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本文研究了聚乙烯醇存在下,钛(Ⅳ)—氯磺酚S的显色反应,提出了用于硅酸盐矿中测微量钛的分光光度法。 相似文献
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We present the quasinormal frequencies of the massive scalar field in the background of a Schwarzchild black hole surrounded
by quintessence with the third-order WKB method. The mass of the scalar field u plays an important role in studying the quasinormal frequencies, the real part of the frequencies increases linearly as mass
of the field u increases, while the imaginary part in absolute value decreases linearly which leads to damping more slowly than the massless
scalar field. The frequencies have a limited value, so it is easier to detect the quasinormal modes. Moreover, owing to the
presence of the quintessence, the massive scalar field damps more slowly.
相似文献
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Miller MJ Walz AJ Zhu H Wu C Moraski G Möllmann U Tristani EM Crumbliss AL Ferdig MT Checkley L Edwards RL Boshoff HI 《Journal of the American Chemical Society》2011,133(7):2076-2079
Although the antimalarial agent artemisinin itself is not active against tuberculosis, conjugation to a mycobacterial-specific siderophore (microbial iron chelator) analogue induces significant and selective antituberculosis activity, including activity against multi- and extensively drug-resistant strains of Mycobacterium tuberculosis. The conjugate also retains potent antimalarial activity. Physicochemical and whole-cell studies indicated that ferric-to-ferrous reduction of the iron complex of the conjugate initiates the expected bactericidal Fenton-type radical chemistry on the artemisinin component. Thus, this "Trojan horse" approach demonstrates that new pathogen-selective therapeutic agents in which the iron component of the delivery vehicle also participates in triggering the antibiotic activity can be generated. The result is that one appropriate conjugate has potent and selective activity against two of the most deadly diseases in the world. 相似文献
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A converged quantum wave packet study is presented for the unimolecular reaction HOOH → OH+OH induced by the fifth OH-overtone excitation employing an ab initio potential energy surface. All six internal vibrational degrees of freedom are explicitly represented in this simulation for total angular momentum zero. It is found that the decay of the survival probability and of the autocorrelation function is non-exponential and that the long time dynamics is likely due to the superposition of a number of resonance states. The simulated overtone spectrum and rotational product distribution is in good agreement with experimental measurements. It is concluded that: (1) the reaction dynamics is non-statistical on a 30 ps timescale, (2) the observed line width is roughly a factor of 1.7 larger than implied by the reactive lifetimes suggesting that a significant portion of the linewidth is due to intramolecular vibrational energy relaxation, and (3) the quantum reaction rate is suppressed by about a factor of two relative to its classical counterpart. 相似文献
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Fanjiang Meng Dianjun Li Shouhong Sun Fei Chen Heqi Wang Guilong Yang Chunrui Wang Jin Guo Lihong Guo Xinhong Ge Chunlei Shao Shiming Li 《Journal of Russian Laser Research》2012,33(4):362-368
High-power repetitively-pulsed TEA CO2 lasers are excited by a glow discharge, and it turns out to be the arc discharge under some conditions. The arc-discharge is a disadvantageous condition and must be avoided. According to the Faraday electromagnetism induction principle, the arc-discharge monitoring system with a magnetic-field probe is designed for high-power repetitively-pulsed TEA CO2 lasers. The magnetic-field variation induced by the discharge current can be tested, and the discharge state can be distinguished according to the output induction voltage. Experimental results show that the magnetic-field induction voltages generated by a glow discharge and an arc discharge are very different ones. The maximum induction voltage of the glow discharge is 2.0?V, while the minimum induction voltage of the arc discharge is 2.5?C4?V. Three alarm levels are set by measuring the arc-discharge intensities. At the first level, automatic filling?Cexhausting equipment starts to refresh the gas media, at the second level, the laser repetition rate is reduced, and at the third level the laser operation stops immediately. As a result, the working reliability of a high-power repetitively-pulsed TEA CO2 laser system can be improved significantly by using the arc-discharge monitoring system. 相似文献
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We consider a coupled dissipative Stuart?CLandau oscillator models. As the propagation time delay in the coupling varies, stability switches for the trivial solution are found. We discuss the spatio-temporal patterns of bifurcating periodic oscillations by using the symmetric bifurcation theory of delay differential equations combined with representation theory of Lie groups. The existence of multiple branches of bifurcating periodic solution is obtained. We also found that the spatio-temporal patterns of bifurcating periodic oscillations alternate according to the change of the propagation time delay in the coupling, i.e., different ranges of delays correspond to different patterns of dissipative Stuart?CLandau oscillators. Some numerical simulations support our analysis results. 相似文献
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Z2-symmetry systems are considered. Firstly the general forms of Z2-symmetry quadratic polynomial system are given, and then a three-dimensional Z2 equivariant system is considered, which describes the relations of two predator species for a single prey species. Finally, the explicit formulas for determining the Fold and Hopf bifurcations are obtained by using the normal form theory and center manifold argument. 相似文献
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以杂萘联苯聚芳醚超滤膜为支撑层,通过间苯二胺(MPD)、哌嗪(PIP)与均苯三甲酰氯(TMC)的界面聚合制备复合膜.用红外光谱和X射线衍射分别分析了超薄功能层的化学结构与聚集态,用原子力显微镜观察了膜表面形貌,并用统计学方法计算了膜表面的平均粗糙度等特性参数,研究了MPD/PIP比例对膜表层化学结构、形貌和分离性能的影响.结果表明,随着二胺单体MPD/PIP比例从0/100提高到100/0,功能层聚酰胺的聚集态具有从无定形向部分结晶转变的趋势,复合膜表面平均粗糙度由17.8nm提高到71.9nm,膜对NaCl的截留率由26%提高到99%,而通量则由130L.m-2.h-1降低到12L.m-2.h-1.复合膜具有良好的稳定性,温度由25℃提高到80℃,通量提高了2倍左右,而对NaCl的截留率基本不变. 相似文献