Bi-2223/Ag异质结的光生电压效应研究

在50 ～ 340 K不同温度下,利用紫色激光(λ=405 nm)对银/铋锶钙铜氧2223异质结界面进行辐照,观测到明显的光生电压效应,发现光生电压的极性分别在超导转变温度TC与320 K附近发生了反转,排除了激光产生的热电势是产生光生电压的原因,分析表明银/铋锶钙铜氧2223异质结界面处存在内建电场:光生电压由异质结界面处的内建电场分离光生电子-空穴对产生的.超导转变温度TC之下以及320 K以上,内建电场方向从超导体指向金属电极;超导转变温度TC与反向温度320 K之间,内建电场从金属指向超导体.     

反式乙烯基联吡啶表面增强拉曼光谱的密度泛函理论研究

反式乙烯基联吡啶具有极好的拉曼散射信号,经常用做探针分子.利用密度泛函理论(DFT)理论,采用BP86,BPw91和B3LYP等方法,Ag原子使用赝式基组,H,C,N等原子使用6-31+ +G(d,p)基组,计算了反式乙烯基联吡啶与银配合物(t-BPE-Ag)的Raman光谱,并且利用势能分布(PED)计算结果对t-BPE分子Raman光谱和SERS谱进行了详细的归属,DFT理论得到结果说明根据DFT理论计算t-BPE-Ag配合物得到的Raman光谱与实验SERS谱基本一致,并且键连Ag原子越多,与实验值会更接近,t-BPE-Ag配合物HOMO与LUMO的能级差估计在449～912 nm范围内.     

A high-throughput search for direct methanol fuel cell anode electrocatalysts of type PtxBiyPbz

We used a high-throughput method to screen for direct methanol fuel cell anode electrocatalysts in the Pt-Bi-Pb system. Previous studies showed that PtBi and PtPb (both NiAs structure type) were active electrocatalysts for the oxidation of formic acid, but only PtPb was active in oxidizing methanol. We synthesized thin films with continuous composition spreads of the three elements by magnetron sputtering at deposition temperatures from ambient to 510 °C. A fluorescence method was then used to identify compositions that were active toward methanol oxidation. Only films deposited between temperatures of 160 and 400 °C showed electrocatalytic activity. The areas that were active for methanol oxidation showed predominantly the NiAs structure type according to XRD, with optimal activity for compositions near PtBi_0.01Pb_0.53.     

Effect of partonic "wind" on charm quark correlations in high-energy nuclear collisions

In high-energy collisions, massive heavy quarks are produced back to back initially and they are sensitive to early dynamical conditions. The strong collective partonic wind from the fast expanding quark-gluon plasma created in high-energy nuclear collisions modifies the correlation pattern significantly. While the hot and dense medium in collisions at the BNL Relativistic Heavy Ion Collider (sqrt[_s{NN}]=200 GeV) can only smear the initial back-to-back D_D correlation, a clear and strong near side D_D correlation is expected at the CERN Large Hadron Collider (sqrt[_s{NN}]=5500 GeV). This is considered as a signature for the strongly coupled quark-gluon plasma.     

Synthesis of Giant π-Extended Molecular Macrocyclic Rings as Finite Models of Carbon Nanotubes Displaying Enriched Size-Dependent Physical Properties

Bottom-up synthesis of π-extended macrocyclic carbon rings is promising for constructing length- and diameter-specific carbon nanotubes (CNTs). However, it is still a great challenge to realize size-controllable giant carbon macrocycles. Herein, a tunable synthesis of curved nanographene-based giant π-extended macrocyclic rings (CHBC[n]s; n=8, 6, 4), as finite models of armchair CNTs, is reported. Among them, CHBC[8] contains 336 all-carbon atoms and is the largest cyclic conjugated molecular CNT segment ever reported. CHBC[n]s were systematically characterized by various spectroscopic methods and applied in photoelectrochemical cells for the first time. This revealed that the proton chemical shifts, fluorescence, and electronic and photoelectrical properties of CHBC[n]s are highly dependent on the macrocycle diameter. The tunable bottom-up synthesis of giant macrocyclic rings could pave the way towards large π-extended diameter- and chirality-specific CNT segments.     

Regulating silver nanowire size enables efficient photoelectric conversion

The increasing demand for the state-of-the-art transparent conductive electrodes has received great interest in synthesizing silver nanowires(AgNWs) with a uniform diameter that exhibit excellent conductance, transparency, flexibility and mechanical ductility. Herein, we report the controllable synthesis of ultrathin AgNWs with high aspect ratio via a polyol-assisted process.The diameter of AgNWs can be continuously modulated from 20 to 80 nm by simply adjusting the aging time. The selfassembled films fabricated by using AgNWs with a diameter of 20 nm as building blocks enable an excellent performance and show a sheet resistance of ～30 Ω/sq and an optical transmittance of 94%. In addition, such nanowire-based conductive films can keep the excellent flexibility and resistance after bending 10,000 cycles. Similarly, the intelligent dimming films prepared by this AgNW films also have excellent flexibility and stability.     

Experimental and numerical study on instability structure of the supersonic mixing layer (Mc = 0.5)

The parameters of instability wave of supersonic mixing layer(Mc=0.5,M1=3.5/M2=1.4) are measured by flow visualization and calculated by means of two-dimensional direct numerical simulaitons of the compressible Navier-Stokes equations.In both cases of the mixing layer with harmonic disturbance or not,the comparative results indicate that the wavelength of the two-dimensional wave is equal to the vortex spacing in the streamwise direction because the difference between them is less than 1%.However,the measur...     

Time Domain Impedance Boundary Conditions for a Slip Mean FlowBoundary

In modeling the physical condition of an impedance boundary, the assumption of either particle displacement continuity (PDC) or particle normal velocity continuity (PVC) at the interface between the acoustic treatment and the adjacent fluid needs to be used. Although it is well accepted that the impedance boundary condition derived from the PDC is the appropriate impedance boundary condition when there is a slip mean flow at the liner surface, the time domain impedance boundary condition is however unstable due to the Kelvin‐Helmholtz instability associated with the ”vortex sheet.” In this paper, an effective time domain impedance boundary condition for a slip mean flow boundary is proposed and validated. Several relevant issues related to the PDC and PVC are discussed. (© 2004 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Parameter and state estimation algorithm for single-input single-output linear systems using the canonical state space models

This paper presents a new parameter and state estimation algorithm for single-input single-output systems based on canonical state space models from the given input–output data. Difficulties of identification for state space models lie in that there exist unknown noise terms in the formation vector and unknown state variables. By means of the hierarchical identification principle, those noise terms in the information vector are replaced with the estimated residuals and a new least squares algorithm is proposed for parameter estimation and the system states are computed by using the estimated parameters. Finally, an example is provided.     

Time-clustering behavior of sharp fluctuation sequences in Chinese stock markets

Sharp fluctuations (in particular, extreme fluctuations) of asset prices have a great impact on financial markets and risk management. Therefore, investigating the time dynamics of sharp fluctuation is a challenge in the financial fields. Using two different representations of the sharp fluctuations (inter-event times and series of counts), the time clustering behavior in the sharp fluctuation sequences of stock markets in China is studied with several statistical tools, including coefficient of variation, Allan Factor, Fano Factor as well as R/S (rescaled range) analysis. All of the empirical results indicate that the time dynamics of the sharp fluctuation sequences can be considered as a fractal process with a high degree of time-clusterization of the events. It can help us to get a better understanding of the nature and dynamics of sharp fluctuation of stock price in stock markets.