Yangian Realization for Dirac Oscillator

We investigate the realizations of Yangian algebra for a Dirac oscillator. Applying the representation theory of Y(sl(2)) to Dirac oscillator, shift operaors for different energy levelsfor this system are obtained.     

一种多波长窄线宽环形掺铒光纤激光器

本文提出了一种利用多个光纤光栅串接来实现环形掺铒光纤多波长,窄线宽激光器的新颖方法,并在实验中验证了这一设计的合理性,得到了稳定的双波长输出。     

药用NO在金属有机骨架材料中的储存和缓释

多孔金属有机骨架化合物具有发达的纳米级孔道,其对生物活性气体一氧化氮(NO)的储存和缓释显示出独特的物理与化学性质。目前,基本采用两种方式储存NO,一是通过与材料中的不饱和金属络合,另一是与材料中的氨基形成N-Diazeniumdiolate结构,两种方式储存的NO均可通过水置换反应释放,其缓释动力学受材料的化学组成、孔结构和NO的结合强度影响。本文主要综述了近年来金属有机骨架材料储存和释放NO的研究进展。     

Enantioselective total synthesis of (+)-amphidinolide t1

An enantioselective first total syntheis of amphidinolide T1 (1) is described. Amphidinolide T1 (1), a 19-membered macrolide isolated from Amphidinium sp., has shown potent antitumor properties against a variety of NCI tumor cell lines. The synthesis is convergent and involves the assembly of C1-C10 segment 2 and C11-C21 segment 3 by an oxocarbenium ion-mediated alkylation and Yamaguchi macrolactonization sequence. The synthesis of fragment 2 involves an efficient cross metathesis and hydrogenation sequence between the terminal olefins of 5 and 6 to form the C4-C5 carbon-carbon bond. Enol ether 4 is designed to be the surrogate of fragment 3 where the sensitive C16-exo-methylene and the C13-hydroxyl group were protected as the bromoether derivative during the Lewis acid-catalyzed alkylation process. Both stereocenters in fragment 5 as well as the C2 and C3 stereocenters in fragment 4 are accessed by a highly diastereoselective ester-derived titanium enolate-mediated syn-aldol reaction. The bromoether derivative 24 was unraveled at the final stage of the synthesis, providing (+)-amphidinolide T1.     

基于流固耦合的锚索涡激振动抑制方法研究

悬浮隧道锚索的涡激振动会加剧锚索的疲劳破坏,进而影响悬浮隧道的使用寿命和安全.文章在海洋立管涡激振动抑制研究的基础上,考虑悬浮隧道锚索倾斜角度和来流方向的影响,采用流固耦合的数值方法,对整流罩方法和三控制杆方法的抑制效果进行了分析.结果表明,在顺来流方向,两种方法均具有良好的抑振效果;锚索有倾斜的情况下,三控制杆方法的效果会有所提升;但在来流方向改变时,整流罩方法具有较强的适应性.     

Large Optical Nonlinearity Induced by Singlet Fission in Pentacene Films

By creating two triplet excitons from one photo‐excited singlet exciton, singlet fission in organic semiconductors has drawn tremendous attention for its potential applications in boosting the efficiency of solar conversion. Here, we show that this carrier‐multiplication effect can also be used to dramatically improve the nonlinear optical response in organic materials. We have observed large optical nonlinearity with a magnitude of χ⁽³⁾ up to 10^?9 esu in pentacene films, which is further shown to be a result of singlet fission by monitoring the temporal dynamics. The potential application of such efficient nonlinear optical response has been demonstrated with a singlet‐fission‐induced polarization rotation.     

Soliton switching in inhomogeneous nonlocal media

We address a simple way to achieve routing of optical spatial solitons via soliton interactions in the inhomogeneous nonlocal media. We reveal that the variation of the nonlocality disturbs the solitons pairs and splits them into two individual solitons which have the same escape angle but opposite deflection directions. In particular, the escape angle monotonically increases with the increase of the nonlocality variation rate. We demonstrate that the soliton pairs could form self-consistent waveguides that are able to controllably guide a weak signal by any output positions.     

光纤光栅弹簧管压力传感器的压力和温度特性

本文利用弹簧管对于压力的机械放大作用,将弹簧管与光纤光栅悬臂梁调谐技术相结合,研制了一种新颖的光纤光栅弹簧管压力传感器,大大提高了光纤布喇格光栅对压力测量的灵敏度,压力灵敏度系数可达-1.79×10^-4/MPa,比裸光栅提高了两个数量级,在0～12MPa的压力范围内,光纤布喇格光栅中心反射波长的改变与压力成良好的线性关系.同时由于悬臂梁热膨胀效应的影响,光纤光栅的温度灵敏度提高为裸光栅的7倍.     

反相液相色谱二元流动相组成的计算机统计试验全局最佳化

本文用一类非线性规划形式表述的分离模型作为最优化标准,用统计试验全局最佳化方法寻求二元流动相的最佳组成。实验证明:至多5个试验和10分钟左右的计算时间即可找到全局最佳点。