全文获取类型
收费全文 | 172篇 |
免费 | 74篇 |
国内免费 | 138篇 |
专业分类
化学 | 260篇 |
晶体学 | 2篇 |
力学 | 1篇 |
数学 | 3篇 |
物理学 | 118篇 |
出版年
2023年 | 2篇 |
2022年 | 7篇 |
2021年 | 8篇 |
2020年 | 8篇 |
2019年 | 9篇 |
2018年 | 11篇 |
2017年 | 12篇 |
2016年 | 13篇 |
2015年 | 18篇 |
2014年 | 18篇 |
2013年 | 36篇 |
2012年 | 30篇 |
2011年 | 32篇 |
2010年 | 31篇 |
2009年 | 20篇 |
2008年 | 16篇 |
2007年 | 25篇 |
2006年 | 25篇 |
2005年 | 17篇 |
2004年 | 10篇 |
2003年 | 7篇 |
2002年 | 4篇 |
2001年 | 5篇 |
2000年 | 6篇 |
1999年 | 4篇 |
1998年 | 6篇 |
1997年 | 1篇 |
1996年 | 2篇 |
1994年 | 1篇 |
排序方式: 共有384条查询结果,搜索用时 15 毫秒
51.
The annealing process for boron implantation is a crucial step during large size nuclear radiation detector fabrication. It can reduce the lattice defects and the projection straggling. A two-step annealing process for boron implantation was developed instead of a one-step annealing process, and the reverse body resistance of a silicon micro-strip detector was significantly increased, which means that the performance of the detector was improved. 相似文献
52.
以3-硝基邻苯二甲酸和咪唑及2,2’-联吡啶为配体构筑了2种配合物[Zn2(npa)2(Im)4](1)和[Cd2(npa)2(2,2’-bipy)2(H2O)2]·2H2O(2)(npa2-=3-硝基邻苯二甲酸根,Im=咪唑,2,2’-bipy=2,2’-联吡啶)。用元素分析、红外光谱对其进行了表征,并用单晶X-射线衍射测定了配合物的晶体结构;测定了配合物1和2的热稳定性。2个配合物均为双核分子,具有M2C8O4十四元大环结构。配合物1的双核单元通过分子间氢键形成3D网络结构,配合物2的双核单元通过分子间氢键和π-π堆积形成2D层状结构。 相似文献
53.
Scalar field quasinormal modes in the dyadosphere spacetime of charged black hole are studied by using the third-order WKB approximation. From numerical results obtained, we find that the scalar field mass u plays an important role in studying the quasinormal frequencies. With the scalar field mass increases, the real parts increase and the magnitudes of the imaginary parts decrease. Particulary, these change are almost linearly. 相似文献
54.
以混合阳离子-嵌段共聚物表面活性剂为模板合成介孔MCM-48 总被引:1,自引:1,他引:1
利用阳离子和嵌段共聚物混合表面活性剂为模板,在水热条件、碱性介质中成功地合成出MCM-48介孔分子筛。在1TEOS(正硅酸乙酯)∶0.125CTAB(十六烷基三甲基溴化铵)∶nP123(聚氧乙烯-聚氧丙烯-聚氧乙烯三嵌段共聚物)∶0.50NaOH(氢氧化钠)∶61H2O(物质的量的比)体系中,n值在较大范围内(0.000 625~0.018 75)可调。通过粉末X射线衍射(XRD)、N2物理吸附、扫描电镜(SEM)对合成样品进行表征。结果表明:聚氧乙烯-聚氧丙烯-聚氧乙烯三嵌段共聚物(P123)的加入可以更大程度地降低合成MCM-48所需阳离子表面活性剂的用量;合成的MCM-48具有高比表面积、高度有序的孔道结构、较集中的孔径分布和较高的热和水热稳定性。 相似文献
55.
Chen Cao Shu-Jin Bao Dr. Xiao-Yan Tang Ze-Ming Xu Chun-Yan Ni Prof. Dr. Jian-Ping Lang 《化学:亚洲杂志》2021,16(18):2674-2680
Reactions of (NH4)2WS4 with CuCN, CuCN/1,2-bis(4-pyridyl)propane (bppa) or [Cu(MeCN)4]PF6/bppa under different reaction conditions afforded a set of two- or three-dimensional W/Cu/S cluster-based coordination polymers including {[Et4N]2[WS4Cu4(μ-CN)2(μ-I)2]}n ( 1 ), [WS4Cu4(μ-CN)2(bppa)2]n ( 2 ) and {[WS4Cu4(bppa)4](PF6)2}n ( 3 ), respectively. Compound 2 can be readily formed from reaction of 1 with bppa under solvothermal conditions. Compounds 1 and 2 feature two-dimensional networks with a “sql” topology, while 3 possesses a two-fold interpenetrated three-dimensional net with a rare “reo” topology. Compounds 1 – 3 in DMF exhibited different third-order nonlinear optical responses, and they all showed a reverse saturable absorption while 2 held a strong self-focusing effect. 相似文献
56.
Coenzyme NAD+ models can be applied in the photooxygenation of sulfides to sulfoxides as organocatalysts at room temperature. A series of sulfoxides are synthesized easily with this protocol and the possible mechanism is discussed. This procedure provides a reliable approach to the clean production of useful sulfoxides in synthetic chemistry. 相似文献
57.
Bi-Zhu Sun Kui He Xiao-Ming Chen Chun-Yan Chen Zhao Wang Chang-Qun Cai 《Chemical Papers》2015,69(10):1284-1290
The analytical resolution of ketoconazole (KTZ) enantiomers was performed by high-performance liquid chromatography with sulphobutylether-β-cyclodextrin (SBE-β-CD) as a chiral mobile phase additive (chiral selector). Some important factors affecting the resolution of KTZ enantiomers were investigated. In addition, the molecular interaction between KTZ and SBE-β-CD was studied using the UV absorption spectrum and HPLC for an understanding of the resolution process. The results show that the type and concentration of the chiral mobile phase additive, the pH of the mobile phase and the volume fraction of methanol (?MeOH) in the mobile phase all have a clear influence on the resolution of KTZ enantiomers. Under optimal conditions, namely the use of 0.5 mmol L?1 SBE-β-CD as the chiral mobile phase additive, pH of 4.0 and ?MeOH in the mobile phase of 0.6, KTZ enantiomers are resolved with a resolution of 3.74. SBE-β-CD can bind to KTZ with a stability constant of 1157. The chromatographic method can provide the complexation stability constants of (+)-KTZ with SBE-β-CD (K(+)) and (?)-KTZ with SBE-β-CD (K(?)). The intrinsic enantioselectivity was calculated from the K(+) to (K(?)) ratio as 1.34. 相似文献
58.
以dpa衍生配体4-methyl-N,N-bis(pyridin-2-ylmethyl)aniline(L)合成2个单核铜配合物[CuL(NO3)2](1)和[CuL(OAc)(H2O)]ClO4(2),并对其进行了表征。单晶结构显示,配合物1中的Cu中心可以描述为畸变的五角双锥构型,而2的Cu中心为畸变的八面体构型。运用电子吸收和发射光谱法研究了配合物与CT-DNA的键合作用,结果表明2个配合物与DNA的相互作用均为部分插入模式。通过改变浓度、时间进一步检测配合物切割DNA的能力,以及验证其切割机理,结果表明在外界诱导剂存在下,2个配合物均表现出强的切割DNA的能力,其作用机理为氧化切割机理,其中活性氧可能为·OH和1O2。利用MTT法测定了配合物对体外HeLa、HepG-2和SGC-7901肿瘤细胞增殖的抑制能力。 相似文献
59.
Run-Zhi Zhang Ji-Min Yang Li Zhang Chun-Yan Xu 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2014,88(13):2325-2330
The solubilities and refractive indexes in the NH4Cl-CaCl2-H2O system were measured at 50 and 75°C and the phase diagrams were constructed on the basis of the experimental data. The mixing parameters and equilibrium constant K sp were evaluated using the Pitzer ion-interaction model representations. The results obtained were in good agreement with the experimental data. The mixed parameters of Pitzer ion-interaction model and equilibrium constant obtained in the work can furthermore be applied to solubility predictions of more complicated systems containing NH4Cl and CaCl2. 相似文献
60.
用水热法合成得到2个配合物,{[ML2(bipy)(H2O)2]·2bipy}n(M=Cd 1,Zn 2;HL=3-羟基肉桂酸,bipy=4,4′-联吡啶),并对它们进行了红外分析、元素分析,热重分析和单晶结构分析。配合物1和2为异质同晶,单斜晶系,P2/c空间群。中心金属M为六配位,相邻的MⅡ通过4,4′-联吡啶桥联形成沿b轴延伸的一维链状结构,此外还存在未配位的4,4′-联吡啶作为客体分子位于链与链之间。通过对配合物1和2的固态荧光测试表明,它们在绿光区均显示发光效应。 相似文献