全文获取类型
收费全文 | 823篇 |
免费 | 18篇 |
国内免费 | 4篇 |
专业分类
化学 | 568篇 |
晶体学 | 12篇 |
力学 | 9篇 |
数学 | 72篇 |
物理学 | 184篇 |
出版年
2022年 | 6篇 |
2021年 | 12篇 |
2020年 | 9篇 |
2019年 | 9篇 |
2018年 | 8篇 |
2016年 | 13篇 |
2015年 | 11篇 |
2014年 | 13篇 |
2013年 | 30篇 |
2012年 | 44篇 |
2011年 | 44篇 |
2010年 | 17篇 |
2009年 | 23篇 |
2008年 | 46篇 |
2007年 | 52篇 |
2006年 | 40篇 |
2005年 | 40篇 |
2004年 | 44篇 |
2003年 | 30篇 |
2002年 | 30篇 |
2001年 | 11篇 |
2000年 | 15篇 |
1999年 | 12篇 |
1998年 | 9篇 |
1997年 | 9篇 |
1996年 | 16篇 |
1995年 | 17篇 |
1994年 | 23篇 |
1993年 | 22篇 |
1992年 | 22篇 |
1991年 | 12篇 |
1990年 | 12篇 |
1989年 | 6篇 |
1988年 | 10篇 |
1987年 | 6篇 |
1986年 | 5篇 |
1985年 | 16篇 |
1984年 | 5篇 |
1983年 | 6篇 |
1982年 | 9篇 |
1981年 | 11篇 |
1980年 | 6篇 |
1979年 | 7篇 |
1978年 | 6篇 |
1977年 | 10篇 |
1976年 | 8篇 |
1975年 | 9篇 |
1974年 | 4篇 |
1973年 | 6篇 |
1972年 | 3篇 |
排序方式: 共有845条查询结果,搜索用时 93 毫秒
11.
B.W. Clare P.J. Jennings J.C.L. Cornish G. Talukder C.P. Lund G.T. Hefter 《Journal of computational chemistry》1993,14(12):1423-1428
A set of simple models of hydrogenated amorphous silicon (a-Si:H) consisting of hypothetical silane molecules with diamond or similar lattices was studied by the semiempirical AM1 method. Densities of states and infrared spectra were calculated for the silane molecules and similar molecules with dangling bonds disorder, and with boron or phosphorus substitution to simulate doping. Some examples are presented, and a comparison is made with experimental properties of a-Si:H. It is proposed to use these models in a study of the Staebler–Wronski photodegradation of a-Si:H and other aspects of amorphous silicon technology. © John Wiley & Sons, Inc. 相似文献
12.
19F and (119)Sn MAS NMR spectroscopy have been used to investigate the fluoride ion conductor, BaSnF(4), a member of the MSnF(4) family of fluorite-related anionic conductors containing double layers of Sn(2+) and M(2+) cations. Two fluorine sublattices were observed by (19)F MAS NMR, which could be assigned to specific sites in the lattice. The first sublattice is due to fluorine atoms located in Ba(2+) double layers and is rigid on the MAS NMR time scale at room temperature. The second sublattice comprises the fluoride ions between the Ba(2+) and Sn(2+) layers, and the few fluorine atoms that inhabit the Sn(2+)-Sn(2+) double layers. These ions are in rapid exchange with each other, and an extremely short correlation time tau(C) for the motion of these ions of <3 x 10(-)(5) s is obtained at -100 degrees C. T(1) measurements indicate that tau(C) approaches 10(-)(8) s at room temperature. (19)F-to-(119)Sn cross-polarization (CP) experiments confirmed the assignments of the resonances, and that the fluorine atoms located next to the tin atoms are extremely mobile at room temperature (and thus do not contribute to the CP process). Two-dimensional (19)F exchange experiments showed that exchange between the rigid and mobile lattice does occur, but at a much slower rate (tau(C) approximately 10 ms at 250 degrees C). Low-temperature (19)F MAS and (19)F-to-(119)Sn CP NMR spectra demonstrate that the motion of the fluoride ions has almost completely frozen out by -150 degrees C. The results are consistent with rapid two-dimensional (anisotropic) conductivity involving the fluoride ions between the Ba and Sn layers. Conductivity in three dimensions requires hops between the ions in the BaF(2)-like layers and the mobile ions. This process does occur, but with exchange rates that are at least 6-7 orders of magnitude slower. 相似文献
13.
Gelebe AC Kaye PT Klein R Sewry JD Soper AG 《Magnetic resonance in chemistry : MRC》2005,43(11):952-955
The influence of substituents and structure on the 13C NMR spectra of four series of benzoxathiepine derivatives has been investigated. Signal assignments in the 13C NMR spectra have been facilitated by the use of several predictive methods, permitting comparison of their relative efficacy. 相似文献
14.
[reaction: see text] Glucuronyl iodide 1 has been studied in detail as a "disarmed" glycosyl donor. In a model reaction, using N-iodosuccinimide (NIS) as a promoter and 2-phenylethanol as acceptor, best results were obtained using NIS with I(2), followed by trimethylsilyltrifluoromethanesulfonate (TMSOTf). When a series of primary and secondary alcohols was glycosylated using these conditions, yields of 60-83% of beta-glucuronides were obtained. Various "nonheavy" metal salts also effectively catalyzed the model reaction but led to significant amounts of alpha-product with less reactive secondary alcohols. 相似文献
15.
16.
Arisaka K Auerbach LB Axelrod S Belz J Biery KA Buchholz P Chapman MD Cousins RD Diwan MV Eckhause M Ginkel JF Guss C Hancock AD Heinson AP Highland VL Hoffmann GW Horvath J Irwin GM Joyce D Kaarsberg T Kane JR Kenney CJ Kettell SH Kinnison WW Knibbe P Konigsberg J Kuang Y Lang K Lee DM Margulies J Mathiazhagan C McFarlane WK McKee RJ Melese P Milner EC Molzon WR Ouimette DA Riley PJ Ritchie JL Rubin P Sanders GH Schwartz AJ Sivertz M Slater WE Urheim J Vulcan WF Wagner DL Welsh RE Whyley RJ 《Physical review letters》1993,71(24):3910-3913
17.
18.
19.
Nernst R Antreasyan D Aschman D Besset D Bienlein JK Bloom ED Brock I Cabenda R Cartacci A Cavalli-Sforza M Clare R Conforto G Cooper S Cowan R Coyne D de Judicibus D Edwards C Engler A Folger G Fridman A Gaiser J Gelphman D Godfrey G Heimlich FH Hofstadter R Irion J Jakubowski Z Keh S Kilian H Kirkbride I Kloiber T Koch W König AC Königsmann K Kraemer RW Lee R Leffler S Lekebusch R Lezoch P Litke AM Lockman W Lowe S Lurz B Marlow D Maschmann W Matsui T Messing F Metzger WJ Monteleoni B 《Physical review letters》1985,54(20):2195-2198
20.