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141.
142.
Chemistry of heterocyclic quinoneimines. 9. Reaction of benzo[a]phenoxazin-9-one with C-nucleophiles
V. I. Vysokov G. B. Afanas'eva O. N. Chupakhin 《Chemistry of Heterocyclic Compounds》1988,24(4):446-449
Selective replacement of the hydrogen atom in the 5 position of the aromatic fragment of the substrate by the residue of a C-nucleophile, which is accompanied by rearrangement of the benzoquinoid structure to a naphthoquinoid structure, occurs in the reaction of benzo[a]phenoxazin-9-one with cyanoacetic acid derivatives under conditions of activation of the reagent.See [1] for Communication 8.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 538–541, April, 1988. 相似文献
143.
E. N. Ulomskii T. S. Shestakova S. L. Deev V. L. Rusinov O. N. Chupakhin 《Russian Chemical Bulletin》2005,54(3):726-732
A new in principle method for the synthesis of 6-aryl(hetaryl)-3,5-diamino-1,2,4-triazines by decomposition of pre-synthesized tetrazolo[1,5-b][1,2,4]triazines was developed. The advantages of this method over traditional methods were demonstrated using the synthesis of a modern antiepileptic preparation lamotrigine, as an example.__________Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 713–719, March, 2005. 相似文献
144.
V. N. Charushin L. M. Naumova M. G. Ponizovskii V. G. Baklykov O. N. Chupakhin 《Chemistry of Heterocyclic Compounds》1987,23(9):1010-1013
Reaction of six-membered ring heterocycle-annulated tetrahydroquinoxalines with potassium permanganate in acetone results in the formation of oxidation products containing a common system of conjugated double bonds.For Communication 24, see Ref. [1].Translated from Khimiya Geterotsklicheskikh Soedinenii, No. 9, pp. 1260–1263, September, 1987. 相似文献
145.
146.
147.
O.N. Chupakhin B.V. Rudakov S.G. Alexeev V.N. Charushin V.A. Chertkov 《Tetrahedron letters》1990,31(52):7665-7668
1- Ethyl-3-alkylthio-5-phenyl-l,2,4-triazinium tetrafluoroborates were found to undergo an unusual dimerization on treatment with triethylamine in methanol or ethanol solution. A mechanism for the formation of 4a,4b,9,10-tetrahydro-l,3,6,8,8a,l0a-hexaazaphenanthrenes is proposed. 相似文献
148.
L. A. Bulygina Z. A. Starikova K. K. Babievskii I. A. Utepova V. L. Rusinov O. N. Chupakhin V. I. Sokolov 《Russian Chemical Bulletin》2008,57(10):2214-2216
Optically active cyclopalladated 6-ferrocenyl-2,2′-bipyridine has been studied by circular dichroism and luminescent spectroscopy; a replacement of the chloride ion at palladium with the rhodanide ion and tert-butyl isocyanide molecule has been carried out; molecular structure of the product in the latter case has been determined by X-ray diffraction analysis. 相似文献
149.
V. I. Ovcharenko O. N. Chupakhin I. S. Kovalev E. V. Tretyakov G. V. Romanenko D. V. Stass 《Russian Chemical Bulletin》2008,57(10):2227-2229
The SNH reaction of lithiated 4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-1-oxyl 3-oxide with quinoline N-oxide affords 4,4,5,5-tetramethyl-2-(1-oxidoquinolin-2-yl)-4,5-dihydro-1H-imidazole-1-oxyl 3-oxide. 相似文献
150.
E. B. Gorbunov G. L. Rusinov R. I. Ishmetova V. N. Charushin O. N. Chupakhin 《Russian Journal of Organic Chemistry》2008,44(1):128-132
Aromatic, heteroaromatic, and aliphatic carbonyl compounds reacted with 6-nitro[1,2,4]triazolo[1,5-a]pyrimidine in the presence of a base to give stable σH-adducts at C7. Reduction of the nitro group in the latter is accompanied by tandem autoaromatization of the azine ring and intramolecular
cyclocondensation with formation of the corresponding 6H-pyrrolo[2,3-e][1,2,4]triazolo[1,5-a]pyrimidines.
Original Russian Text ? E.B. Gorbunov, G.L. Rusinov, R.I. Ishmetova, V.N. Charushin, O.N. Chupakhin, 2008, published in Zhurnal
Organicheskoi Khimii, 2008, Vol. 44, No. 1, pp. 130–134.
Dedicated to Full Member of the Russian Academy of Sciences G.A. Tolstikov on his 75th anniversary 相似文献