二维光子晶体T型波导分支器数值模拟研究

采用平面波展开法和时域有限差分法,对GaAs二维正方晶格光子晶体的色散特性和带隙结构进行了数值模拟研究,并对GaAs二维光子晶体线缺陷构成的T型波导分支器的微波传输特性进行了模拟和优化。数值模拟结果表明,光子晶体填充比对带隙结构有显著地影响。通过在拐角处插入额外的电介质棒对GaAs二维正方光子晶体T型波导分支器进行优化,数值模拟的结果表明,优化的GaAs二维正方光子晶体T型波导分支器在一阶带隙范围内透射系数将提高到0.96以上。     

一种补偿时间步长限制的粒子模拟-蒙特卡罗碰撞模型

从碰撞次数的概率分布出发,推导出一种补偿蒙特卡罗碰撞模型,采用以正态分布计算得到的平均碰撞次数作为碰撞概率,来补偿传统方法中忽略的多次碰撞。通过模拟不同折合电场强度条件下He气放电产生电子的运动规律,验证了补偿蒙特卡罗碰撞模型的正确性。计算结果表明:补偿蒙特卡罗碰撞模型可以有效地提高计算效率,特别适用于高气压气体放电现象的粒子模拟。     

基于改进模糊聚类法的维修专业设置方法研究

针对当前数字化部队存在维修保障专业冗余、维修人员闲置、维修保障资源使用冲突的问题,对功能相似的维修专业进行合并重组提高维修保障效率。在现有基于装备功能组成的维修专业设置的基础上,运用改进的模糊聚类法对现行二级维修专业进行分类聚合,构建基于装备技术构成的维修专业设置模型。该模型对功能相似的冗余维修专业进行合并,可以减少维修专业冗余和维修人员的闲置,避免维修保障资源使用的冲突,为数字化部队维修专业设置提供可行方案。     

One-step preparation of branched PEG functionalized AIE-active luminescent polymeric nanoprobes

The synthesis of amphiphilic aggregation-induced emission(AIE) dyes based organic nanoparticles has recently attracted increasing attention in the biomedical fields. These AIE dyes based nanoparticles could effectively overcome the aggregation caused quenching effect of conventional organic dyes, making them promising candidates for fabrication of ultrabright organic luminescent nanomaterials. In this work, AIE-active luminescent polymeric nanoparticles(4-NH_2-PEG-TPE-E LPNs) were facilely fabricated through Michael addition reaction between tetraphenylethene acrylate(TPE-E) and 4-arm-poly(ethylene glycol)-amine(4-NH_2-PEG) in rather mild ambient. The 4-NH_2-PEG can not only endow these AIE-active LPNs good water dispersibility, but also provide functional groups for further conjugation reaction. The size, morphology and luminescent properties of 4-NH_2-PEG-TPE-E LPNs were characterized by a series of techniques in detail. Results suggested that these AIE-active LPNs showed spherical morphology with diameter about 100–200 nm. The obtained 4-NH_2-PEG-TPE-E LPNs display high water dispersibility and strong fluorescence intensity because of their self assembly and AIE properties of TPE-E.Biological evaluation results demonstrated that 4-NH_2-PEG-TPE-E LPNs showed negative toxicity toward cancer cells and good fluorescent imaging performance. All of these features make 4-NH_2-PEG-TPE-E LPNs promising candidates for biological imaging and therapeutic applications.     

基于IGAHP-熵-博弈论-Choquet积分的新型装甲装备通用质量特性评价模型研究

针对新型装甲装备通用质量特性评价准则相互关联的问题,在建立评价指标体系的基础上,结合新型装甲装备特点,明确了通用质量特性对评价的要求,运用改进群体层次分析法(Improved Group Analytic Hierarchy Process, IGAHP)确定了指标的主观权重,采用熵权法明确了指标的客观权重,并引入博弈论的思想融合了主客观权重,考虑到评价准则之间的关联性问题,引入了模糊测度的概念,运用Choquet积分实现了新型装甲装备通用质量特性评价,为新型装甲装备通用质量特性的改进研究奠定了基础。     

Comparison of theories for stability of truss structures. Part 2: Computation of critical solution of stability

Critical solution of stability is the optimum solution of cross-sectional area with stability constraint. By applying the linear Eulerian theory of stability, the critical solution with discrete variables for general truss structures is computed in this paper. Then, in order to compare the results with the ones in previous publications and to reveal the applicability of various theories of stability, the critical solutions with continuous cross-sectional areas are computed for several examples by applying various theories of stability.     

利用二次球形配位构筑亲水型隧道框架结构

质子化N,N,N’,N’-四苄基乙二胺可与[Fe(CN)6]3－, [SnCl6]2－和[TeCl6]2－二次球形配位分别形成可容纳客体分子的包结物晶体(1～3). 晶体1通过NH＋…NC－, NH＋…p(NC)和CH…p(NC)组合合成子, 构筑了亲水性层柱隧道结构, 孔径尺寸为1.03 nm×1.12 nm, 两个乙醇分子和两个水分子填充于隧道中; 晶体2通过CH…Cl－合成子, 构筑了亲水性层间隧道结构, 孔径尺寸为0.94 nm×0.73 nm, 三个水分子和两个氯离子填充于隧道中; 晶体3的结构与晶体2相似, 也是通过CH…Cl－合成子, 构筑了层间亲水性隧道结构, 孔径尺寸为0.94 nm×0.72 nm, 两个水分子填充于隧道中.     

手性双胺双膦-铱体系催化芳香酮的高对映选择性氢转移氢化

在异丙醇溶液中,从[Ir(COD)Cl]2和C2-对称的手性双胺双膦配体原位制备了手性能-Ir(Ⅰ)配合物,并直接用于催化几种芳香酮的不对称氢转移氢化。结果表明,该配合物是异丙基苯基酮不对称转移氢化的优秀催化剂,当底物酮与催化剂的摩尔比(S/C)为1200:1时,在室温下反应4h后,得到相应的手性芳香醇的转化率和对映选择性分别高达98%和98%ee.     

A compact wavelength division de-multiplexer based on directional coupling of one-dimensional photonic crystal waveguides

A fundamental dual-channel wavelength division de-multiplexer (WDDM) based on directional coupling of one-dimensional photonic crystal waveguides is presented, and its transmission characteristics of the WDDM are investigated by using finite-difference time-domain method. Calculated results indicate that for this WDDM, without any structural optimization, a high transmittance of more than 95% is observed at output ports. Combining the fundamental dual-channel WDDM with flexible bends of one-dimensional photonic crystal waveguides, we construct a simple and compact four-channel WDDM. Those WDDMs are expected to be applied to highly dense photonic integrated circuits.     

时变等离子体高功率微波频率上转换的粒子模拟

基于电磁波与时变介质相互作用能够实现电磁波频率上转换的原理,通过粒子模拟(PIC)方法对电磁波与时变等离子体薄层相互作用进行模拟,实现了频率由2.45 GHz提升至130 GHz,功率转化效率约为0.39%。探究了等离子体参数(包括等离子体密度、有限的等离子体上升时间以及等离子体薄层厚度)对频率上转换的影响。模拟结果验证了等离子体密度决定上转换频率,与理论结果相符。模拟结果表明,等离子体薄层厚度越大,得到的上转换波的能量越大;等离子体的上升时间越小,上转换波的转换效率和频谱纯度越高。采用等离子体密度21020 cm-3,等离子体厚度1 cm,等离子体上升时间0.04 ns 可以得到可观的130 GHz上转换波输出。