定量中子数字成像散射校正的蒙特卡罗模拟

 中子数字成像过程中,散射中子可降低像质致使提取样品的定量信息变得困难。针对该情况,分析了中子微光成像系统图像散射降质的原理,采用点扩展函数的叠加来表征散射中子引起图像降质的过程,借助于蒙特卡罗方法（MC）对点扩展函数进行模拟和建模,将点扩展函数描述为样品厚度以及样品到探测器距离为参量的解析函数,研究了点扩展函数的计算方法。研究结果表明,借助于MC方法构建系统的点扩展函数之解析函数,并利用该函数对中子图像进行散射校正,是一种行之有效的定量中子数字成像散射校正方法。     

光纤麦克风传感探头设计的理论分析

鉴于光纤传感器具有体积小、结构简单、灵敏度高、抗电磁干扰且光纤本身的低损耗、耐腐蚀和安全可靠等优良特性,将光纤传感器应用到麦克风中可使麦克风的体积显著降低而灵敏度和抗电磁干扰性显著提高。提出一种新型反射式光纤麦克风的设计方法,采用Y形单根多模反射式光纤传感探头结构形式,给出了光纤麦克风的系统框图。由光纤出射光场分布理论出发,给出弹性膜片在声场作用下,中心形变大小h与出射光光强调制函数I(Z″)的关系。根据实际应用中有关参数的取值,用Matlab软件模拟出膜片形变后变形量h与光强调制函数I(Z″)的关系曲线。     

浸渍工艺对ZrO2纤维布结构及性能的影响

采用前驱体浸渍工艺制备ZrO2纤维布.利用SEM、XRD研究粘胶织物及ZrO2纤维布的微观结构;测试了ZrO2纤维布的横向抗张强度,研究了浸渍工艺对ZrO2纤维布微观结构、面密度和抗张强度的影响.结果表明:粘胶织物是制备ZrO2纤维布的理想前驱体材料;改善浸渍方式、提高浸渍溶液浓度和温度均能提高ZrO2纤维布的面密度;浸渍方式显著影响单根纤维的致密程度,残液去除方式显著影响纤维的分散程度,采用辊压浸渍和离心甩干去除残液的方式能够显著提高ZrO2纤维布的抗张强度.     

高填方地基中场地地震动参数确定研究

高填方地基的广泛应用,使得对在不同高填方地质情况下,开展研究地震动参数的变化规律有着重要的工程指导意义。根据某机场高填方工程的地基参数,分别概化建立了不同填方厚度、不同压实度、不同厚度原土基的土层计算模型。通过计算得出了场地地震动反应结果。对比研究计算结果,得出了不同高填方地层地质情况下地震动参数的变化特征。为工程设计提供了有效的参数和科学合理的依据。     

苯并咪唑类缓蚀剂的3D-QSAR研究及分子设计

采用比较分子场分析法(CoMFA)和比较分子相似性指数分析法(CoMSIA), 对苯并咪唑衍生物抗盐酸腐蚀的缓蚀性能进行了三维定量构效关系研究, 并使用留一法交叉验证手段对3D-QSAR模型的稳定性及预测能力进行了分析. 结果表明, 立体场、静电场和氢键供体场(电子给体)是影响苯并咪唑缓蚀剂缓蚀性能的主要因素; 所构建的CoMFA模型(q2=0.541, R2=0.996)和CoMSIA模型(q2=0.581, R2=0.987)均具有较好的统计学稳定性和预测能力. 基于3D-QSAR等势图设计出了几种具有较好缓蚀性能的苯并咪唑化合物, 为油气田新型缓蚀剂的研发提供了一种新思路.     

Influence of Control Parameters on the Competition Between Spiral Waves and Target Waves

In this paper we systematically investigate the influence of control parameters on the competition results between spiral waves and target waves. Driving frequency f, amplitude A and injection area n of the input signals are three important parameters and the competition results between spiral waves and target waves are influenced by these three parameters remarkably. Based on these understandings we can control spiral waves effectively by suitable combination these parameters to generate faster target waves. And the effective controllable parameter regions are also studied.     

A New Tetrasubstituted Imidazole Based Difunctional Probe for UV-spectrophotometric and Fluorometric Detecting of Fe3+ Ion in Aqueous Solution

Two new compounds,4-(2-bromophenxl-4,5-diphenyl-imidazol-1-yl)ani 1 ine(probe 1)and 4-[2,4,5-tris(4-bromopheny1)-1H-imidazol-1-y1]aniline(probe 2),were synthesized via a soft and high-efficiency one-pot microwave-assisted method under solvent-free conditions.Their sensing to different metal ions was detected by UV spectrophotometry and fluorescence spectrometry.Probe 2 revealed highly selective and sensitive UV and fluorescence response to Fe^3+ion.Upon the addition of Fe^3+ion,probe 2 showed obvious color change of the solution,conspicuous absorbance enhancement and relatively quick fluorescence quenching.The detection limit for Fe^3+ion was respectively calculated to be 0.72μmol/L(fluorescent detection)and 0.48μmol/L(UV-spectnim detection).Also,probe 2 was bound by Fe^3+ion to tonn a 1:1 complex.Moreover,preliminary application of probe 2 tor detecting Fe^3+ion in aqueous solution was attempted,and satisfying results were obtained.     

Ethylene/1-Hexene Copolymerization with Modified Ziegler-Natta Catalyst

Siloxane compounds were treated with the compounds containing internal donors, such as aromatic ester, phosphate, or 1,3-diether compounds, and the resulting intermediates were further reacted with TiCl₄ to form the modified Ziegler-Natta catalysts for ethylene/1-hexene(E-H) copolymerization. Using the modified Ziegler-Natta catalysts, the effect of the internal donors and the molar ratio of alcohol to magnesium on the catalyst performance was investigated by the orthogonal experiments. The synthetic method of the catalysts was also optimized by choosing the proper way to mix the internal donors. The branch degree, sequence structure, molecular weight, and molecular weight distribution of the copolymer products were determined by Fourier transform infrared spectroscopy(FTIR), carbon-13 nuclear magnetic resonance(¹³C NMR) spectrometry and gel permeation chromatography(GPC). Under the optimum conditions, the catalytic system with tetraethyl orthosilicate and 2,2-dimethoxypropane as the internal donors exhibited the best performance with an activity of 926.74 g copolymer/(g Cat·h^-1). The branch degree, 1-hexene content, and molecular weight distribution of the resulting copolymers reached up to 40 branches/1000C, 5.99% and 5.8, respectively.     

肝素钠掺杂球状聚吡咯的合成及其电化学电容

以生物制剂肝素钠为掺杂剂,由自组装方法合成出平均粒径为100 nm的球状聚吡咯(PPy),用作超级电容器电极材料.透射电镜(TEM)、循环伏安、恒流充放电和电化学交流阻抗测试表明,肝素钠掺杂聚吡咯呈现较好的形貌和电容性质,在电流密度3 mA/cm2下充放电,单电极比电容达到338 F/g.     

一种实时测量入射激光波长及方位的新方法

提出了一种利用CCD和光栅实时测量入射激光波长及方位的新方法。该方法利用成像CCD,通过测量入射激光成像点在电视成像坐标系中的位置来确定激光的入射方位;根据光学系统中成像点位置与光栅入射角和衍射角的几何关系,利用光栅测量入射激光的波长。介绍了该方法的测量原理及光学系统结构,给出了测量入射激光波长及方位的计算表达式,分析了测量误差,并在室内通过测量实验对该方法进行了验证。