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排序方式: 共有1410条查询结果,搜索用时 15 毫秒
981.
Tancredi Carli Dan Clements Amanda Cooper-Sarkar Claire Gwenlan Gavin P. Salam Frank Siegert Pavel Starovoitov Mark Sutton 《The European Physical Journal C - Particles and Fields》2010,66(3-4):503-524
A method to facilitate the consistent inclusion of cross-section measurements based on complex final-states from HERA, TEVATRON and the LHC in proton parton density function (PDF) fits has been developed. This can be used to increase the sensitivity of LHC data to deviations from Standard Model predictions. The method stores perturbative coefficients of NLO QCD calculations of final-state observables measured in hadron colliders in look-up tables. This allows the a posteriori inclusion of parton density functions (PDFs), and of the strong coupling, as well as the a posteriori variation of the renormalisation and factorisation scales in cross-section calculations. The main novelties in comparison to original work on the subject are the use of higher-order interpolation of Lagrangian form, which substantially improves the trade-off between accuracy and memory use, and a CPU and computer memory optimised way to construct and store the look-up table using modern software tools. It is demonstrated that a sufficient accuracy on the cross-section calculation can be achieved with reasonably small look-up table size by using the examples of jet production and electro-weak boson (Z, W) production in proton-proton collisions at a center-of-mass energy of 14 TeV at the LHC. The use of this technique in PDF fitting is demonstrated in a PDF-fit to HERA data and simulated LHC jet cross-sections as well as in a study of the jet cross-section uncertainties at various centre-of-mass energies. 相似文献
982.
试提出一种高荧光及强背景噪声情况下表面增强拉曼散射光谱的提取方法。该方法从分析荧光谱及背景噪声信号的组成入手,构建相应模型对荧光谱及噪声信号进行估计,通过比较估计结果与实际数据的差别识别谱峰信号,并定位谱峰的基底位置。通过在若丹明6G、前列腺特异抗原测量及pH值传感实验中的实际应用检验可知,该方法可提高表面增强拉曼散射光谱信号的分辩率和测量准确度,在微量物质鉴别及物质含量定量测量方面有较好的应用前景。 相似文献
983.
We demonstrate on-chip hybrid integration of chalcogenide glass waveguides and quantum cascade lasers (QCLs). Integration is achieved using an additive solution-casting and molding method to directly form As(2)S(3) strip waveguides on an existing QCL chip. Integrated As(2)S(3) strip waveguides constructed in this manner display strong optical confinement and guiding around 90° bends, with a NA of 0.24 and bend loss of 12.9dB at a 1mm radius (λ=4.8μm). 相似文献
984.
Philippe FD Prada C de Rosny J Clorennec D Minonzio JG Fink M 《The Journal of the Acoustical Society of America》2008,124(2):779-787
This paper reports the results of an investigation into extracting of the backscattered frequency signature of a target in a waveguide. Retrieving the target signature is difficult because it is blurred by waveguide reflections and modal interference. It is shown that the decomposition of the time-reversal operator method provides a solution to this problem. Using a modal theory, this paper shows that the first singular value associated with a target is proportional to the backscattering form function. It is linked to the waveguide geometry through a factor that weakly depends on frequency as long as the target is far from the boundaries. Using the same approach, the second singular value is shown to be proportional to the second derivative of the angular form function which is a relevant parameter for target identification. Within this framework the coupling between two targets is considered. Small scale experimental studies are performed in the 3.5 MHz frequency range for 3 mm spheres in a 28 mm deep and 570 mm long waveguide and confirm the theoretical results. 相似文献
985.
986.
Using the AutoGraphiX system, we obtain conjectures of the form l(n)?q1⊕i(G)?u(n) where q1 denotes the signless Laplacian index of graph is one the four operations is another invariant chosen among minimum, average and maximum degree, average distance, diameter, radius, girth, proximity, remoteness, vertex, edge and algebraic connectivities, independence number, domination number, clique number, chromatic number and matching number, Randi? index, l(n) and u(n) are best possible lower and upper bounds function of the order n of G. Algebraic conjectures are obtained in 120 cases out of 152 and structural conjectures in 12 of the remaining cases. These conjectures are known, immediate or proved in this paper, except for 17 of them, which remain open. 相似文献
987.
Claire Bouvy Evgeny Chelnokov Wladimir Marine Robert Sporken Bao-Lian Su 《Journal of Non》2009,355(18-21):1152-1156
ZnO@mesoporous silica nanocomposite was prepared by the impregnation of a CMI-1 material in a Zn(NO3)2 solution followed by calcination under O2. Intensive characterization was carried out by N2 adsorption–desorption measurements, scanning and transmission electron microscopy. The optical properties of the ZnO@mesoporous silica nanocomposite were studied by photoluminescence spectroscopy. Quantum Size Effect was firstly demonstrated by subjecting the sample to a 254 nm excitation light, and was further confirmed by using a 680 nm excitation laser beam, which implies a two-photon absorption process. By focusing the 680 nm laser beam on different places in the sample, a very localized random laser effect, also induced by a two-photon absorption process, was detected. 相似文献
988.
989.
Yong Wang Pascal Pigeon Siden Top Juan SanzGarcía Claire Troufflard Ilaria Ciofini Michael J. McGlinchey Grard Jaouen 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(25):8509-8513
Ferrociphenols, especially those possessing a heterocycle at the terminus of an aliphatic chain, display strong anticancer activity through a novel redox mechanism that generates active metabolites such as quinone methides (QMs). X‐ray crystallography and UV/Vis spectroscopy reveal that the specific lone pair (lp)–π interaction between a carbonyl group of the imide and the quinone motif of the QM plays an important role in the exceptional cytotoxic behaviour of their imido‐ferrociphenol precursors. This intramolecular lp–π interaction markedly enhanced the stability of the QMs and lowered the pKa values of the corresponding phenol/phenolate couples. As the first example of such a non‐covalent interaction that stabilizes QMs remotely, it not only expands the scope of the lp–π interaction in supramolecular chemistry, but also represents a new mode of stabilization of a QM. This unprecedented application of lp–π interactions in imido‐ferrociphenol anticancer drug candidates may also have great potential in drug discovery and organocatalyst design. 相似文献
990.
Hai T. Dong Amy L. Speelman Claire E. Kozemchak Debangsu Sil Carsten Krebs Nicolai Lehnert 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(49):17859-17863
Non‐heme high‐spin (hs) {FeNO}8 complexes have been proposed as important intermediates towards N2O formation in flavodiiron NO reductases (FNORs). Many hs‐{FeNO}8 complexes disproportionate by forming dinitrosyl iron complexes (DNICs), but the mechanism of this reaction is not understood. While investigating this process, we isolated a new type of non‐heme iron nitrosyl complex that is stabilized by an unexpected spin‐state change. Upon reduction of the hs‐{FeNO}7 complex, [Fe(TPA)(NO)(OTf)](OTf) ( 1 ), the N‐O stretching band vanishes, but no sign of DNIC or N2O formation is observed. Instead, the dimer, [Fe2(TPA)2(NO)2](OTf)2 ( 2 ) could be isolated and structurally characterized. We propose that 2 is formed from dimerization of the hs‐{FeNO}8 intermediate, followed by a spin state change of the iron centers to low‐spin (ls), and speculate that 2 models intermediates in hs‐{FeNO}8 complexes that precede the disproportionation reaction. 相似文献