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61.
62.
An equation to express ion exchange selectivity coefficient was derived and used for calculating that of PPY film with the results obtained by cyclic voltammetric measurement. PPY film was synthesized by electrochemical method in aqueous solution using K4Fe(CN)6 as supporting electrolyte, and the anions were doped into the film. Ion exchange behaviour of doped Fe (CN)63-/4- in the PPY film with Cl?, NO3? or F? ions in solution has been studied, and the corresponding ion exchange selectivity coefficients were determined. 相似文献
63.
Dong Hwan Choi Yoshio Katakura Rieko Matsuda Yuzuru Hayashi Masato Hirobe Yasuhiro Goda Kazuaki Ninomiya Suteaki Shioya 《Analytical sciences》2007,23(2):215-218
The mathematical model for predicting the precision, limit of detection (LOD) and range of quantitation (ROQ) in a competitive enzyme-linked immunosorbent assay (ELISA) proposed by Hayashi et al. (Anal. Chem., 2004, 76, 1295) was validated. The model describes the relative standard deviation (RSD) of concentration estimates by the RSDs of pipetting volumes of analyte, enzyme-conjugated antigen, antibody and substrate solutions, and the standard deviation (SD) of inherent absorbances between the wells in an ELISA plate. For 6 kinds of direct competitive ELISA kits, the LOD and ROQ predicted by the model agreed well with those obtained by experiments with real samples. It was also confirmed that the model is applicable to the prediction of uncertainty that depends on the pipetting error of the viscous antiserum solution. The model was demonstrated to be useful for estimating the LOD and ROQ of competitive ELISA. 相似文献
64.
Won-Sang Chung 《International Journal of Theoretical Physics》2003,42(12):2941-2946
In this paper we use the bosonic realization of ospq(1/2) algebra to obtain its metaplectic representation. The group element for this algebra is shown to be described in terms of the basic hypergeometric function. 相似文献
65.
66.
Xun Dong 《Discrete and Computational Geometry》2006,35(3):457-471
We prove that the bounded complex of an affine oriented matroid is
pure and collapsible. We also generalize Zaslavsky's central
decomposition theorem for hyperplane arrangements to affine
oriented matroids. 相似文献
67.
In this note, the authors resolve an evolutionary Wente's problem associated to heat equation, where the special integrability of det▽u for u ∈ H1(R2,R2) is used. 相似文献
68.
We report X-ray absorption near edge structures (XANES) study of CeAl2 thin films of various thicknesses, 40-120 nm, at Al K- and Ce L3-edges. The threshold of the absorption features at the Al K-edge shifts to the higher photon energy side as film thickness decreases, implying a decreased in Al p-orbital charges. On the other hand, from Ce L3-edge spectra, we observed a decrease in the 5d4f occupancy as the surface-to-bulk ratio increases. The valence of Ce in these thin films, as revealed by the Ce L3-edge spectral results, is mainly trivalent. From a more detailed analysis we found a small amount of Ce4+ contribution, which increases with decreasing film thickness. Our results indicate that the surface-to-bulk ratio is the key factor which affects the electronic structure of CeAl2 thin films. The above observations also suggest that charge transfer from Al to Ce is associated with the decrease of the film thickness. 相似文献
69.
70.
运用一种新的动力学突变检测方法——排列熵(permutation entropy,PE)算法,计算并分析了中国华北地区52个站点1960年—2000年逐日平均气温资料的排列熵演化情况,发现中国华北地区气温在20世纪70年代中期、80年代初均发生了较大突变;进一步用经验模态分解(empirical mode decomposition,EMD)方法对排列熵序列进行逐级平稳化处理,结果发现这一地区的气温突变与准10年这一年代际时间尺度的周期变率密切相关,其原因与太阳黑子活动有着密切联系.
关键词:
华北
突变
排列熵算法
经验模态分解 相似文献