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71.
We show, using extensive molecular dynamics simulations, that the dynamics of the electric double layer (EDL) is very much dependent on the wettability of the charged surface on which the EDL develops. For a wetting surface, the dynamics, characterized by the so-called zeta potential, is mainly controlled by the electric properties of the surface, and our work provides a clear interpretation for the traditionally introduced immobile Stern layer. In contrast, the immobile layer disappears for nonwetting surfaces, and the zeta potential deduced from electrokinetic effects is considerably amplified by the existence of a slippage at the solid substrate. 相似文献
72.
Huge fluctuations in weight measurements at the bottom of a two-dimensional vertical sheet of grains
Weight measurements at the bottom of a quasi-2D vertical sheet of static cohesionless grains are carried out. The grains are held between two coaxial cylinders. This peculiar setup allows us to set either periodic or fixed lateral boundary conditions. Huge relative fluctuations in weight measurements appear in case of fixed lateral walls. This may be related to some indetermination in the mobilization state of friction forces on lateral walls. This argument would hold for any piling, but would lead to huge fluctuations in 2D systems only, because of averaging effects in 3D. 相似文献
73.
Justina Grabowska Karuna Kar Nanda R.T. Rajendra Kumar J.P. Mosnier M.O. Henry Simon B. Newcomb Patrick McNally Lisa OReilly Xu Lu Enda McGlynn 《Superlattices and Microstructures》2007,42(1-6):327
Self-organized ZnAl2O4 nanostructures with the appearance (in SEM) of high aspect ratio horizontal nanowires are grown on uncatalysed c-sapphire by vapour phase transport. The nanostructures grow as three equivalent crystallographic variants on c-sapphire. Raman and cathodoluminescence spectroscopy confirm that the nanostructures are not ZnO and TEM shows that they are the cubic spinel, zinc aluminate, ZnAl2O4, formed by the reaction of Zn and O with the sapphire substrate. 相似文献
74.
Theoretical and experimental study of differential group delay and polarization dependent loss of Bragg gratings written in birefringent fiber 总被引:3,自引:0,他引:3
Sébastien Bette Christophe Caucheteur Marc Wuilpart Patrice Mégret 《Optics Communications》2007,269(2):331-337
In this paper, we completely study the wavelength dependency of differential group delay (DGD) and polarization dependent loss (PDL) for Bragg gratings written in birefringent fibers. Based on the coupled mode theory, we present analytical expressions for the evolution with wavelength of the transmission coefficient, the DGD and the PDL. The wavelength dependencies of these evolutions on the birefringence are then discussed. Experimental results are finally presented for an apodized FBG written in a bow-tie fiber. A very good agreement between theory and experience is reported, confirming the validity of the theoretical analysis. 相似文献
75.
Abdollah Sarani Nathalie De GeyterRino Morent Christophe Leys 《Applied Surface Science》2011,257(20):8737-8741
In this paper, an atmospheric pressure plasma jet sustained in pure argon and an argon/water vapour mixture has been used to modify the surface of polypropylene (PP) films. The gas temperature of the plasma jet was found to be 625 K in an active zone between the electrodes and was found to increase in the afterglow. Based on these results, the PP films are placed as close as possible to the edge of the capillary in order to avoid thermal damage to the polymer. XPS results on the untreated and modified PP samples revealed incorporation of a significant amount of oxygen on the polymer surface, however, this oxygen inclusion is more pronounced for the argon/water vapour jet due to the higher radicals density in the jet afterglow. One can therefore conclude that adding water vapour to an argon plasma jet can be a convenient way to increase the efficiency of plasma surface modification. 相似文献
76.
Vladislav Ganine Denis Laxalde Christophe Pierre 《Journal of sound and vibration》2011,330(3):445-460
Light and flexible rotating parts of modern turbine engines operating at supercritical speeds necessitate application of more accurate but rather computationally expensive 3D FE modeling techniques. Stacked disks misalignment due to manufacturing variability in the geometry of individual components constitutes a particularly important aspect to be included in the analysis because of its impact on system dynamics. A new parametric model order reduction algorithm is presented to achieve this goal at affordable computational costs. It is shown that the disks misalignment leads to significant changes in nominal system properties that manifest themselves as additional blocks coupling neighboring spatial harmonics in Fourier space. Consequently, the misalignment effects can no longer be accurately modeled as equivalent forces applied to a nominal unperturbed system. The fact that the mode shapes become heavily distorted by extra harmonic content renders the nominal modal projection-based methods inaccurate and thus numerically ineffective in the context of repeated analysis of multiple misalignment realizations. The significant numerical bottleneck is removed by employing an orthogonal projection onto the subspace spanned by first few Fourier harmonic basis vectors. The projected highly sparse systems are shown to accurately approximate the specific misalignment effects, to be inexpensive to solve using direct sparse methods and easy to parameterize with a small set of measurable eccentricity and tilt angle parameters. Selected numerical examples on an industrial scale model are presented to illustrate the accuracy and efficiency of the algorithm implementation. 相似文献
77.
Valette J Park JY Gröhn O Uğurbil K Garwood M Henry PG 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2007,189(1):1-12
In NMR spectroscopy, volume selection can be advantageously achieved using adiabatic pi pulses, which enable high bandwidth and B(1) insensitivity. In order to avoid the generation of non-linear phase profiles and the subsequent signal loss caused by incoherent averaging, adiabatic pi pulses are usually used in pairs for volume selection in each spatial dimension. Alternatively, when performing spectroscopic imaging (SI), a high enough spatial resolution results in negligible phase dispersion within each pixel. This allows using only one pulse per selected spatial dimension, resulting in a reduced echo-time and reduced power deposition. In this work, the feasibility of such an approach is explored theoretically and numerically, allowing the derivation of explicit conditions to obtain SI images without artifact. Adequate spatial and spectral post-processing procedures are described to compensate for the effect of non-linear phase profiles. These developments are applied to SI in the rat brain at 9.4 T, using a new adiabatic sequence named Pseudo-LASER. 相似文献
78.
B. Doggett S. Chakrabarti R. OHaire A. Meaney E. McGlynn M.O. Henry J.P. Mosnier 《Superlattices and Microstructures》2007,42(1-6):74
Phosphorus-doped ZnO films were grown by pulsed laser deposition using a ZnO:P2O5-doped target as the phosphorus source with the aim of producing p-type ZnO material. ZnO:P layers (with phosphorus concentrations of between 0.01 to 1 wt%) were grown on a pure ZnO buffer layer. The electrical properties of the films were characterised from temperature dependent Hall-effect measurements. The samples typically showed weak n-type conduction in the dark, with a resistivity of 70 Ω cm, a Hall mobility of μn0.5 cm2 V −1 s−1 and a carrier concentration of n3×1017 cm−3 at room temperature. After exposure to an incandescent light source, the samples underwent a change in conduction from n- to p-type, with an increase in mobility and decrease in concentration for temperatures below 300 K. 相似文献
79.
Nathalie Henrich Gunilla Sundin Daniel Ambroise Christophe d'Alessandro Michle Castellengo Boris Doval 《Journal of voice》2003,17(4):481-494
This study aims to explore the perceptual relevance of the variations of glottal flow parameters and to what extent a small variation can be detected. Just Noticeable Differences (JNDs) have been measured for three values of open quotient (0.4, 0.6, and 0.8) and two values of asymmetry coefficient (2/3 and 0.8), and the effect of changes of vowel, pitch, vibrato, and amplitude parameters has been tested. Two main groups of subjects have been analyzed: a group of 20 untrained subjects and a group of 10 trained subjects. The results show that the JND for open quotient is highly dependent on the target value: an increase of the JND is noticed when the open quotient target value is increased. The relative JND is constant: ΔOq/Oq = 14% for the untrained and 10% for the trained. In the same way, the JND for asymmetry coefficient is also slightly dependent on the target value–an increase of the asymmetry coefficient value leads to a decrease of the JND. The results show that there is no effect from the selected vowel or frequency (two values have been tested), but that the addition of a vibrato has a small effect on the JND of open quotient. The choice of an amplitude parameter also has a great effect on the JND of open quotient. 相似文献
80.
We demonstrate experimentally a novel technique for characterizing transverse spatial coherence by using the Wigner distribution function. The method is based on the measurement of interference between a pair of rotated and displaced replicas of the input beam with an area-integrating detector, and it provides an optimal signal-to-noise ratio in regimes when array detectors are not available. We analyze the quantum-optical picture of the presented measurement for single-photon signals and discuss possible applications in quantum information processing. 相似文献