Studies on the electrochemiluminescent behavior of luminol on indium tin oxide (ITO) glass

The electrochemiluminescence (ECL) of luminol on indium tin oxide (ITO) glass was high even under a low potential around 0.4-0.5 V, which was quite different from other electrodes such as platinum. ITO nanoparticles were synthesized and used in the research on ITO glass in the ECL process. A static interaction between ITO and luminol is confirmed from UV-vis and fluorescence spectra. Then the ECL enhancement can be supposed to originate from the adsorption of luminol on ITO, which facilitated luminol’s oxidization to the excited state, giving out ECL. On the other hand, ITO can catalyze the generation of reactive oxygen species (ROSs), similar to some other nanomaterials, which also favored the ECL enhancement of luminol.     

Beam spreading of truncated Gaussian beams in Kolmogorov turbulence

Based on the extended Huygens-Fresnel principle and the hard-edge aperture function expanded as the sum of finite-term complex Gaussian function, analytical expression for average intensity of truncated Gaussian beam in Kolmogorov turbulence is derived, and some limiting cases are discussed. The influences of many factors, such as Fresnel number, wavelength, truncation parameter and structure constant on beam spreading are studied with the help of the average intensity formula. We found that the peak value of average intensity decreases and the beam spot spreads with the decrease of Fresnel number. The change of peak intensity against Fresnel number is slower with large aperture than that with small aperture. When Fresnel number is not small enough the influence of turbulence on intensity profiles is so small that can be neglected if structure constant is small.     

Enhanced weak-signal sensitivity in two-photon microscopy by adaptive illumination

We describe a technique to enhance both the weak-signal relative sensitivity and the dynamic range of a laser scanning optical microscope. The technique is based on maintaining a fixed detection power by fast feedback control of the illumination power, thereby transferring high measurement resolution to weak signals while virtually eliminating the possibility of image saturation. We analyze and demonstrate the benefits of adaptive illumination in two-photon fluorescence microscopy.     

Effect of 90 deg ferroelastic twin walls on lattice dynamics of nanocrystalline tetragonal ferroelectric perovskites

A combined transmission electron microscopy (TEM) and Raman spectroscopy study has been performed on nanocrystalline Ba_0.9Sr_0.1TiO₃ (BST) crystals and tubes. TEM investigations revealed the existence of 90 deg ferroelastic twins in the materials. Raman spectra showed an obvious shoulder (∼750 cm^-1) from the broad band at ∼720 cm^-1 that nominally represents the quasimode of E(LO₄) and A₁(LO₃). The intensity of this shoulder increases with the twin population in the nanocrystalline materials, suggesting a correlation between the lattice dynamical characteristics and the long-range ferroelastic strain of the twin wall. The ferroelastic strain is mainly constrained along the c-axis of the BST unit cell, and the effect of this constraint is more pronounced in nanocrystalline materials than in bulks due to a significant wall volume ratio in twinned nano-materials. A₁ phonons showing collective ion dynamics along the c-direction could be then hardened by the strain, while E symmetry exhibiting vibrations perpendicular to the c-axis would be less affected. The theoretically predicted giant LO–TO coupling in tetragonal ferroelectric perovskites [18] suggests that the hardening of the softest A₁(TO₁) mode in A₁ symmetry is accompanied by that of the hardest A₁(LO₃) phonon. Consequently, the shoulder could be ascribed to the ferroelastic strain induced hardening of the quasimode with a considerable contribution from the A₁(LO₃) phonon. PACS 61.72.Ff; 63.22.+m; 77.80.Bh; 77.80.Dj     

Propagation of cosh-Gaussian beams diffracted by a circular aperture in turbulent atmosphere

An analytical formula for the average intensity of cosh-Gaussian (ChG) beams diffracted by an aperture in turbulent atmosphere is derived and some limiting cases are discussed. By using the average intensity formula, some numerical simulation comparisons are made and some special cases are studied, especially the influences of the ChG beam parameter (Ω₀), the propagation distance, the aperture and its size on the average normalized intensity distribution. It is determined that the evolution properties of the average normalized intensity profile in turbulent atmosphere with aperture are different not only from those of free space with aperture but also from those in turbulent atmosphere without aperture. PACS 42.68.Bz; 42.79.Ag; 42.25.Fx     

Interference of arsenic diffusion by argon implantation

In the study of ion implantation, electrically active ions or noble gas ions are often used for damage study, range profiling, etc. Very seldom are both electrically active ions and noble gas ions implanted at about the same depth. In the work reported here, argon and arsenic ion implants and their interference in diffusion were studied by using backscattering, electrical measurements, and transmission electron microscopy (TEM). Several unexpected phenomena were observed.

First, when both Ar and As are implanted in high doses (about 10¹⁶/cm²), at depths around a few hundred nanometers, the Ar significantly hampers the As diffusion, and the As prevents the outdiffusion of the Ar. The interference occurs regardless of which ion is implanted first.

Second, when Si wafers uniformly doped with about 4 × 10¹⁹ As/cm³ are ion-implanted with log¹⁶ Ar/cm² at 130 keV, the As atoms stay uniformly distributed. When the sample is annealed at a temperature between 900 and 1100°C in a nitrogen ambient, however, double peaks for both Ar and As are observed by backscattering. The nonuniform distribution of As after the heat treatment of the uniformly distributed As is puzzling.

Finally, the As profile for an As capsule diffused on a silicon wafer is greatly altered when the wafer has been pre-implanted with Ar. Arsenic atoms tend to build up at the same depth as the Ar atoms.

Several other observations concerning Ar and As are equally puzzling. This paper discusses the observations and some plausible explanations.     

高功率窄线宽光纤激光器的研究进展

近年来,光纤激光器得到了快速发展,且逐步应用于多个领域,功率的进一步提升仍然是光纤激光器的研究热点,光束合成是实现功率提升的重要手段,光束合成要求子光束为窄线宽光纤激光器,因此窄线宽光纤激光器的研究对光束合成功率的提升有重要意义。本文对窄线宽高功率光纤激光器的发展和研究现状进行了详细的介绍,并基于目前的研究现状分析了其发展的主要限制因素,并展望了未来的发展趋势。     

一种新型双参量光纤布喇格光栅传感器的研制

介绍了一种新型的具有双参量测量功能的光纤布喇格光栅传感器.该传感器采用了特殊的结构,安装了两个不同中心波长的光纤布喇格光栅,可以实现两曲面之间狭小间隙的微小位移和温度的同时测量.实验表明,该传感器结构紧凑、体积小,具有良好的重复性和稳定性,位移测量误差不超过±10 μm,温度测量误差不超过±2℃.     

The thermal blooming of high-energy beams from a solid-state heat-capacity laser in the atmosphere

Based on the one-aerosol model, we investigate the influence of thermal blooming on the propagation of solid-state heat-capacity laser (SSHCL) beams in atmosphere. By employing only this aerosol model and ignoring the diffraction and atmospheric turbulence, we evaluate the change in the average transmittance when the incident intensity and the propagation distance are changed. We conclude that the effect of thermal blooming on the propagation of SSHCL beams in the atmosphere is dependent on the incident intensity and the propagation distance. As the incident intensity and propagation distance increase, the influence of thermal blooming on the average transmittance strengthens. However, when the incident intensity is not strong enough, the incident intensity barely affects the average transmittance. PACS 42.65.Jx; 42.55.Rz; 42.68.Ay; 42.68.Jg     

Efficient all solid-state continuous-wave orange laser at 598 nm

We report for the first time a continuous-wave (CW) orange radiation at 598 nm by intracavity sum-frequency generation of 1341 nm Nd:GdVO₄ laser and 1080 nm Nd:YAlO₃ (Nd:YAP) laser. Orange laser is obtained by using a doubly cavity, type-II critical phase matching KTP crystal sum-frequency mixing. With total pump power of 36 W, TEM₀₀ mode orange laser at 598 nm of 268 mW is obtained. The orange power stability in 30 min is better than 3.8%.