ionic liquids (RTILs) is a topical subject in both academia and industry. In the last decades, the number of applications for RTILs has followed an exponential curve and spilled over the boundaries of chemistry. Still, one of the main drawbacks of these compounds is their difficult access. The present ultrasound-assisted method affords a general and easy access to a large variety of room-temperature ionic liquids.     

Diffusion approximation for billiards with totally accommodating scatterers

We study the 2D motion of independent point particles colliding with a periodic array of circular obstacles. The interaction between the particles and the obstacles is described by a total accommodation reflection law. Assuming that the array of scatterers has finite horizon, the density of particles is approximated by the solution of a diffusion equation in the long-time and large-scale regime. The proof relies on a multiscale asymptotics and gives the order of approximation.     

Relaxation effects in the quantification of fat using gradient echo imaging

Quantification of fat has been investigated using images acquired from multiple gradient echoes. The evolution of the signal with echo time and flip angle was measured in phantoms of known fat and water composition and in 21 research subjects with fatty liver. Data were compared to different models of the signal equation, in which each model makes different assumptions about the T1 and/or T2* relaxation effects. A range of T1, T2*, fat fraction and number of echoes was investigated to cover situations of relevance to clinical imaging. Results indicate that quantification is most accurate at low flip angles (to minimize T1 effects) with a small number of echoes (to minimize spectral broadening effects). At short echo times, the spectral broadening effects manifest as a short apparent T2 for the fat component.     

Huge fluctuations in weight measurements at the bottom of a two-dimensional vertical sheet of grains

Weight measurements at the bottom of a quasi-2D vertical sheet of static cohesionless grains are carried out. The grains are held between two coaxial cylinders. This peculiar setup allows us to set either periodic or fixed lateral boundary conditions. Huge relative fluctuations in weight measurements appear in case of fixed lateral walls. This may be related to some indetermination in the mobilization state of friction forces on lateral walls. This argument would hold for any piling, but would lead to huge fluctuations in 2D systems only, because of averaging effects in 3D.     

Robustness of fat quantification using chemical shift imaging

The purpose of this study was to investigate the effect of parameter changes that can potentially lead to unreliable measurements in fat quantification. Chemical shift imaging was performed using spoiled gradient echo sequences with systematic variations in the following: two-dimensional/three-dimensional sequence, number of echoes, delta echo time, fractional echo factor, slice thickness, repetition time, flip angle, bandwidth, matrix size, flow compensation and field strength. Results indicated no significant (or significant but small) changes in fat fraction with parameter. The significant changes can be attributed to the known effects of T1 bias and two forms of noise bias.     

Design and performance of BOREAS,the beamline for resonant X‐ray absorption and scattering experiments at the ALBA synchrotron light source

The optical design of the BOREAS beamline operating at the ALBA synchrotron radiation facility is described. BOREAS is dedicated to resonant X‐ray absorption and scattering experiments using soft X‐rays, in an unusually extended photon energy range from 80 to above 4000 eV, and with full polarization control. Its optical scheme includes a fixed‐included‐angle, variable‐line‐spacing grating monochromator and a pair of refocusing mirrors, equipped with benders, in a Kirkpatrick–Baez arrangement. It is equipped with two end‐stations, one for X‐ray magnetic circular dichroism and the other for resonant magnetic scattering. The commissioning results show that the expected beamline performance is achieved both in terms of energy resolution and of photon flux at the sample position.     

Improvement of kinetics,yield, and colloidal stability of biogenic gold nanoparticles using living cells of <Emphasis Type="Italic">Euglena gracilis</Emphasis> microalga

Recent years have witnessed a boom in the biosynthesis of a large variety of nanomaterials using different biological resources among which algae-based entities have been gaining much more attention within the community of material scientists worldwide. In our previously published findings, we explored some factors that governed the biofabrication of gold nanoparticles using living cultures of microalgae, such as the utilized microalgal genera, the phylum they belong to, and the impact of tetrachloroauric acid concentrations on the ability of these strains to perform the biosynthesis of gold nanoparticles once in contact with these cations. As a follow-up, we present in this paper an improvement of the features of bioproduced gold colloids using living cells of Euglena gracilis microalga when this species is grown under either mixotrophic or autotrophic conditions, i.e., exposed to light and grown in an organic carbon-enriched culture medium versus under autotrophic conditions. As an outcome to this alteration, the growth rate of this photosynthetic microorganism is multiplied 7–8 times when grown under mixotrophic conditions compared to autotrophic ones. Therefore, the yield, the kinetics, and the colloidal stability of the biosynthesized gold nanoparticles are dramatically enhanced. Moreover, the shape and the size of the as-produced nano-objects via this biological method are affected. In addition to round-shaped gold nanoparticles, particular shapes, such as triangles and hexagons, appear. These findings add up to the amassed knowledge toward the design of photobioreactors for the scalable and sustainable production of interesting nanomaterials.     

Entire Solutions of Hydrodynamical Equations with Exponential Dissipation

We consider a modification of the three-dimensional Navier–Stokes equations and other hydrodynamical evolution equations with space-periodic initial conditions in which the usual Laplacian of the dissipation operator is replaced by an operator whose Fourier symbol grows exponentially as e^|k|/k_d{{{\rm e}^{|k|/k_{\rm d}}}} at high wavenumbers |k|. Using estimates in suitable classes of analytic functions, we show that the solutions with initially finite energy become immediately entire in the space variables and that the Fourier coefficients decay faster than e^{-C(k/k_d) ln(|k|/k_d)}{{{\rm e}^{-C(k/k_{\rm d})\,{\rm ln}(|k|/k_{\rm d})}}} for any C < 1/(2 ln 2). The same result holds for the one-dimensional Burgers equation with exponential dissipation but can be improved: heuristic arguments and very precise simulations, analyzed by the method of asymptotic extrapolation of van der Hoeven, indicate that the leading-order asymptotics is precisely of the above form with C = C _* = 1/ ln 2. The same behavior with a universal constant C _* is conjectured for the Navier–Stokes equations with exponential dissipation in any space dimension. This universality prevents the strong growth of intermittency in the far dissipation range which is obtained for ordinary Navier–Stokes turbulence. Possible applications to improved spectral simulations are briefly discussed.     

1H and 13C NMR Determination of the Enantiomeric Purity of Substituted 4-Amino-3- (thien-2-Yl)-Butyric Acids and 4-Amino-3-(Benzo[b]Furan-2-yl)-Butyric Acids,Ligands of the GabaB Receptor.

The enantiomeric composition and absolute configuration of 4-Amino-3-(benzo[b]furan-2-yl)-Butanoic Acids and of 4-Amino-3-(thien-2-yl)-Butanoic Acids 1 may be accurately determined by ¹H and ¹³C nuclear magnetic resonance analysis of the corresponding derivatives 3 prepared by reaction with chiral reagents. Correlation with HPLC is signaled.