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951.
Mathurin Grogna Rudi Cloots André Luxen Christine Jérôme Catherine Passirani Nolwenn Lautram Jean‐F. Desreux Christophe Detrembleur 《Journal of polymer science. Part A, Polymer chemistry》2011,49(17):3700-3708
New hydrosoluble magnetic resonance imaging (MRI) macrocontrast agents are synthesized by reversible addition fragmentation chain transfer (RAFT) copolymerization of poly(ethylene oxide) methyl ether acrylate (PEOMA) with an acrylamide bearing a ligand for gadolinium, followed by the complexation of Gd3+. This convenient and simple grafting through approach leads to macrocontrast agents with a high relaxivity at high frequency that is imparted by the restricted tumbling of the Gd3+ complex caused by its attachment to the polymer backbone. Importantly a very low protein adsorption is also evidenced by the hemolytic CH50 test. It is the result of the poly(ethylene oxide) (PEO) brush that efficiently hides the gadolinium complex and renders it stealth to the proteins of the immune system. Improved contrast and long blood circulating properties are thus expected for these macrocontrast agents. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011 相似文献
952.
Evaluation of a combined glycomics and glycoproteomics approach for studying the major glycoproteins present in biofluids: Application to cerebrospinal fluid 下载免费PDF全文
953.
Maxime Charman Frédéric Léonardi Sébastien Dominguez Cédric Bissuel Christophe Derail 《Journal of Polymer Science.Polymer Physics》2011,49(22):1597-1604
The dispersion of multiwalled carbon nanotubes (CNTs) in an ethylene propylene rubber matrix was investigated using an internal mixer. Poly(ethylene‐co‐polyvinyl acetate) (EVA) statistic copolymer was used as a dispersing agent. The effects of the concentration of the dispersing agent and the matrix viscosity on the quality of the dispersion of 1 wt % of CNTs were studied by using microscopy and rheology in the melt state. It was demonstrated that the dispersion is governed principally by the viscosity of the matrix. As expected, better dispersion was observed when the matrix exhibited a lower viscosity. The influence of the filler content on the rheological and electrical properties is presented. A Cross model with a yield stress is proposed to describe the rheological behavior of these materials, which exhibit a viscoelastic solid behavior from 1 wt % CNT content. Electrical measurement data indicate that the electrical percolation threshold was 2.9 wt %. © 2011 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 49: 1597–1604, 2011 相似文献
954.
Comprehensive Two-dimensional Gas Chromatography for Analysis of the Volatile Compounds and Fishy Odor Off-flavors from Heated Rapeseed Oil 总被引:1,自引:0,他引:1
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Roland Coratger Bastien Calmettes Youness Benjalal Xavier Bouju Christophe Coudret 《Surface science》2012,606(3-4):444-449
The electronic and structural properties of large molecules composed of a central hexa-phenylbenzene core surrounded by six adamantyl groups (Ad6HPB) adsorbed on Ag(111) have been investigated using low temperature scanning tunneling microscopy (STM), adsorption and image calculations. On large 2D domains, the molecular organization displays two lattices. In one of them, molecules are slightly nested as a result of their relative flexibility during packing. These compounds also exhibit contrast variations in terms of used bias voltage in the self-assembled domains as well as in single molecule observations. This is attributed to the peculiar electronic properties of Ad6HPB and to the role of peripheral groups. 相似文献
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Romain Sallio Stéphane Lebrun Francine Agbossou-Niedercorn Christophe Michon Eric Deniau 《Tetrahedron: Asymmetry》2012,23(13):998-1004
Two alternative synthetic approaches to a variety of enantioenriched 6-arylated piperidin-2-ones have been developed. The first one is based on the hydrogenation of suitably arylated chiral cyclic enehydrazides. The second approach relies on the asymmetric catalytic hydrogenation of the corresponding N-alkylated precursors. 相似文献
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