全文获取类型
收费全文 | 1602篇 |
免费 | 201篇 |
国内免费 | 218篇 |
专业分类
化学 | 1238篇 |
晶体学 | 31篇 |
力学 | 95篇 |
综合类 | 12篇 |
数学 | 130篇 |
物理学 | 515篇 |
出版年
2024年 | 3篇 |
2023年 | 32篇 |
2022年 | 62篇 |
2021年 | 77篇 |
2020年 | 54篇 |
2019年 | 76篇 |
2018年 | 53篇 |
2017年 | 57篇 |
2016年 | 86篇 |
2015年 | 71篇 |
2014年 | 98篇 |
2013年 | 93篇 |
2012年 | 142篇 |
2011年 | 168篇 |
2010年 | 96篇 |
2009年 | 87篇 |
2008年 | 101篇 |
2007年 | 95篇 |
2006年 | 88篇 |
2005年 | 71篇 |
2004年 | 66篇 |
2003年 | 47篇 |
2002年 | 37篇 |
2001年 | 24篇 |
2000年 | 32篇 |
1999年 | 37篇 |
1998年 | 20篇 |
1997年 | 19篇 |
1996年 | 16篇 |
1995年 | 21篇 |
1994年 | 13篇 |
1993年 | 10篇 |
1992年 | 16篇 |
1991年 | 9篇 |
1990年 | 10篇 |
1989年 | 4篇 |
1988年 | 3篇 |
1987年 | 9篇 |
1986年 | 9篇 |
1985年 | 1篇 |
1983年 | 1篇 |
1982年 | 3篇 |
1971年 | 2篇 |
1959年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有2021条查询结果,搜索用时 10 毫秒
21.
22.
23.
A facile microwave-assisted ethylene glycol method is developed to synthesize the SnO2 nanoparticles dispersed on or encapsulated in reduced graphene oxide (SnO2-rGO) hybrids. The morphology, structure, and composition of SnO2-rGO are investigated by scanning electron microscopy, transmission electron microscope, thermo-gravimetric analyzer, X-ray diffraction, Raman spectroscopy, and X-ray photoelectron spectroscopy. The electrochemical performance of SnO2-rGO as anode materials for lithium-ion batteries was tested by cyclic voltammetry, galvanostatic charge–discharge cycling, and rate capability test. It is found that the SnO2 nanoparticles with a uniform distribution have p-type doping effect with rGO nanosheets. The as-prepared SnO2-rGO hybrids exhibit remarkable lithium storage capacity and cycling stability, and the possible mechanism involved is also discussed. Their capacity is 1222 mAhg?1 in the first cycle and maintains at 700 mAhg?1 after 100 cycles. This good performance can be mainly attributed to the unique nanostructure, good structure stability, more space for volume expansion of SnO2, and mass transfer of Li+ during cycling. 相似文献
24.
A Cu-TiC alloy, with nanoscale TiC particles highly dispersed in the submicron-grained Cu matrix, was manufactured by a self-developed two-step ball-milling process on Cu, Ti and C powders. The thermostability of the composite was evaluated by high-temperature isothermal annealing treatments, with temperatures ranging from 727 to 1273 K. The semicoherent nanoscale TiC particles with Cu matrix, mainly located along the grain boundaries, were found to exhibit the promising trait of blocking grain boundary migrations, which leads to a super-stabilized microstructures up to approximately the melting point of copper (1223 K). Furthermore, the Cu-TiC alloys after annealing at 1323 K showed a slight decrease in Vickers hardness as well as the duplex microstructure due to selective grain growth, which were discussed in terms of hardness contributions from various mechanisms. 相似文献
25.
26.
27.
金属Zn液态结构变化的研究 总被引:2,自引:0,他引:2
利用TB模型给出的原子间相互作用势详细计算了不同温度下Zn的双体分布函数g(r),结果发现随着温度的不断降低,液态金属Zn的g(r)第一峰变得高而尖,第二峰由弱变强,说明了液态金属Zn的有序度随温度降低而不断增强;利用键对分析技术统计了液态金属Zn在不同温度下的键取向序参数、键对数。键取向序参数及键对数随温度的变化,进一步证明了低温液态的有序度高于高温液态,从而充分说明液态金属在不同温度下有不同的结构形式,而不像人们想象得那样杂乱无章。 相似文献
28.
Haowen Huang Chunhui Li Caiting Qu Shaowen Huang Fang Liu Yunlong Zeng 《Journal of nanoparticle research》2012,14(3):754
In this article, a type of core–shell nanostructure, Au2S/AuAgS/Ag3AuS2-coated gold nanorods (GNRs) with unique optical properties was used as a sensing platform to detect fish sperm DNA (fsDNA).
The prepared core–shell nanorods are positively charged due to the adsorption of the positively charged cetyltrimethylammonium
bromide (CTAB) cations on their surface. fsDNA can form ternary fsDNA–CTAB–nanorod complexes together with CTAB and nanorod,
which provides a useful platform to detect fsDNA through absorption spectra and resonance light scattering (RLS) spectroscopy.
In this sensitive core–shell nanorod sensor, CTAB concentration and the nanoparticle dosage play important roles and have
been investigated. Moreover, the fsDNA–CTAB–nanorod complexes induce a great enhancement of RLS intensity of the core–shell
GNRs and directly proportional to the concentration of fsDNA, reaching a detection limit of about 10−9 mg/mL. This study will be significant for as-prepared core–shell GNRs for future application in biological systems. 相似文献
29.
Yongbo Bian Jin Guo Changzheng Gao Chunguang Li Hong Li Jia Wang Bin Cui Xiaofeng He Chao Li Na Li Guoqiang Li Qiang Zhang Xueqiang Zhang Jibao Meng Yusheng He 《Physica C: Superconductivity and its Applications》2010,470(15-16):617-621
This paper presents a miniaturized high performance high temperature superconducting (HTS) microwave receiver front-end subsystem, which uses a mini stirling cryocooler to cool a high selective HTS filter and a low noise amplifier (LNA). The HTS filter was miniaturized by using specially designed compact resonators and fabricating with double-sided YBCO films on LAO substrate which has a relatively high permittivity. The LNA was specially designed to work at cryogenic temperature with noise figure of 0.27 dB at 71 K. The mini cryocooler, which is widely used in infrared detectors, has a smaller size (60 mm × 80 mm × 100 mm) and a lighter weight (340 g) than the stirling cryocoolers commonly used in other HTS filter subsystem. The whole front-end subsystem, including a HTS filter, a LNA, a cryocooler and the vacuum chamber, has a size of only φ120 mm × 175 mm and a weight of only 3.3 kg. The microwave devices inside the subsystem are working at 71.8 K with a consumed cooling power of 0.325 W. The center frequency of this subsystem is 925.2 MHz and the bandwidth is 2.7 MHz (which is a fractional bandwidth of 0.2%), with the gain of 19.75 dB at center frequency and the return loss better than ?18.11 dB in the pass band. The stop band rejection is more than 60 dB and the skirt slope is exceeding 120 dB MHz?1. The noise figure of this subsystem is less than 0.8 dB. This front-end subsystem can be used in radars and communication systems conveniently due to it’s compact size and light weight. 相似文献
30.