meso-四(4-吡啶基)卟啉荧光熄灭法测定痕量钯的研究

系统地研究了在十二烷基磺酸钠（ＳＤＳ）存在下，钯（Ⅱ）与ｍｅｓｏ－四（４－吡啶基）卟啉的荧光熄灭反应．提出了高灵敏测定痕量钯（Ⅱ）的荧光分析新方法．该反应在ｐＨ值为４．６的醋酸－醋酸钠缓冲溶液中经沸水浴加热而完成，生成的配合物使卟啉的荧光强度定量熄灭，进而在强酸性条件下测量其荧光强度，发现钯（Ⅱ）的浓度在４～１２０μｇ／Ｌ范围内与显色剂的荧光强度的变化值（ΔＦ）有良好的线性关系．     

Theoretical investigations of the molecular conformation and reorganization energies in the organic diamines as hole‐transporting materials

Recently, organic diamine compounds have been widely used as hole‐transporting materials. In this work, DFT B3LYP method with the 6‐31G^* basis set was performed to investigate the influence of molecular conformation on the reorganization energy of a series of tetra(aryl)benzidine‐based hole‐transport materials. The results indicate that there are two types (i.e., ISB and BD/TPD) of geometric differences of the organic diamines with the relaxation processes. The reorganization energy of the ISB type is lower than that of the BD/TPD type. For the ISB type, the terminal phenyl moiety of the molecular framework plays an important role in determining the Marcus‐type reorganization energy and the central biphenyl moiety does not. A methyl group attached to a terminal phenyl can be used to tune the reorganization energy. According to the statistical analysis, four geometric parameters could affect the reorganization energy of the BD/TPD type. The conformation of either the central biphenyl or the terminal phenyl moiety of the BD/TPD type determines the Marcus‐type reorganization energy associated with the charge transport process at the molecular level. Presumably, this calculation can be employed to predict the electroluminescence (EL) character of the other organic diamines and to improve the design of new hole‐transporting materials in organic light‐emitting devices (OLEDs). Copyright © 2007 John Wiley & Sons, Ltd.     

可调谐集成光学Ti:LiNbO3光波导定向耦合滤波器

波分复用技术是当今光纤通信系统中的关键技术之一。具有增加光纤通信系统容量的巨大潜力,集成光学复用技术对于单模光纤通信系统特别重要本文给出了一种集成光学复用器件的设计和制作,这种集成光学滤波器是在之切LiNbO₃衬底上用非对称钛扩散条波导定向耦合器构成,它适于1.32μm和1.55μm波长耦合滤波。为了使单模光纤和条波导有效耦合,我们研制出了硅V型槽,并给出了一种光纤与波导的连接结构。提供了一种切实可行的途径。     

关于自同构作用下的不变元

文章主要讨论了代数（环）、（双）Ｈｏｐｆ代数中自同构作用下不变元素的性质，得到一些新的结果：设Ａ是有限维半单代数，则ＡｕｔＡ作用下的不变元属于中心，并且举出反例说明这个性质不能一般化到有限维代数、有限维半单（双）Ｈｏｐｆ代数．     

塔里木盆地植物区系的研究

塔里木盆地位于欧亚大陆腹地．该区自然环境独特，植被呈紧缩型分布．植物区系组成贫乏，种子植物１０５属１６５种。分隶３５科，多属于温带成分．特有成分比例较高．生活型以地面芽植物占优势，植被具有温带荒漠的特殊属性．本地区植物区系形成于第三纪．主要来源于华夏植物区系，是华夏植物区系向本地区发展，并在独特环境中蜕变的结果，其中有部分是从本地的荒漠环境中发展起来的．同时还存在古地中海及安哥拉区系成分．区系植物中既有第三纪的种，也有第四纪的种，即在第三纪形成荒漠植物区系，第四纪由于气候进一步变干燥，植物的耐旱适应又有新的发展．     

表面弛豫效应对界面区域CBED的影响

对Al_2O_3颗粒增强铝复合材料与K_2Ti_5O_(13)晶须增强铝复合材料中的增强相/金属界面区域点阵位移场进行CBED研究,并对其进行电子衍射动力学理论模拟计算,结果表明:表面弛豫效应对晶须/铝界面法线方向上位移分量大小的分布影响显著,而对界面切线方向上位移分量的影响很小。这一结果对于解决CBED法测量界面应变场时遇到的表面弛豫效应问题是有意义的。     

Electron-phonon scattering in an asymmetric double barrier resonant tunneling structure

We calculate the electron-phonon scattering rate for an asymmetric double barrier resonant tunneling structure based on dielectric continuum theory, including all phonon modes, and show that interface phonons contribute much more to the scattering rate than do bulk-like LO phonons for incident energies which are approximately within an order of magnitude of the Fermi energy. The maximum scattering rate occurs for incident electron energies near the quantum well resonance. Subband nonparabolicity has a significant influence on electron-phonon scattering in these structures. We show that the relaxation time is comparable to the dwell time of electrons in the quantum well for a typical resonant tunneling structure. Received: 23 December 1997 / Revised: 24 March 1998 / Accepted: 9 March 1998     

铝靶激光反射率的动态研究

本文分析了强激光作用下铝合金靶表面反射率的时间变化规律。利用转镜调Ｑ钕玻璃激光器和积分球装置对铝ＬＹ１２的表面激光反射率动态变化规律进行了测量，得到了功率密度在１０￣６～１０￣９Ｗ／ｃｍ￣２范围内的相应结果。同时，从金属近自由电子模型－Ｄｒｕｄｅ理论出发，对金属铝的电导率与温度变化关系进行了数值模拟，亦得到了相应的反射率变化规律，实验结果与数值模拟结果基本符合。当激光功率密度更同时（１０￣１１～１０￣１５Ｗ／ｃｍ￣２），由等离子体模型和局部热力学平衡（ＬＴＥ）理论，得到了反射率随温度变化的数值模拟结果，与国外的实验结果符合得较好。     

含螺环原碳酸酯齐聚物的合成表征及与环氧树脂的固化反应

合成了一种新的带羟基的螺环原碳酸酯，根据它与ＭＤＩ或ＨＤＩ的不同配比，制备了分子量不同的预聚物，其结构得到了核磁和红外数据的证实。用示差扫描量热仪和红外跟踪环氧树脂及其与预聚物混合后的固化反应过程。