Characterization and optical properties of ZnS nanorods branched out from ZnS film on Zn foil

Complex nanomaterial‐film‐metal substrate architectures, which are composed of ZnS nanorods, island‐like ZnS film and Zn foil, have been formed via a simple vapor deposition route. The growth of the complex nanostructures is initiated by the preferred formation of ZnS film, and ZnS nanorods branches out from ZnS film flows a liquid‐phase epitaxial growth mode. The ZnS nanorod is switched to an angle, which may be attributed to the sudden change of vapor pressure and temperature reduction by the end of vapor deposition process. The room‐temperature photoluminescence spectrum shows that complex ZnS nanostructures have a strong blue emission band centered at about 423 nm and a weak broad green emission band centered at about 515 nm. (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

PERTURBED PERIODIC SOLUTIONFOR BOUSSINESQ EQUATION

We consider the solution of the good Boussinesq equation Utt -Uxx ＋ Uxxxx = （U2）xx, -∞ 〈 x 〈 ∞, t ≥ 0, with periodic initial value U（x, 0） = ε（μ ＋ φ（x））, Ut（x, 0） = εψ（x）, -∞ 〈 x 〈 ∞, where μ = 0, φ（x） and ψ（x） are 2π-periodic functions with 0-average value in [0, 2π], and ε is small. A two parameter Bcklund transformation is found and provide infinite conservation laws for the good Boussinesq equation. The periodic solution is then shown to be uniformly bounded for all small ε, and the H1-norm is uniformly bounded and thus guarantees the global existence. In the case when the initial data is in the simplest form φ（x） = μ＋a sin kx, ψ（x） = b cos kx, an approximation to the solution containing two terms is constructed via the method of multiple scales. By using the energy method, we show that for any given number T 〉 0, the difference between the true solution u（x, t; ε） and the N-th partial sum of the asymptotic series is bounded by εN＋1 multiplied by a constant depending on T and N, for all -∞ 〈 x 〈 ∞, 0 ≤ ｜ε｜t ≤ T and 0 ≤ ｜ε｜≤ε0.     

Schur convexity and Schur multiplicative convexity for a class of symmetric functions with applications

For x = (x ₁, x ₂, …, x _n ) ∈ (0, 1 ] ⁿ and r ∈ { 1, 2, … , n}, a symmetric function F _n (x, r) is defined by the relation

Hopf bifurcations, Lyapunov exponents and control of chaos for a class of centrifugal flywheel governor system

In this paper, complex dynamical behavior of a class of centrifugal flywheel governor system is studied. These systems have a rich variety of nonlinear behavior, which are investigated here by numerically integrating the Lagrangian equations of motion. A tiny change in parameters can lead to an enormous difference in the long-term behavior of the system. Bubbles of periodic orbits may also occur within the bifurcation sequence. Hyperchaotic behavior is also observed in cases where two of the Lyapunov exponents are positive, one is zero, and one is negative. The routes to chaos are analyzed using Poincaré maps, which are found to be more complicated than those of nonlinear rotational machines. Periodic and chaotic motions can be clearly distinguished by all of the analytical tools applied here, namely Poincaré sections, bifurcation diagrams, Lyapunov exponents, and Lyapunov dimensions. This paper proposes a parametric open-plus-closed-loop approach to controlling chaos, which is capable of switching from chaotic motion to any desired periodic orbit. The theoretical work and numerical simulations of this paper can be extended to other systems. Finally, the results of this paper are of practical utility to designers of rotational machines.     

Synthesis, characterization, spectroscopic, and electrochemiluminescence properties of a solvatochromic azacrown-containing cyanoruthenate(II): potential applications in separation and indirect photometric detection of cations and amino acids in HPLC

A new anionic ruthenium(II) complex, (Et4N)[Ru(tpyA18C6)(CN)3] (tpyA18C6=N-[4'-(2,2':6',2'-terpyridyl)]-1,4,7,10,13-pentaoxa-16-azacyclohexadodecane), has been synthesized and characterized. The complex was found to show pronounced solvatochromic behavior and, when dissolved in solution, changed its color from purple to yellow when the solvent system was varied from pure acetonitrile to pure water. Its absorption and emission energies in various solvents showed a linear dependence of the Gutman's acceptor number. The characteristic photoluminescence and electrochemiluminescence (ECL) of the complex were also found to be progressively quenched as the proportion of water in a water/acetonitrile mixture increased. Large changes in the chemical shifts of the 1H NMR and 13C NMR signals of [Ru(tpyA18C6)(CN)3]- in different solvents were observed. The complex has also been demonstrated to serve as a mobile-phase additive in high-performance liquid chromatography for separation of metal cations and amino acids. Comparison studies with the crown-free analogue, (Et4N)[Ru(tpy)(CN)3] (tpy = 2,2':6',2'-terpyridine), showed that other than the ion-pair effect, the allosteric host-guest interaction provided by the presence of the pendant crown was essential to the separation performance of the complex. Indirect detection of nonabsorbing analytes has been achieved by monitoring the absorbance changes of the eluent at the metal-to-ligand charge-transfer (MLCT) absorption band maximum of the complex at 445 nm. The effects of pH, ionic strength, and polarity of the mobile phase as well as the complex concentration on the selectivity and resolution have also been studied.     

Simultaneous determination of 109 pesticides in unpolished rice by a combination of gel permeation chromatography and Florisil column purification, and gas chromatography/mass spectrometry

A multi-residue method is described for the simultaneous analysis of 109 pesticides with different properties in unpolished rice. The range covers organophosphorus, organochlorine, carbamate, and synthetic pyrethroid pesticides. The pesticides were extracted from the sample using ethyl acetate. Most higher molecular weight components such as lipids in the co-extractives were removed by gel permeation chromatography (GPC) with a Bio-bead SX-3 column. A Florisil column with ethyl acetate/hexane as the eluting solvents was used for further cleanup. The pesticides were finally simultaneously determined by gas chromatography/mass spectrometry (GC/MS) in selective ion monitoring (SIM) mode. The average recoveries for most pesticides (spiked level 0.02, 0.1 and 1 microg/g) ranged from 70% to 110%, the relative standard deviation (RSD) was below 20% in every case, and the limit of detection (LOD) varied from 1 to 20 ng/g.     

Investigation on the relationship of proline with wheat anti-drought under soil water deficits

Proline (content) is closely with plant anti-drought, especially under soil water deficits. Many reports from crops and other plants have proved this. Wheat is the second important crop on the globe, whose research in this aspect of importance for food quality, safety, and yield in field. The related difference in physiological indicators and proline content for different soil water treatments among wheat with different genotypes is not clear, which has limited deep study of wheat anti-drought molecular biology and related anti-drought biotechnological breeding. Our current study was focused on the physiological relationship of proline and different genotype wheat anti-drought under soil water deficits. Main results showed that different wheat genotype had different soil water stress threshold. Pro content had closed relationship with soil water stress threshold and wheat anti-drought. Developmental course also impacted Pro content for different wheat genotypes.     

Sensitive single-layered oxygen-sensing systems: polypyridyl ruthenium(II) complexes covalently attached or deposited as langmuir-blodgett monolayer on glass surfaces

Oxygen-sensing elements containing single-layered structures of luminescent indicators of ruthenium(II) bipyridyl complexes on glass surfaces prepared by covalent attachment and LB deposition are described. They are capable of detecting gaseous oxygen concentration by luminescence quenching of the indicator with reproducible and large quenching efficiencies that are comparable to the best quenching efficiencies obtained by other ruthenium(II) polypyridine based complexes immobilized in matrixes. The large quenching efficiencies for both films imply that the probe complexes are effectively quenched by oxygen, which is probably due to the thin single-layered structures with large surface-to-area ratio and short distance between the probe complexes and oxygen.     

Resonant electron transfer and luminescent enhancement in a toluene suspension of Si nanocrystals

Efficient resonant electron transfer from the surface bonding structure to the conduction band of quantum confined Si nanocrystals is observed by Si nanocrystals in a toluene suspension. Based on the electron transfer mechanism, the enhancement of photoluminescence originates from the band-to-band recombination in the p-type Si nanocrystals suspended in a toluene solution. The energy levels of the electrons in the Si nanocrystals chemisorbed with toluene molecules are calculated using the method of linear combination of atomic orbitals, and the characteristics of the obtained density of states is in good agreement with the observed photoluminescence properties.     

Non-zwitterionic structures of aliphatic-only peptides mediated the formation and dissociation of gas phase radical cations

We have investigated how the non-zwitterionic and zwitterionic structures of aliphatic-only tripeptides affect the formation and dissociation of peptide radical cations in the gas phase. The non-zwitterionic forms of the aliphatic-only peptides in their metal complexes play an important role in determining whether the electron transfer pathway predominates. We extended this study by synthesizing permanent non-zwitterionic and zwitterionic forms of aliphatic-only peptide radical cations and exploring their reactivities in the gas phase. Collision-induced dissociation spectra demonstrated the feasibility of generating both non-zwitterionic and zwitterionic forms. Radical cations in zwitterionic forms may indeed mediate the beta and gamma carbon-carbon bond cleavages of leucine and isoleucine side chains from the GlyGlyXle radical peptides; this feature allows leucine and isoleucine residues to be distinguished unambiguously.