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81.
Doezé RH Maltman BA Egan CL Ulijn RV Flitsch SL 《Angewandte Chemie (International ed. in English)》2004,43(24):3138-3141
82.
83.
Polystyrene-bound cumulated ylide Ph3PCCO was prepared on a large scale in two steps. It reacts with Grignard compounds, amines and alcohols to give immobilized acyl, amide and ester ylides, respectively. Their Wittig reactions lead to alkenes free of phosphane oxide. Optically pure 5-substituted tetramates were obtained from reactions of resin-bound Ph3PCCO with alpha-ammonium esters in one step. The mycotoxin (-)-tenuazonic acid was accordingly prepared in just three steps. 相似文献
84.
A concise stereocontrolled formal total synthesis of (+/-)-podophyllotoxin using sulfoxide chemistry
A short stereoselective formal total synthesis of (+/-)-podophyllotoxin has been carried out from a sulfoxide, using a one-pot tandem conjugate addition/aldol/electrophilic aromatic substitution reaction to form a tetralin, which was converted into picropodophyllin in two steps. 相似文献
85.
86.
Particles moving along curved trajectories will diffuse if the curvature fluctuates sufficiently in either magnitude or orientation. We consider particles moving at a constant speed with either a fixed or a Gaussian distributed magnitude of curvature. At small speeds the diffusivity is independent of the speed. At larger particle speeds, the diffusivity depends on the speed through a novel exponent. We apply our results to intracellular transport of vesicles. In sharp contrast to thermal diffusion, the effective diffusivity increases with vesicle size and so may provide an effective means of intracellular transport. 相似文献
87.
Ismaili L Truong TT André C Thomassin M Mozer JL Robert JF Xicluna A Refouvelet B Millet J Nicod L Guillaume YC 《Journal of AOAC International》2003,86(2):222-228
The mechanism of the binding of D,L dansyl amino acids to teicoplanin was investigated. Na+ was used as an indicator of the interactions between the solutes and teicoplanin. The number (n) of sodium ions, Na+, excluded from the solute-teicoplanin interface when analyte transfer occurred was determined. A thermodynamic study and enthalpy-entropy compensation were performed to further explore the interaction mechanism. From these results, it was shown that teicoplanin was balanced between 2 conformational states characterized by distinct enantioselective properties. This approach indicates that liquid chromatography (LC) is a useful tool to extract physicochemical and molecular information from retention data. Thus, LC can be used as a complementary technique with the conventional techniques of molecular interaction analysis. 相似文献
88.
Givaja G Blake AJ Wilson C Schröder M Love JB 《Chemical communications (Cambridge, England)》2003,(19):2508-2509
The complexation of palladium(II) by a unique family of [2+2] diiminodipyrromethane macrocycles yields compounds that adopt structures reminiscent of Pac-Man porphyrins. 相似文献
89.
Multidimensional potential energy landscapes (PELs) have a Gaussian distribution for the energies of the minima, but at the same time the distribution of the hyperareas for the basins of attraction surrounding the minima follows a power-law. To explore how both these features can simultaneously be true, we introduce an “egg-box” model. In these model landscapes, the Gaussian energy distribution is used as a starting point and we examine whether a power-law basin area distribution can arise as a natural consequence through the swallowing up of higher-energy minima by larger low-energy basins when the variance of this Gaussian is increased sufficiently. Although the basin area distribution is substantially broadened by this process, it is insufficient to generate power-laws, highlighting the role played by the inhomogeneous distribution of basins in configuration space for actual PELs. 相似文献
90.
Tammy J. Siciliano Michael C. Deblock Semih Durmus Claire A. Tessier 《Journal of organometallic chemistry》2011,696(5):1066-8615
Bis(1,3-dimethylimidazol-2-ylidene)silver(I) nitrate and bis(4,5-dichloro-1,3-dimethylimidazol-2-ylidene)silver(I) nitrate were prepared by reacting the corresponding imidazolium nitrate salts with silver oxide. Bis(1,3-dimethylimidazol-2-ylidene)gold(I) nitrate and bis(4,5-dichloro-1,3-dimethylimidazol-2-ylidene)gold(I) nitrate salts were prepared via transmetallation of their silver precursors with chloro dimethylsulfide gold. The anticancer properties were determined using NCI-H460 lung cancer cells. Efficacy was established by comparison of the gold and silver compounds with cisplatin. 相似文献