Anisotropy of sound velocity for a new PbB4O7 crystal as determined by the laser ultrasonic technique

4 O₇ crystal is a new nonlinear optical crystal. For the first time the anisotropy of the velocities of its longitudinal and surface acoustic waves (SAWs) are determined by laser ultrasonic technique. The velocities of surface waves for X-, Y-, and Z-cut crystals are also calculated. The theoretical calculations of slowness curves are in good agreement with experimental results. The SAW slowness curve is elliptical for Y- or Z-cut crystal wafers, and circular for an X-cut wafer. Received: 27 January 1997/Accepted: 30 July 1997     

Fano effect of a parallel-coupled triple Rashba quantum dot system

Using the nonequilibrium Keldysh Green's function technique, the Fano effect of a parallel-coupled triple Rashba quantum dot system is investigated. The conductance as a function of electron energy is numerically calculated. Compared with the case of a parallel-coupled double quantum dot system, two additional Fano resonance peaks occur in the conductance spectrum. By adjusting the structural parameters, the two Fano resonance peaks may change into the resonance peaks. In addition, the influence of Rashba spin-orbit interaction on the conductance is studied.     

三角形钠原子团簇中的表面等离激元

运用含时密度泛函理论研究等边三角形钠原子团簇中的表面等离激元激发.发现:在团簇尺寸较大时,沿三角形底边和底边中垂线方向激发的共振模式不同,然而沿两方向的吸收光谱线形一样,主要吸收峰的共振能量也相同.低能聚集共振在空间引起电场增强的极大值主要分布在三角形的端点附近.     

Influence of orifice spacing on twin bubbles formation in shear-thinning fluids: Laser image measurement

A laser image system for investigating the influence of orifice spacing on twin bubbles formation in shear-thinning fluid was established. The bubbles formation process at two orifices could be directly visualized and real-time recorded through computer by means of He–Ne laser as light source using the beam expanding and light amplification technology. The shape and size of bubbles generating in carboxymethylcellulose (CMC) aqueous solutions were studied experimentally at the orifices spacing 1D_o, 2D_o and 3D_o (D_o orifice diameter). The results reveal that the minute bubbles can be imaged clearly and amplified without distortion in the higher concentration solutions, and therefore the shape and size of bubbles are obtained accurately. With the increase of orifice spacing, bubble instantaneous volume in shear-thinning fluid decreases at the radial expansion stage but then increases at vertical elongation period, and the deformation and deviation of bubbles forming goes down due to the reduced interaction of adjacent bubble.     

有限时间Lyapunov指数的高精度计算新方法

针对目前有限时间Lyapunov指数(FTLE)计算方法准确度不高和无法获得边界值的问题,基于对偶数理论提出了一种新的高精度计算方法.首先描述了基于有限空间差分方法计算FTLE的缺点和问题:其次介绍了基于对偶数理论的高精度导数计算方法及其显著优点,并将动力系统的柯西一格林形变张量计算问题转化为对偶数空间中非线性微分方程数值求解问题;最后对单摆和非线性Duffing振子两个典型物理动力系统进行了数值实验.结果表明:基于对偶数理论的新方法能有效、方便和高精度地计算出有限时间Lyapunov指数场,并成功识别出所包含的拉格朗日相关结构.     

Influence of precipitant solution pH on the structural, morphological and upconversion luminescent properties of Lu2O3:2%Yb, 0.2%Tm nanopowders

Lutetium oxide nanopowders codoped with Tm³⁺ and Yb³⁺ were synthesized by the reverse-strike co-precipitation method. Effects of precipitant solution pH on the structural, morphological and upconversion luminescent properties of Lu₂O₃:2%Yb, 0.2%Tm nanopowders had been investigated. The results show that pH value of the precipitant (NH₄HCO₃) solution has a significant effect on the particle size, morphology and upconversion emission intensity of the Lu₂O₃:2%Yb, 0.2%Tm nanopowders. All the samples obtained from different pH value of precipitant solution can be readily indexed to pure cubic phase of Lu₂O₃, indicating good crystallinity. The upconversion emission intensity of Lu₂O₃:2%Yb, 0.2%Tm nanopowders obtained from the precipitant solution with pH=11 is the strongest. The enhancement of the upconversion luminescence is suggested to be the consequence of reducing the number of OH⁻ groups and the enlarged nanopowder size. The strong blue, weak red and near infrared emissions from the prepared nanopowders were observed under 980 nm laser excitation, and attributed to the ¹G₄→³H₆, ¹G₄→³F₄ and ³H₄→³H₆ transitions of Tm³⁺ ion, respectively.     

Novel red perovskite phosphor Ca2AlNbO6:Eu for white light-emitting diode application

Eu³⁺-doped perovskite phosphors of Ca₂AlNbO₆ were synthesized from a solid state reaction. A small amount of the Li₂CO₃ flux was found to greatly shorten calcination time and reduce reaction temperature. The structural and optical properties of the samples were systematically investigated. The excitation spectra of Ca₂AlNbO₆:Eu³⁺ reveal two excitation bands at 398 (⁷F₀→⁵L₆) and 466 nm (⁷F₀→⁵D₂), which match well with the two popular emissions from near-UV and blue LED chips. Under blue light excitation, the red emission of Ca₂AlNbO₆:0.05Eu³⁺ is twice more intense than that of (Y_0.95Eu_0.05)₂O₃. The chromaticity coordinates of (Ca_0.95Eu_0.05)₂AlNbO₆ (x=0.654, y=0.346) are close to the standard values (x=0.670, y=0.330) of National Television Standard Committee (NTSC). The optical properties suggest that Ca₂AlNbO₆:Eu³⁺ is an efficient red-emitting phosphor for light-emitting diode applications.     

Phase-matched high-order harmonics by interaction of Ar atoms with high-repetition-rate low-energy femtosecond laser pulses

High-order harmonics are generated by coherent interaction of an intense laser and atoms or molecules[1]. With the development of the intense ultrashort pulse laser, the research of high-order harmonic generation has reached the water-window in spectral region[2] and subfemtosecond in time domain[3]. Especially, the generation and application of subfemtosecond pulse led the study of high-order harmonic generation into a completely new world[4, 5]. It has made the study of ultrafast science fro…     

Electroless deposition of open-end Cu nanotube arrays

Cu nanotube arrays were fabricated by electroless deposition using porous anodic aluminium oxide membranes as templates. This was accomplished by a four-step procedure, i.e. pore-wall modification, polishing treatment, sensitization-activation and electroless deposition. The as-synthesized Cu nanotubes possess controllable inner diameter and open ends.     

Spectroscopic properties of Yb3+-doped Y3Al5O12 nano-ceramics obtained under different sintering pressures

Yb³⁺:YAG nano-ceramics have been obtained by a low temperature/high pressure sintering process. Structural properties have been studied by X-ray diffraction (XRD). Grain sizes and R.M.S micro-strains have been calculated based on the XRD patterns by Rietveld analysis method. Emission spectra and decay curves have been recorded and analyzed. It has been observed that the decay time decreases with the increase of sintering pressure. Presence of Yb³⁺–Yb³⁺ pairs have been detected by cooperative emission spectroscopy.