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101.
Boyd DR Sharma ND King AW Shepherd SD Allen CC Holt RA Luckarift HR Dalton H 《Organic & biomolecular chemistry》2004,2(4):554-561
Direct and indirect evidence, of unexpected stereoselective reductase-catalysed deoxygenations of sulfoxides, was found. The deoxygenations proceeded simultaneously, with the expected dioxygenase-catalysed asymmetric sulfoxidation of sulfides, during some biotransformations with the aerobic bacterium Pseudomonas putida UV4. Stereoselective reductase-catalysed asymmetric deoxygenation of racemic alkylaryl, dialkyl and phenolic sulfoxides was observed, without evidence of the reverse sulfoxidation reaction, using anaerobic bacterial strains. A purified dimethyl sulfoxide reductase, obtained from the intact cells of the anaerobic bacterium Citrobacter braakii DMSO 11, yielded, from the corresponding racemates, enantiopure alkylaryl sulfoxide and thiosulfinate samples. 相似文献
102.
Decomposition of N2O has been studied on pure La2CuO4, La2CuO4 with 5 and 10 wt. % LaNi5 and oxidized LaNi5 in the temperature range of 240–490 °C at 50 and 200 Torr initial pressures of N2O. The addition of LaNi5 decreases the energy of activation compared to that of La2CuO4 which has been explained based on the dispersity of NiO over La2CuO4.
N2O La2CuO4 La2CuO4 LaNi5 5–10 .%, 240–490°C N2O 50 200 . LaNi5 , . NiO La2CuO4.相似文献
103.
104.
Richard H. Jones Christopher A. Ramsden Helen L. Rose 《Journal of heterocyclic chemistry》1996,33(4):1031-1034
Irradiation of 2-phenylbenzimidazole ( 3 ) in the presence of methyl acrylate (20 equivalents) using a medium pressure mercury lamp gives methyl 2-(2-phenylbenzimidazol-1-yl)propionate ( 4 ) (75%) whose structure has been confirmed by an X-ray analysis. A similar reaction using acrylonitrile gave only a low yield (1%) of the corresponding propionitrile derivative 5 . A mechanism involving photoexcitation of 2-phenylbenzimidazole ( 3 ) followed by sequential single electron transfer, proton transfer and radical coupling is proposed to account for the formation of the novel photoadducts 4 and 5 . 相似文献
105.
Two simple modification methods for ordered mesoporous silicas were examined and compared. MCM-41 molecular sieve was physically coated with 4-cyano-4-biphenyl [4(4-pentenyloxy)]benzoate (CBPB) and chemically modified using trimethylethoxysilane. The structural and surface properties of the obtained materials were characterized using elemental analysis, thermogravimetry and nitrogen adsorption over a wide pressure range.It was shown that the pore size of the MCM-41 material was not decreased significantly after the coating procedure, even for high loadings of CBPB. Moreover, low pressure adsorption measurements indicated that significant fractions of the MCM-41 surface were not covered by CBPB, even for high CBPB loadings, which suggests that the attained coverage may be very nonuniform. The chemical bonding procedure led to a marked decrease in the pore size and change of surface properties.It was demonstrated that nitrogen adsorption measurements provide a means of a thorough characterization of modified MCM-41 materials, allowing to estimate the surface area, pore volume and pore size distribution. Moreover, low pressure adsorption data can be used to qualitatively or semiquantitatively assess the surface coverage of the coated/bonded organic groups, which may be used to estimate the uniformity of the coverage and therefore, the usefulness of the modification procedure. 相似文献
106.
Addition of palladium acetate to 2-(dicyclohexylphosphino)-phenylferrocene gave palladacycle 16 that is a very effective precatalyst for the Suzuki cross-coupling of aryl chlorides at room temperature (1 mol% 16) or 60 degrees C (> or = 0.01 mol% 16). 相似文献
107.
The total synthesis of taurospongin A by two new approaches has been achieved where pi-allyltricarbonyliron lactone complexes have been used to control highly stereoselective additions of the nucleophiles to a carbonyl unit located in the side chain of these complexes. 相似文献
108.
Baber RA Charmant JP Cook AJ Farthing NE Haddow MF Norman NC Orpen AG Russell CA Slattery JM 《Dalton transactions (Cambridge, England : 2003)》2005,(19):3137-3139
Treatment of the diborane(4) compound B(2)(NMe(2))(4) with aniline or 2,6-dimethylaniline results in the primary amido compounds B(2)(NHR)(4)(R = Ph, 2,6-Me(2)C(6)H(3)); subsequent treatment with n-BuLi in toluene in each case affords the first examples of anionic imidodiborates namely Li(4)(thf)(6)B(2)(NPh)(4) and Li(4)(thf)(4)B(2)(N-2,6-Me(2)C(6)H(3))(4); all complexes have been characterised crystallographically. 相似文献
109.
The results detail a novel methodology for the electrochemical determination of ammonia based on its interaction with hydroquinone in DMF. It has been shown that ammonia reversibly removes protons from the hydroquinone molecules, thus facilitating the oxidative process with the emergence of a new wave at less positive potentials. The analytical utility of the proposed methodology has been examined with a linear range from 10 to 95 ppm and corresponding limit-of-detection of 4.2 ppm achievable. Finally, the response of hydroquinone in the presence of ammonia has been examined in the room temperature ionic liquid 1-ethyl-3-methylimidazolium bis(trifluormethylsulfonyl)imide, [EMIM][N(Tf)2]. Analogous voltammetric waveshapes to that observed in DMF were obtained, thereby confirming the viability of the method in either DMF or [EMIM][N(Tf)2] as solvent. 相似文献
110.
Five new cyclophane host molecules (corrals) are prepared by linking together two α,α′-di(4-hydroxyphenyl)-1,4-diisopropylbenzene or α,α′-di(3,5-dimethyl-4-hydroxyphenyl)-1,4-diisopropylbenzene units with two permethylene spacers. Three small cyclophane hosts (boxes) are synthesized by cyclization of α,α′-di(4-hydroxyphenyl)-1,4-diisopropylbenzene with di(bromomethyl)benzene compounds. Solid-state structures of one corral and one box are reported. 相似文献