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91.
92.
Claude Tournut 《Macromolecular Symposia》1994,82(1):99-109
After a brief presentation of the standard non-functionalized copolymers of vinylidene fluoride, the preparation of new functionalized copolymers is described, by copolymerization of vinylidene fluoride, with other fluoromonomers and non-fluorinated monomers including at least one hydroxy or other functional group. The copolymers are analysed by the conventional methods. Examples of formulation show that these new copolymers are able to give coatings applicable outdoors and offering the same excellent durability as PVDF. 相似文献
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To minimize a convex function, we combine Moreau-Yosida regularizations, quasi-Newton matrices and bundling mechanisms. First
we develop conceptual forms using “reversal” quasi-Newton formulae and we state their global and local convergence. Then,
to produce implementable versions, we incorporate a bundle strategy together with a “curve-search”. No convergence results
are given for the implementable versions; however some numerical illustrations show their good behaviour even for large-scale
problems. 相似文献
96.
Antonin Desmecht Dr. Debobrata Sheet Claude Poleunis Prof. Sophie Hermans Prof. Olivier Riant 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(6):1436-1440
The chemical functionalization of carbon nanotubes is often a prerequisite prior to their use in various applications. The covalent grafting of 4,4,5,5-tetramethyl-1,3,2-dioxaborolane (BPin) functional groups directly on the surface of multi- and single-walled carbon nanotubes, activated by nucleophilic addition of nBuLi, was carried out. Thermogravimetric analysis (TGA) coupled with mass spectrometry, Raman spectroscopy, X-ray photoelectron spectroscopy (XPS) and time-of-flight secondary ions mass spectrometry (ToF-SIMS) confirmed the efficiency of this methodology and proved the integrity and covalent grafting of the BPin functional groups. These groups were further reacted with various nucleophiles in the presence of a copper(II) source in the conditions of the aerobic Chan–Lam–Evans coupling. The resulting materials were characterized by TGA, XPS and ToF-SIMS. This route is efficient, reliable and among the scarce reactions that enable the direct grafting of heteroatoms at carbonaceous material surfaces. 相似文献
97.
Eléonore Mathis Marie-Laure Michon Claude Billaud Pauline Grau Anthony Bocahut Caroll Vergelati Didier R. Long 《Journal of polymer science. Part A, Polymer chemistry》2020,58(8):1177-1188
Thermoset (TS) epoxy resins can be toughened with a thermoplastic (TP) for high-performance applications. The final structure morphology has to be controlled to achieve high mechanical properties and high impact resistance. Four polyethersulfone-modified epoxy resins are considered. They consist of different epoxy monomer structure (TGAP, triglycidyl-p-aminophenol and TGDDM, tetraglycidyl diaminodiphenylmethane) and a fixed amount of thermoplastic, and they are cured with two different amounts of curing agent. A reaction-induced phase separation occurs for all formulations generating morphologies, different in shapes and scales. The aim is to control the final morphology and in particular its dominant length scale. This morphology depends on the phase separation process, from the initiation to its final stage. The initiation relies on the relative miscibility of the components and on the stoichiometry between epoxy and curing agent. The kinetics depends on the viscosity of the systems. The different morphologies are characterized by electron microscopy or neutron scattering. Dynamic mechanical analysis allows confirming the presence of a phase separation even when it is not observable by electron microscopy. Vermicular morphologies with few hundreds nanometer width are obtained for the systems containing the TGAP as epoxy monomer. Systems formulated with TGDDM presents morphologies on much smaller scale of order a few tens of nanometers. We interpret the different sizes of the morphologies as a consequence of a larger viscosity for the TGDDM systems as compared to the TGAP ones rather than by a latter initiation of phase separation. 相似文献
98.
Claude Ederer Matej Komelj James W. Davenport Manfred Fhnle 《Journal of Electron Spectroscopy and Related Phenomena》2003,130(1-3):97-100
The magnetic dipole term T appearing in the X-ray magnetic circular dichroism (XMCD) spin sum rule can be eliminated from the analysis within the spin sum rule by angle-dependent XMCD spectroscopy if the effects of spin–orbit coupling are small so that Tx+Ty+Tz≈0. It is shown by the ab initio electron theory for the extreme case of a low-dimensional system, i.e., for a free-standing monatomic Co wire that this relation is strongly violated, indicating that the determination of T by the angle-dependent XMCD is possibly not very reliable for low-dimensional magnetic systems. 相似文献
99.
Claude Marion 《代数通讯》2013,41(3):853-925
Let p 1, p 2, p 3 be primes. This is the second article in a series of three on the (p 1, p 2, p 3)-generation of the finite projective special unitary and linear groups PSU3(p n ), PSL3(p n ), where we say a noncyclic group is (p 1, p 2, p 3)-generated if it is a homomorphic image of the triangle group T p 1, p 2, p 3 . This paper is concerned with the case where p 1 = 2 and p 2 = p 3. We determine for any prime p 2 the prime powers p n such that PSU3(p n ) (respectively, PSL3(p n )) is a quotient of T = T 2, p 2, p 2 . We also derive the limit of the probability that a randomly chosen homomorphism in Hom(T, PSU3(p n )) (respectively, Hom(T, PSL3(p n ))) is surjective as p n tends to infinity. 相似文献
100.