Order from Chaos: Self‐Assembly of Nanoprism from a Mixture of Tetratopic Terpyridine‐Porphyrin Conformers

Porphyrins have been widely used in the self‐assembly of metallo‐supramolecules. In this study, we introduced 2,2':6,2"‐terpyridine (tpy) into a porphyrin core to synthesize a tetratopic building block with multiple conformers. During the self‐assembly with Zn(II), such a mixture of conformers was able to form a discrete nanoprism with all building blocks in one conformation. Detailed characterizations, including NMR, ESI‐MS and traveling‐wave ion mobility‐mass spectrometry (TWIM‐MS), all supported the formation of the desired assemblies. AFM and TEM further confirmed the dimensions of assembled nanoprisms. Moreover, the photophysical properties of the ligands and complexes were noticeably different depending upon size and metal ion center.     

基于Gene Ontology的表达谱与基因功能相似性的相关性研究

聚类是芯片数据分析中被广泛使用的方法。未知基因的功能通常通过其与已知基因在不同生物状态下具有表达相似性来进行预测。然而，还未有人就这种通过表达相似性来进行功能注释的方法的可靠性进行评估。本文利用Gene Ontology对表达相似性和基因功能相似性的相关关系进行了全面的研究。研究表明，尽管表达谱的相似性和基因功能相似性之间有一定的依赖关系，但相关性较弱。在Gene Ontology的三大类中，相对生物过程和分子功能，基因表达谱的相似性更有助于细胞组分的注释。本文的研究结果对于基因功能的预测有一定的指导意义。     

Photochemistry of nonconjugated bichromophoric systems III. Synthesis and photoreaction of poly(ethylene glycol) biscoumarinyloxyacetates

A series of poly(ethylene glycol) biscoumarinyloxyacetatea have been synthesized and their intramolecular photochemical cyclodimerizations have been studied. It was found that only syn-HT configuration products were obtained when these bisesters were directly irradiated in chloroform, and the yields of the products decreased with the increase of the chain length. This photocyclization reaction is a convenient and effective method to synthesize macrocyclic compounds.     

Zs－93硒剂对移植性小鼠S＿（180）肉瘤的抑制作用及其免疫活性

用硒与尿素化合，新生的由杂环有机硒所组成的Ｚｓ－９３硒剂治疗移植性Ｓ１８０肉瘤，有显著的抑瘤作用（Ｐ＜０．０１），其作用表现出一定的剂量效应，以５μｇ／只小鼠为最适，抑瘤率达６０．７６％，治疗组小鼠的Ｔ细胞、ＳＯＤ活性均有增强。     

叔醇脱水成烯反应的溶剂化能力与介电常数的关系

我们用Fe_2(SO_4)_3·xH_2O为催化剂,对2-甲基-2-已醇脱水生成烯烃反应的溶剂化能力及其动力学做了研究,测定了20种不同溶剂中的反应速率常数和以丙至辛6种直链醇为溶剂于不同温度下反应的速率常数,确定了溶剂化能力与溶剂介电常数之间的线性关系。这方面工作尚未见报道。     

Chemical Constituents from Cynoglossum gansuense

Two new alkaloids, i.e., (2,3‐dihydro‐1‐oxo‐1H‐pyrrolo[1,2‐a]pyrrol‐7‐yl)methyl (2S*,3S*)‐3‐[(β‐D ‐glucopyranosyl)oxy]‐2‐hydroxy‐2‐(1‐methylethyl)butanoate ( 1 ) and 1,2‐dihydro‐8‐methoxy‐2‐oxoquinoline‐4‐carboxylic acid ( 2 ), were isolated from the alcoholic extract of the whole plant of Cynoglossum gansuense, together with twelve known compounds Their structures were characterized by means of spectroscopic methods, especially by ¹H‐, ¹³C‐, and 2D‐NMR, as well as by HR‐MS experiments and comparison with literature data.     

气相色谱-质谱联用测定苯乙烯中的阻聚剂对叔丁基邻苯二酚

 建立了气相 质谱联用 (GC/MS)测定苯乙烯中阻聚剂对叔丁基邻苯二酚含量的方法。苯乙烯样品直接进样 ,通过毛细管柱 (HP 1,30m× 0 32mmi.d .× 0 2 5 μm)分离 ,由电子轰击 (EI)源于选择离子监测 (SIM)模式下进行检测。结果表明 ,对叔丁基邻苯二酚含量在 5mg/kg～ 5 0mg/kg时线性关系良好 (r2 =0 9987) ,回收率高 ;与美国材料测试标准ASTMD4 5 90中的分光光度测量法比较具有操作简捷、准确度高的特点。     

Bis[1,1′‐bis(diphenylphosphino)ferrocenium] hexadecachlorotetraantimony(III) ethanol solvate

In the title compound, [Fe(C₁₇H₁₄P)₂]₂[Sb₄Cl₁₆]·C₂H₆O, the Fe atoms lie on inversion centres and the pairs of cyclopentadienyl rings are consequently in a fully staggered conformation. The centrosymmetric anionic clusters formed by [Sb₄Cl₁₆]^4? are surrounded by the cations and are held together by weak C—H?Cl interactions. These formations stack along the a axis to form columns, and the columns are interconnected by another weak C—H?Cl interaction along the b axis.     

A Theoretical Study on the Conductivity of Carbon Doped BNNT

From the changes in energy band, density of state (DOS) and electronic structure calculated by the DFT/B3LYP method, the conductivity of carbon doped boron‐nitride nanotube (BNNT), which is formed by C‐C bond substituting B‐N bond, was discussed. The results indicate that the substitution will strengthen the conductivity of the tube, and its semi‐conductivity might be adjusted by controlling the substitution.