Selective Acetylation of Alcohols and Amines with Ethyl Acetate in the Presence of H<Subscript>6</Subscript>[PMo<Subscript>9</Subscript>V<Subscript>3</Subscript>O<Subscript>40</Subscript>] as the Catalyst

Summary. Acetylation of various alcohols and benzyl amine was tested in the presence of H₆[PMo₉V₃O₄₀], a mixed addenda heteropolyacid, in ethyl acetate under reflux condition. Phenols and anilines are not affected under the reaction conditions. Selective transestrification of alcohols can be achieved in the presence of phenol and aniline derivatives using this method.     

二氧化钛光催化体系中的羟基自由基的测定

通过ESR光谱测定表明TiO2悬浮液在紫外光照射下产生羟基自由基氧化物种.羟基自由基氧化酸性桃红(sulforhodamine B,SRB)使其褪色,在565 nm处用分光光度法测定其吸光度值的变化,可间接测定羟基自由基的生成量.确定了体系的最佳实验条件pH为2.5;SRB浓度为2.0×10-5mol/L;TiO2浓度为0.1 g/L;光照时间为12 min.采用抗坏血酸为羟基自由基清除剂,测定了其自由基清除率,表明拟定该体系可作为筛选抗氧化剂的方法之一.     

The Preparation and Characterization of Highly Dispersed PdO over Alumina for Low‐temperature Combustion of Methane

PdO/Al₂O₃ catalysts prepared by glow discharge plasma treatment followed by thermal calcination show a much higher dispersion and a better catalytic activity for methane combustion at relatively low temperatures. The dispersion of palladium active species by such plasma prepared catalysts is 29.7%, 5.4 times higher than that of conventional catalysts. XPS analysis indicates that a surface enrichment of Pd active species (PdO) has been achieved after plasma treatment. The surface atomic composition of PdO of plasma prepared catalysts reaches 10.5%. XRD characterization also confirms a wellcrystallized PdO phase present on the plasma prepared catalyst. The lightoff temperature of the plasma prepared catalyst is 370°C, 50°C lower than that obtained from the conventional catalyst.     

Synthesis of 2,2＇-（Substituted Arylmethylene）bis（1,6,6-trimethyl 6,7,8,9-tetrahydrophenanthro[1,2-b]furan-10,11-dione） Derivatives

The reactions of tanshinone IIA with aromatic aldehydes have been investigated and several 2, T-（substituted arylmethylene） bis （1,6,6-trimethyl-6,7,8,9-tetrahydrophenanthro[1,2-b]- furan- 10, 11-dione） derivatives were obtained,     

水性丙烯酸酯共聚物交联体系的流变性

用旋转粘度计研究了甲基丙烯酸甲酯／丙烯酸丁酯／丙烯酸三元共聚物水性交联体系的流变性，考察了树脂含量、金属鳌合物含量和氨水水化对其流变性的影响。结果表明：三元共聚物水性交联体系呈非牛顿流体流变行为，具有剪切变稀特性；随树脂含量或鳌合物含量增加，体系的增稠能力得以增强；水化不仅可改善体系的增稠性能，而且可增强体系的非牛顿流变性。     

Determination of imazalil by on-line coupled capillary isotachophoresis with capillary zone electrophoresis

A simple, rapid and reproducible capillary isotachophoretic on-line coupled with capillary zone electrophoresis (CITP-CZE) method for the determination of IMz in food packaging extracts and its residues in apples is described. A good separation of the IMZ from other sample constituents was achieved within 15 minutes without any sample clean up. Method characteristics (linearity, accuracy, intra-assay and detection limit) were determined. Less amount of time involved, sufficient sensitivity and low running cost are the important attributes of CITP-CZE method.     

Kinetic Determination of Microquantities of Rutin by Perturbation of the Bray-Liebhafsky Oscillatory Reaction in an Open System

A kinetic method is described for the microquantitative (microconcentration/microvolume) determination of rutin based on potentiometric monitoring of the concentration perturbations of the Bray-Liebhafsky (BL) oscillatory reaction being in a non-equilibrium stationary state close to a bifurcation point. The experiments are carried out in an open reactor. The response of the matrix system to perturbations by different concentrations of rutin ethanolic solutions is followed by a Pt-electrode. In the concentration range between 7.8×10^–8moldm^–3 and 9.1×10^–6mol dm^–3, we found a linear dependence of the maximal potential shift, E_m, on the logarithm of the rutin concentrations. The unknown concentrations can be determined from the calibration curve up to an accuracy of ±5%. The detection limit is 3.6×10^–8mol dm^–3. The amount of required sample can be as small as 10µL.     

Lanthanide nitrate complexes with 2-azacyclononanone

Thermal behavior of rare earth nitrate complexes with 2-azacyclononanone (AZA) with Ln(NO₃)₃·3(AZA) composition (where Ln=Gd, Er and Ho) was analyzed in kinetic point of view. Kinetic parameters were calculated from thermogravimetric data. All obtained results were similar. The first decomposition step was representative to the loss of ligand and the residue was essentially Ln₂O₃. Furthermore, a reaction path was proposed for the thermal decomposition of the Ln(NO₃)₃·3(AZA).     

Elastic scattering cross sections for 160<Superscript>°</Superscript> and 170<Superscript>°</Superscript>backscattering of 1.40-2.64 MeV protons from natural vanadium

Summary The elastic scattering cross sections of natural vanadium for protons have been measured for beam energies below 2.64 MeV in steps of 10 keV and in the angular 160° and 170°. The overall standard error (Δσ_Exp/σ_Exp) in the measured cross sections is estimated to be better than ±3% at all the beam energies and angles. The results are presented in graphical and tabular forms that should be useful for those who wish to use the cross sections for material analysis.     

固定HCG抗体膜的跨膜电位

高分子膜作为一项新兴技术,在很多领域得到日益广泛的应用.近十几年,随着生物工程和生物传感器的迅速发展,高分子生物功能膜的研究倍受重视.高分子生物功能膜是采用固定化技术,将具有分子识别功能的材料(如酶、抗原、抗体等)固定在高分子膜上而制得的.在固定化膜表面发生的生物化学反应,可以引起膜的荷电状态的变化,从而导致跨膜电位的变化。有关固定化膜的报导较多,但主要限于固定化的方法及其应用方面的研究,而有关高分