Athermal metal-free planar waveguide concave grating demultiplexer

An athermal metal-free planar waveguide concave grating demultiplexer is proposed. We designed the dielectric mirror at the grating facet instead of coating with the metal on the back wall of the grating facet. The transfer-matrix method is introduced to design the dielectric mirror and the reflectance spectral responses of the 2D waveguide structure are simulated using the FDTD software (RSoft, Inc.). To reduce the temperature sensitivity of the device, the three-focal-point method is introduced. We use the design example to show the high-reflectance bandwidth of the dielectric mirror. The fabrication errors are also taken into consideration. By using the numerical model of the scalar diffraction theory, the flat-top spectral responses of the channels are simulated.     

连续激光辐照锗材料损伤的数值模拟研究

 以热传导理论和热弹应力理论为基础,建立了连续平顶激光辐照锗材料的二维非稳态物理模型。对受辐照锗材料的热-力场分布进行数值模拟,比较了激光辐照时间对靶材热-力场分布的影响,探讨了温度场及应力场空间梯度随半径的分布以及激光辐照时间对热-力场空间梯度的影响。计算结果表明,靶材中心温升效应最大,而应力最大值出现在光斑半径外侧;光斑边缘处温度场和应力场梯度绝对值均达到最大,随着辐照时间的延长,材料同一点温度场和应力场梯度均增大。在给定条件下,计算了靶材的损伤时间,应力损伤域值最先达到。     

甲烷再燃还原NO过程中SO2的交互作用

综合Leeds机理,采用Chemkin程序的PFR模块,以Glarborg实验中的柱塞流反应器作为模拟对象,研究了甲烷再燃还原NO过程中SO2交互作用的影响.利用该模型计算甲烷再燃还原NO的结果与Glarborg的实验结果吻合;存在最佳空气过量系数0.8时甲烷再燃还原NO效率最高.进一步分析SO2对再燃还原NO影响的结...     

A method to quantitatively estimate rainfall rate above water surface based on different spectra shapes generated by rainfall

A method combined with the nonlinear least-square regression to quantitatively estimate rainfall rate over water surface from the different spectrum shapes generated by rainfall in some frequency bands was presented.About 2000 min spectrum data generated by rainfall have been collected in an open-lake in Xiamen city.As a result,the spectrum shape in 15-30 kHz is fitted to log-linear law which allows classification of rain into three categories from the spectrum slope:no rain,drizzle(rainfall rate>10 mm/h)and heavy rain(rainfall rate>10 mm/h).Then,rainfall detection is made and rainfall rate is quantified in drizzle time with Logistic model in the frequency bands of 2-15 kHz,and the rainfall rate in heavy rainfall also quantified with log-linear regression.Finally,all measured spectrum data are used to calculate rainfall rate with the algorithm.The results show that the estimated rainfall rates are comparably coincident with the synchronously measured ones.The average error of accumulative rainfall per min is only l%-4%.     

H9N2亚型禽流感病毒细胞适应株细胞致病性和HA、NA基因序列分析

对分离自中国南方的H9N2亚型禽流感病毒A/Chicken/Guangxi/KMⅢ/99(H9N2)进行了MDCK细胞的连续传代和NA基因序列的初步分析.研究发现,病毒接种细胞36 h左右出现细胞病变(CPE),细胞肿胀变圆,聚集,脱落.流感病毒经MDCK细胞连续传代19代后,HA效价与亲代病毒相当.将传代获得的第19代病毒进行基因克隆,与亲代病毒进行序列比较,发现经传代后其HA1羧基端的分子特征是:R-S-S-R,仍属于非低致病力毒株.     

PS微球阵列的制备与表面增强拉曼散射研究

为了研究不同直径PS微球(表面溅射Ag膜)基底的表面增强拉曼散射(SERS)效应,制造了一个新的表面增强拉曼散射(SERS)基底。通过在n型(100)单晶硅片上采用旋涂的方法,得到不同直径的呈六角形有序排列的单层PS微球阵列,然后在PS微球阵列表面磁控溅射一层约30 nm的Ag膜。利用拉曼光谱仪以罗丹明R6G为探针进行了SERS光谱测定,分析比较了不同直径PS微球阵列的表面增强拉曼散射效应,结果表明,溅射有Ag膜的PS微球基底在不同直径下均有不同程度的SERS效应。随着微球直径的增加,PS微球阵列的起伏程度不断加强(粗糙度不断增加),SERS信号逐渐增强,当球直径达到600 nm时,峰的增强信号达到最大,进而获得了一个最优化的SERS基底。同时发现在基底上获得了高信噪比的R6G的SERS光谱, 与苯环相关的一系列CC双键伸缩振动特征谱以及与苯环相关的面内、面外变形振动特征谱均获得了明显增强。这种单一的大区域的拉曼散射基底,呈现出高低相间起伏分布的微观形貌,不同PS微球之间的空隙和深度有很明显的不同,能够显著改善表面Ag膜颗粒的大小和分布,进而提高了PS微球基底的SERS活性。该基底所具有的特殊阵列结构使其在利用SERS探究化学和生物等领域的单分子结构有很大的应用潜力。     

Dynamical behaviors for generalized pendulum type equations with p-Laplacian

We consider a pendulum type equation with p-Laplacian {({\varphi }_p(x^{\prime }))}^{\prime }+{G_x}^{\prime }(t,x)=p(t), where {{\displaystyle \varphi }}_p(u)={\left|u\right|}^{p-\mathrm{2}}u,p>\mathrm{1},G(t,x) and p(t) are 1-periodic about every variable. The solutions of this equation present two interesting behaviors. On the one hand, by applying Moser's twist theorem, we find infinitely many invariant tori whenever {\displaystyle {\int }_{\mathrm{0}}^{\mathrm{1}}p(t)}\mathrm{d}t=\mathrm{0}, which yields the bounded-ness of all solutions and the existence of quasi-periodic solutions starting at t = 0 on the invariant tori. On the other hand, if p(t) = 0 and {G_x}^{\prime }(t,x) has some specific forms, we find a full symbolic dynamical system made by solutions which oscillate between any two different trivial solutions of the equation. Such chaotic solutions stay close to the trivial solutions in some fixed intervals, according to any prescribed coin-tossing sequence.     

Zr-Mn-K催化剂超临界相合成甲醇与异丁醇的研究

用共沉淀法和超临界流体干燥法,分别制备了Ｚｒ－Ｍｎ－Ｋ沉淀型催化剂和超细催化剂．以正十一～十三烷的混合物为超临界介质,在反应温度３６０～４１０℃、合成气压力７．５ＭＰａ、ＧＨＳＶ１７００ｈ－１及介质压力２．０８ＭＰａ的实验条件下,分别考察了超细催化剂和沉淀催化剂的气相和超临界相催化合成气制甲醇、异丁醇的性能．气相和超临界相反应的研究均表明,超细催化剂催化合成异丁醇的活性高于沉淀催化剂;在超临界条件下反应,超细催化剂上产物的异丁醇含量较高（为２３％～３２％）,甲醇含量为２２％～３３％,其它醇均在１０％左右．气相与超临界相反应结果的对比显示,超临界流体促进产物的脱附与传递,提高了ＣＯ的转化率．但超临界流体对甲烷的萃取作用强于对醇的萃取,醇选择性低于气相反应．在超临界条件下合成甲醇、异丁醇仍遵循异丁醇形成的链增长机理,超临界流体改变了链增长各步骤的相对速度,致使超临界相反应的产物分布不同于气相反应的产物分布．     

介质阻挡放电与 CuZSM-5 结合方式对脱除 NOx 的影响

 研究了介质阻挡放电 (DBD) 与 CuZSM-5 结合方式, 即 DBD 和 CuZSM-5 两段分置 (两段法) 或将 CuZSM-5 放入 DBD 区 (一段法), 对脱除氮氧化物的影响. 结果表明, 在 NO/N2 或 NO/C2H4/N2 无氧体系中, DBD 与 CuZSM-5 结合产生的协同效应很小; 在 NO/O2/N2 富氧体系中, DBD 与 CuZSM-5 结合导致氮氧化物转化率下降; 而在 NO/C2H4/O2 /N2 富氧体系中, 在 250 ºC, 空速 12 000 h1, 输入放电能量密度 (Ein) 155 J/L 的条件下, 单纯催化、单纯等离子体放电、一段法和两段法时氮氧化物转化率分别为 39%, 1.5%, 79% 和 52%. 两段法产生了中等程度的协同效应, 主要是第一段等离子体放电产生新稳态物种 (如 NO2, CO 和 CO2 等) 起作用; 而一段法产生的协同效应较大, 主要是由于等离子体放电产生的新稳态物种和激发态短寿命物种 (如 N2*, NO*, CH 和 CN 等) 共同起作用.     

双核mn2+配合物的合成、结构及表面光电性能

双核锰配合物;氢键;表面光电性能;表面光电压光谱