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961.
以金属有机骨架化合物ZIF-8为载体,Pd(C3H5)(C5H5)为金属有机前体,采用金属有机气相沉积方法在室温下制备了Pd@ZIF-8催化剂.Pd纳米粒子在ZIF-8载体上均匀分布,粒子尺寸约为1.5–3.5 nm.Pd@ZIF-8在温和条件下对多种卤代芳烃和苯硼酸的偶联反应均具有良好的活性.ZIF-8优异的化学稳定性不仅保证了其在制备过程中结构的完整,而且赋予了催化剂优异的循环使用性能.反应后Pd@ZIF-8材料的晶体结构、孔结构以及粒子分布均未发生明显的变化.  相似文献   
962.
Chuang  Wei-Chu  Spence  Seymour M. J. 《Meccanica》2019,54(9):1327-1338
Meccanica - The application of performance-based design (PBD) requires the modeling of the dynamic response of the system beyond the elastic limit. If probabilistic PBD is considered, this implies...  相似文献   
963.
964.
This paper deals with a technique to transform a free surface flow problem in the physical domain with an unknown boundary to a standard domain that has a fixed boundary. All the difficulties in the physical domain are reduced to finding an unknown mapping function that can be solved iteratively in a standard domain. A derivation is first presented to express an analytic function in terms of the boundary value of its imaginary part. Using a relationship between boundaries of the standard and the physical domains, a formula for the generalized Schwarz–Christoffel transformation is then developed. Based on the generalized Schwarz–Christoffel integral and the Hilbert transform, a pair of non‐linear boundary integro‐differential equations in an infinite strip is formulated for solving fully non‐linear free surface flow problems. The boundary integral equations are then discretized with quadratic elements in an untruncated standard domain and solved by the Levenberg–Marquardt algorithm. Several examples of supercritical flow past obstructions are provided to demonstrate the flexibility and the accuracy of the proposed numerical scheme. Copyright © 2000 John Wiley & Sons, Ltd.  相似文献   
965.
Thermoplastic and organic‐soluble aromatic polyamides containing both bulky triphenylethane units and flexible ether linkages were prepared directly from 1,1‐bis[4‐(4‐carboxyphenoxy)phenyl]‐1‐phenylethane ( III ) with various aromatic diamines or from 1,1‐bis[4‐(4‐aminophenoxy)phenyl]‐1‐phenylethane ( V ) with various aromatic dicarboxylic diacids via triphenyl phosphite and pyridine. These polyamides had inherent viscosities ranging from 0.71 to 1.77 dL/g. All the polymers easily were dissolved in aprotic polar solvents such as N‐methyl‐2‐pyrrolidone and N,N‐dimethylacetamide, and some even could be dissolved in less polar solvents such as tetrahydrofuran. The flexible and tough films cast from the polymer solutions possessed tensile strengths of 89 to 104 MPa. The polyamides were thermally stable up to 460°C in air or nitrogen. Glass‐transition temperatures of these polyamides were observed in a range of 179 to 268°C via differential scanning calorimetry or thermomechanical analysis. © 2000 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 38: 247–260, 2000  相似文献   
966.
967.
The objective of this paper is to present a methodology of using a two‐step split‐operator approach for solving the shallow water flow equations in terms of an orthogonal curvilinear co‐ordinate system. This approach is in fact one kind of the so‐called fractional step method that has been popularly used for computations of dynamic flow. By following that the momentum equations are decomposed into two portions, the computation procedure involves two steps. The first step (dispersion step) is to compute the provisional velocity in the momentum equation without the pressure gradient. The second step (propagation step) is to correct the provisional velocity by considering a divergence‐free velocity field, including the effect of the pressure gradient. This newly proposed method, other than the conventional split‐operator methods, such as the projection method, considers the effects of pressure gradient and bed friction in the second step. The advantage of this treatment is that it increases flexibility, efficiency and applicability of numerical simulation for various hydraulic problems. Four cases, including back‐water flow, reverse flow, circular basin flow and unsteady flow, have been demonstrated to show the accuracy and practical application of the method. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   
968.
In this paper we investigate strongly regular rings. In terms of W-ideals of rings some characterizations of strongly regular rings are given.  相似文献   
969.
Oxidative addition of diorganyl diselenides to the coordinatively unsaturated, low-valent transition-metal-carbonyl fragment [Mn(CO)(5)](-) produced cis-[Mn(CO)(4)(SeR)(2)](-). The complex cis-[PPN][Mn(CO)(4)(SePh)(2)] crystallized in triclinic space group P&onemacr; with a = 10.892(8) ?, b = 10.992(7) ?, c = 27.021(4) ?, alpha = 101.93(4) degrees, beta = 89.79(5) degrees, gamma = 116.94(5) degrees, V = 2807(3) ?(3), and Z = 2; final R = 0.085 and R(w) = 0.094. Thermolytic transformation of cis-[Mn(CO)(4)(SeMe)(2)](-) to [(CO)(3)Mn(&mgr;-SeMe)(3)Mn(CO)(3)](-) was accomplished in high yield in THF at room temperature. Crystal data for [Na-18-crown-6-ether][(CO)(3)Mn(&mgr;-SeMe)(3)Mn(CO)(3)]: trigonal space group R&thremacr;, a = 13.533(3) ?, c = 32.292(8) ?, V = 5122(2) ?(3), Z = 6, R = 0.042, R(w) = 0.041. Oxidation of Co(2+) to Co(3+) by diphenyl diselenide in the presence of chelating metallo ligands cis-[Mn(CO)(4)(SePh)(2)](-) and cis-[Mn(CO)(4)(TePh)(2)](-), followed by a bezenselenolate ligand rearranging to bridge two metals and a labile carbonyl shift from Mn to Co, led directly to [(CO)(4)Mn(&mgr;-TePh)(2)Co(CO)(&mgr;-SePh)(3)Mn(CO)(3)]. Crystal data: triclinic space group P&onemacr;, a = 11.712(3) ?, b = 12.197(3) ?, c = 15.754(3) ?, alpha = 83.56(2) degrees, beta = 76.13(2) degrees, gamma = 72.69(2) degrees, V = 2083.8(7) ?(3), Z = 2, R = 0.040, R(w) = 0.040. Addition of fac-[Fe(CO)(3)(SePh)(3)](-) to fac-[Mn(CO)(3)(CH(3)CN)(3)](+) resulted in formation of (CO)(3)Mn(&mgr;-SePh)(3)Fe(CO)(3). This neutral heterometallic complex crystallized in monoclinic space group P2(1)/n with a = 8.707(2) ?, b = 17.413(4) ?, c = 17.541(4) ?, beta = 99.72(2) degrees, V = 2621(1) ?(3), and Z = 4; final R = 0.033 and R(w) = 0.030.  相似文献   
970.
New niobium imido complexes (RN)Nb(NEt2)3 (R = Prn, Pri and But), potential precursors to grow niobium containing thin films by chemical vapor deposition (CVD), were prepared by reacting the corresponding (RN)NbCl3py2 complexes (R = Prn, Pri and But; py = pyridine) with LiNEt2 in hydrocarbon solvents. The structures of (RN)NbCl3py2 (R = Pri and But), determined by X-ray crystallography, are mononuclear with distorted octahedral geometries, For each complex, three chloride ligands are cis to the imido ligand and occupy meridional positions. One of two py ligands is cis to and the other is trans to the imido ligand. For (PriN)NbCl3py2, the Nb=NPri bond distance (Å) is 1.733(3) and the ∠Nb=N-Pri angle (°) is 178.0(3). Crystal data: monoclinic, space group P21/n, a = 8.805(2), b = 14.930(4), c = 13, 407(3) Å, β = 93.37(2)°, V = 1759.5(7) Å3, Z = 4, Dc = 1.565 g cm3. For (ButN)NbCl3py2, the Nb=NBut bond distance (Å) is 1.734(4) and the ∠Nb=N-Bul angle (°) is 174.8(4). Crystal data: monoclinic, space group P21/c, a = 9.609(1), b = 13.591(6), c = 14.615(2) Å, β = 90.05(1)°, V = 1908.5(9) Å3, Z = 4, Dc = 1.492 g cm?3.  相似文献   
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