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101.
V. R. Shaginyan A. Z. Msezane K. G. Popov J. W. Clark M. V. Zverev V. A. Khodel 《JETP Letters》2012,96(6):397-404
Physicists are engaged in vigorous debate on the nature of the quantum critical points (QCP) governing the low-temperature properties of heavy-fermion metals. Recent experimental observations of the much-studied compound YbRh2Si2 in the regime of vanishing temperature incisively probe the nature of its magnetic-field-tuned QCP. The jumps revealed both in the residual resistivity ??0 and the Hall resistivity R H, along with violation of the Wiedemann-Franz law, provide vital clues to the origin of such non-Fermi-liquid behavior. The empirical facts point unambiguously to association of the observed QCP with a fermion-condensation phase transition. Based on this insight, the resistivities ??0 and R H are predicted to show jumps at the crossing of the QCP produced by application of a magnetic field, with attendant violation of the Wiedemann-Franz law. It is further demonstrated that experimentally identifiable multiple energy scales are related to the scaling behavior of the effective mass of the quasiparticles responsible for the low-temperature properties of such heavy-fermion metals. 相似文献
102.
Rongji Liu Kecheng Cao Adam H. Clark Peilong Lu Montaha Anjass Johannes Biskupek Ute Kaiser Guangjin Zhang Carsten Streb 《Chemical science》2020,11(4):1043
The top-down fabrication of catalytically active molecular metal oxide anions, or polyoxometalates, is virtually unexplored, although these materials offer unique possibilities, for catalysis, energy conversion and storage. Here, we report a novel top-down route, which enables the scalable synthesis and deposition of sub-nanometer molybdenum-oxo clusters on electrically conductive mesoporous carbon. The new approach uses a unique redox-cycling process to convert crystalline MoIVO2 particles into sub-nanometer molecular molybdenum-oxo clusters with a nuclearity of ∼1–20. The resulting molybdenum-oxo cluster/carbon composite shows outstanding, stable electrocatalytic performance for the oxygen reduction reaction with catalyst characteristics comparable to those of commercial Pt/C. This new material design could give access to a new class of highly reactive polyoxometalate-like metal oxo clusters as high-performance, earth abundant (electro-)catalysts.The top-down synthesis and deposition of polyoxometalate-like clusters on porous carbon is reported together with the high electrocatalytic oxygen reduction reactivity of the composite. 相似文献
103.
Dry organic solvents are used for various organic reactions that employ moisture sensitive reagents. The processes to dry these solvents are hazardous and costly. Setting up reactions in an open atmosphere while using moisture sensitive reagents has little to no effect on the rate or yield of the reaction under mechanochemical conditions. We believe this is partly due to the gaseous nature of the water vapor in the air compared to the dissolved water and oxygen in solution. 相似文献
104.
105.
We present a new model for the physics of thresholdless switching in chiral smectics. In the limit of high polarization, the electro-optics of chiral smectic C liquid crystals are dominated by two distinct electrostatic effects. Complete (surface to surface) 'stiffening' of the polarization field by its charge self-interaction causes the polarization to orient as a uniform block. Complete screening of applied electric field by polarization charge leads to voltage-induced orientation where the electric field in the liquid crystal is exactly zero, These effects, both operative during the 'V-shaped' portion of thresholdless transmission vs. voltage curves, combine to produce 'V-shaped' switching. 相似文献
106.
Aleksandra Borisova Mario De Bruyn Vitaliy L. Budarin Peter S. Shuttleworth Jennifer R. Dodson Mateus L. Segatto James H. Clark 《Macromolecular rapid communications》2015,36(8):774-779
Bio‐derived polysaccharide aerogels are of interest for a broad range of applications. To date, these aerogels have been obtained through the time‐ and solvent‐intensive procedure of hydrogel fomation, solvent exchange, and scCO2 drying, which offers little control over meso/macropore distribution. A simpler and more versatile route is developed, using freeze drying to produce highly mesoporous polysaccharide aerogels with various degrees of macroporosity. The hierarchical pore distribution is controlled by addition of different quantities of t‐butanol (TBA) to hydrogels before drying. Through a systematic study an interesting relationship between the mesoporosity and t‐butanol/water phase diagram is found, linking mesoporosity maxima with eutectic points for all polysaccharides studied (pectin, starch, and alginic acid). Moreover, direct gelation of polysaccharides in aqueous TBA offers additional time savings and the potential for solvent reuse. This finding is a doorway to more accessible polysaccharide aerogels for research and industrial scale production, due to the widespread accessibility of the freeze drying technology and the simplicity of the method.
107.
Bettina Schweda Dr. Matiss Reinfelds Jakob Hofinger Georg Bäumel Dr. Thomas Rath Dr. Petra Kaschnitz Prof. Dr. Roland C. Fischer Prof. Dr. Michaela Flock Prof. Dr. Heinz Amenitsch Prof. Dr. Markus Clark Scharber Prof. Dr. Gregor Trimmel 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(23):e202200276
A series of non-fullerene acceptors based on perylene monoimides coupled in the peri position through phenylene linkers were synthesized via Suzuki-coupling reactions. Various substitution patterns were investigated using density functional theory (DFT) calculations in combination with experimental data to elucidate the geometry and their optical and electrochemical properties. Further investigations of the bulk properties with grazing incidence wide angle X-ray scattering (GIWAXS) gave insight into the stacking behavior of the acceptor thin films. Electrochemical and morphological properties correlate with the photovoltaic performance of devices with the polymeric donor PBDB-T and a maximum efficiency of 3.17 % was reached. The study gives detailed information about structure–property relationships of perylene-linker-perylene compounds. 相似文献
108.
There has been much recent progress in the understanding and reduction of the computational cost of the hybrid Monte Carlo algorithm for lattice QCD as the quark mass parameter is reduced. In this letter we present a new solution to this problem, where we represent the fermionic determinant using n pseudofermion fields, each with an nth root kernel. We implement this within the framework of the rational hybrid Monte Carlo algorithm. We compare this algorithm with other recent methods in this area and find it is competitive with them. 相似文献
109.
Ab initio band-structure calculations based on density functional theory have been completed for alpha-quartz phase GeO2 to obtain electric-field gradients (efg) for oxygen atoms, including those for GeO2 at elevated pressure and temperature. To interpret the resulting efg values and examine correlations between structure and 17O quadrupolar coupling parameters, additional ab initio self-consistent Hartree-Fock molecular orbital calculations were completed. The quadrupolar coupling constant was found to have a strong dependence on Ge-O distance and angleGe-O-Ge, with the quadrupolar asymmetry parameter being primarily dependent on angleGe-O-Ge. Analytical expressions describing these dependencies consistent with earlier investigations of analogous silicate compounds are also reported. 相似文献
110.