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41.
本文用ab initio计算方法,采用STO-3G基组,对二硝基卤代甲烷CH_2(NO_2)_3(1),CF_2(NO_2)_2(2);CCl_2(NO_2)_2(3)等分子作了单点计算,研究其旋转势能.全构型优化研究了五个具有对称性构型的结构和稳定性,并作了理论分析和探讨. 相似文献
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A de Bruijn covering code is a q‐ary string S so that every q‐ary string is at most R symbol changes from some n‐word appearing consecutively in S. We introduce these codes and prove that they can have size close to the smallest possible covering code. The proof employs tools from field theory, probability, and linear algebra. Included is a table of the best known bounds on the lengths of small binary de Bruijn covering codes, up to R = 11 and n = 13, followed by several open questions in this area. © 2004 Wiley Periodicals, Inc. Random Struct. Alg., 2004 相似文献
44.
The chemometric calibration performance was systematically investigated by two parameters (changing the chemical matrix as well as the signal-to-noise ratio) of the NIR (near-infrared) spectrum. Three different analytes (hexane, cyclohexane, toluene) were selected and heptane was used as a solvent. The degree of spectral difference significantly affected the calibration performance. The largest structural difference between the analyte and the solvent provided the best calibration result for a given signal-to-noise ratio. Additionally, the signal-to-noise ratio of the spectra also directly influenced the calibration performance. Overall, the spectral difference and signal-to-noise ratio were the major factors for governing the chemometric calibration performance, especially in the low-concentration range. 相似文献
45.
激光相干阵列探测中的二元全息光栅 总被引:2,自引:0,他引:2
从外差阵列探测出发,围绕木振光束整形问题,就计算全息位相光栅在激光相干雷达系统中的应用进行了理论及实施方面的研究,得出较好的结果。 相似文献
46.
Mitsunori Oda Yosuke Fukuchi Satoshi Ito Nguyen Chung Thanh Shigeyasu Kuroda 《Tetrahedron letters》2007,48(52):9159-9162
Reactions of pyrrolidine with 2 equiv of aldehydes without any catalyst in a pressurized vessel at 140–200 °C yielded 1,3-disubstituted pyrroles. -Branched aldehydes gave fairly good yields of the corresponding products by this method, which provides a facile non-oxidative procedure for synthesizing 1,3-dialkylpyrroles from inexpensive pyrrolidine and aldehydes. 相似文献
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Hyun-Joo Kim Seog-Tae Han Jeong-Geun Kim Tai-Seong Kim Kwang-Dong Kim Chang-Hoon Lee Moon-Hee Chung Yong-Gi Kim 《International Journal of Infrared and Millimeter Waves》2002,23(1):135-147
The frequency tuning range of waveguide oscillator and its stability depend sensitively on the dimension of the resonance cap. Therefore the driving-point impedances with the various dimensions of the resonance cap are calculated by using HFSS(High Frequency Simulation System). In this paper the comparisons between theoretical results of the driving-point impedances as a function of frequency and that of experimental results are described. The oscillation frequency range could be predicted by using the theoretical evaluation methods which are proposed. It shows that resonance cap size and disc height have an effect on the frequency tuning characteristics of Gunn oscillator. 相似文献
49.
Tumor cells transduced with herpes simplex virus thymidine kinase gene have been intensively applied to the field of positron emission tomography via imaging of its substrate. As a pilot synthesis approach, a facile preparation of 5‐[125I] iodoarabinosyl uridine starting from commercially available uridine is reported herein. 相似文献
50.
Cu nanotube arrays were fabricated by electroless deposition using porous anodic aluminium oxide membranes as templates. This was accomplished by a four-step procedure, i.e. pore-wall modification, polishing treatment, sensitization-activation and electroless deposition. The as-synthesized Cu nanotubes possess controllable inner diameter and open ends. 相似文献