基于垂直结构的有机光发射晶体管制备与性能研究

制备了一种有机垂直光发射晶体管, 兼具有机发光二极管的发光和晶体管的开关调节两个功能.其结构为一个有机发光单元垂直堆叠在一个电容单元上,两单元通过一个共有的源电极连在一起.当电容单元被充电时,积累在源电极的电荷能有效地调节源极与有机层之间的载流子注入势垒,从而达到控制源漏输出电流的大小,最终控制发光单元发光的强度.实验结果表明,器件可提供02 mA的输出电流,其大小可驱动发光单元发光,工作电压（开启电压）为6 V.这种垂直集成方案,实现了器件多功能化,为有机发光二极管有源矩阵驱动的实际应用提供了一种新的解决方法. 关键词： 有机光发射晶体管 垂直 电容     

基于ZBLANⅩⅣPr,Yb频率上转换发光的三维立体显示

本文对利用ZBLANⅩⅣPr,Yb频率上转换发光的三维立体显示做了研究,探讨了其中的一些物理问题.在实验中,我们利用Yb³⁺离子敏化的方法提高Pr³⁺的上转换发光效率;通过降低能引起单频上转换发光的激光强度来提高寻址点和非寻址点在显示过程中的对比度.     

Seasonal variation of 129I species in the Baltic Proper

Iodine speciation plays a significant role in iodine volatilizing into atmosphere from the seas, as well as serving as a biological indicator. Despite this importance, the data on iodine species revealed inconclusive evidence of what factors controlling speciation transformation. We here present new data on profiles of ¹²⁹I speciation in the Baltic Proper during November 2009. Along with the two earlier investigations (August 2006 and April 2007), an assessment of seasonal variation of ¹²⁹I species is presented. The results show that, due to the anoxic nature of Baltic Proper, presence of ¹²⁹IO₃ ^? in the Baltic Proper does not follow an obvious seasonal cycle, as the case with ¹²⁹I^?. Concentrations of ¹²⁹I^? in the Baltic Proper exhibit higher values in summer than the other two seasons (spring and winter), which might be associated with degrading of organic matter and release from sediment to water column that is more pronounced during summer. ¹²⁹I^? in surface water from the three seasons does not reflect the release function from the reprocessing facilities during the period April 2007 to November 2009. Consequently variability of ¹²⁹I^? in surface seawater of the Baltic Proper depends, to some extent, on local physical as well as biochemical conditions.     

Poly(methyl methacrylate‐co‐pentaerythritol tetraacrylate‐co‐butyl methacrylate)‐g‐polystyrene: Synthesis and high oil‐absorption property

Well‐defined high oil‐absorption resin was successfully prepared via living radical polymerization on surface of polystyrene resin‐supported N‐chlorosulfonamide group utilizing methyl methacrylate and butyl methacrylate as monomers, ferric trichloride/iminodiacetic acid (FeCl₃/IDA) as catalyst system, pentaerythritol tetraacrylate as crosslinker, and L ‐ascorbic acid as reducing agent. The polymerization proceeded in a “living” polymerization manner as indicated by linearity kinetic plot of the polymerization. Effects of crosslinker, catalyst, macroinitiator, reducing agent on polymerization and absorption property were discussed in detail. The chemical structure of sorbent was determined by FTIR spectrometry. The oil‐absorption resin shows a toluene absorption capacity of 21 g g^?1. The adsorption of oil behaves as pseudo‐first‐order kinetic model rather than pseudo‐second‐order kinetic model. © 2013 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013     

Synthesis of a benzoxazine with precisely two phenolic OH linkages and the properties of its high‐performance copolymers

A phenolic OH‐containing benzoxazine ( F‐ap ), which cannot be directly synthesized from the condensation of bisphenol F, aminophenol, and formaldehyde by traditional procedures, has been successfully prepared in our alternative synthetic approach. F‐ap was prepared by three steps including (a) condensation of 4‐aminophenol and 5,5'‐methylenebis(2‐hydroxybenzaldehyde) (1) , (b) reduction of the resulting imine linkage by sodium borohydride, and (c) ring closure condensation by formaldehyde. The key starting material, (1) , was prepared from 2‐hydroxybenzaldehyde and s‐trioxane in the presence of sulfuric acid. F‐ap is structurally similar to bis(3,4‐dihydro‐2H‐3‐phenyl‐1,3‐benzoxazinyl)methane ( F‐a, a commercial benzoxazine based on bisphenol F/aniline/formaldehyde) except for two phenolic OHs. The phenolic OHs can provide reaction sites with epoxy and 1,1'‐(methylenedi‐p‐phenylene)bismaleimide (BMI). The structure–property relationships between the thermosets of F‐ap /epoxy, F‐a /epoxy, F‐ap /BMI, and F‐a /BMI were discussed. Experimental data showed that thermosets based on F‐ap /epoxy and F‐ap /BMI provided much better thermal properties than those based on F‐a /epoxy and F‐a /BMI. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 2686–2694     

BRD96N光调制吸收增强现象的实验研究

通过光谱响应特性实验和记录／读出图像实验，研究了基因变异型细菌视紫红质（BR_D96N）分子膜对单色光的光调制特性.发现BR_D96N分子膜在550nm—600nm范围内对调制光有吸收增强的现象，且对此范围内不同波长的单色光其调制程度有差异.利用曲线拟和方法发现550nm—600nm吸收增强的变化过程分为快过程和慢过程，其对应的时间常数分别为30s和5min.利用强度调制器的吸收强度与图像灰度之间的关系，分析了560nm—600nm范围内出现图像反转的实验现象. 关键词： 细菌视紫红质D96N分子膜 光谱响应 吸收增强现象 图像反转现象     

射流抛光多相紊流流场的数值模拟

 理论分析了射流抛光的紊动冲击射流特点,构建了射流抛光的垂直冲击射流模型和斜冲击射流模型。根据射流抛光冲击射流的特点,比较各种流体模型后,采用RNG k-e 模型应用于射流抛光模型的计算。利用计算流体力学理论的二阶迎风格式对抛光模型方程离散,用SIMPLEC数值计算方法对射流抛光过程的紊动冲击射流和离散相磨粒分布进行数值模拟,得到了射流抛光过程的连续流场和离散相磨粒与水溶液的耦合流场,同时计算出了抛光液射流在工件壁面上的压力、速度、紊动强度、剪切力分布和磨粒体积质量分布,分析了垂直射流抛光模型和斜冲击射流抛光模型紊流流场的特点。     

Zero—field—cooled and field—cooled magnetizations and magnetic susceptibility of itinerant ferromagnet SrRuO3

Zero-field-cooled(ZFC) magnetization,field-cooled(FC) magnetization,ac magnetic susceptibility and major hysteresis loops of itinerant ferromagnet SrRuO3 have been measured at magnetic ordering temperatures ranging from 5 to 160K.An empirical model is proposed to calculate the measured ZFC magnetization.The result indicates that the calculated ZFC magnetization compares well with the measured one.Based on the generalized Preisach model.both the ZFC and FC curves are reproduced by numerical simulations.The critical temperature and critical exponents are determined by measuring the ac magnetic susceptibility in different bias magnetic fields at temperatures in the vicinity of the point of phase transition.     

Polymeric ytterbium(ii) complex with pyridyl amido ligands

The reaction of potassium pyridyl amido ligand {L = [N(R)(2-C5H3N-6-Me)]–, R = CH2But} with YbI2(thf)2 afforded the linear polymeric complex [K0.5(L)3YbiiK0.5]n, which was characterized by X-ray structure analysis.