首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   805篇
  免费   3篇
  国内免费   1篇
化学   546篇
力学   14篇
数学   103篇
物理学   146篇
  2024年   4篇
  2023年   13篇
  2022年   9篇
  2021年   26篇
  2020年   33篇
  2019年   29篇
  2018年   14篇
  2017年   14篇
  2016年   22篇
  2015年   29篇
  2014年   8篇
  2013年   33篇
  2012年   50篇
  2011年   56篇
  2010年   30篇
  2009年   40篇
  2008年   54篇
  2007年   56篇
  2006年   63篇
  2005年   35篇
  2004年   33篇
  2003年   24篇
  2002年   16篇
  2001年   15篇
  2000年   3篇
  1999年   6篇
  1998年   14篇
  1997年   4篇
  1996年   9篇
  1995年   6篇
  1994年   5篇
  1993年   9篇
  1992年   5篇
  1991年   11篇
  1988年   2篇
  1987年   1篇
  1985年   3篇
  1982年   1篇
  1981年   7篇
  1980年   6篇
  1979年   1篇
  1976年   1篇
  1974年   2篇
  1970年   1篇
  1966年   1篇
  1964年   1篇
  1962年   2篇
  1886年   1篇
  1879年   1篇
排序方式: 共有809条查询结果,搜索用时 15 毫秒
81.
    
Continuous flow systems for chemical synthesis are becoming a major focus in organic chemistry and there is a growing interest in the integration of biocatalysts due to their high regio- and stereoselectivity. Methods established for 3D bioprinting enable the fast and simple production of agarose-based modules for biocatalytic reactors if thermally stable enzymes are available. We report here on the characterization of four different cofactor-free phenacrylate decarboxylase enzymes suitable for the production of 4-vinylphenol and test their applicability for the encapsulation and direct 3D printing of disk-shaped agarose-based modules that can be used for compartmentalized flow microreactors. Using the most active and stable phenacrylate decarboxylase from Enterobacter spec. in a setup with four parallel reactors and a subsequent palladium(II) acetate-catalysed Heck reaction, 4-hydroxystilbene was synthesized from p-coumaric acid with a total yield of 14.7 % on a milligram scale. We believe that, due to the convenient direct immobilization of any thermostable enzyme and straightforward tuning of the reaction sequence by stacking of modules with different catalytic activities, this simple process will facilitate the establishment and use of cascade reactions and will therefore be of great advantage for many research approaches.  相似文献   
82.
83.
84.
    
  相似文献   
85.
    
Lars Kappertz  Christof Büskens 《PAMM》2023,22(1):e202200257
With the transition towards renewable energy underway, demand-side management together with the local generation of renewable energy is receiving growing attention. Optimizing the self-consumption of locally produced renewable energy can not only have financial benefits for the respective household or business (and improve their autarky from increasingly unstable energy markets), but also help improve grid stability against the volatility of some sources of renewable energy. In order to optimize the self-consumption of a given household or enterprise with an energy management system, the energy demand and generation, as well as the behaviour of all controlled devices have to be forecast. There are many different methods of mathematically modelling these different properties, but the task becomes especially challenging for dynamic systems like energy storage systems. Here, the state of charge at a specific time point depends on both external influences and the previous time point's state of charge, thus modelling errors quickly accumulate. In the context of small and medium agricultural enterprises, examples of such dynamic systems can be electrical storages, like a battery, or thermal storages like a milk cooling tank or a heat pump. In this work, a common way for the modelling of these systems is explored, namely parameter identification. Here, the parameters of an ordinary differential equation representing the assumed physical behaviour of the system are identified from measured data of states and controls in an optimization problem. The success of this approach, and with it the performance of the derived model depends on how well the physical equations actually describe the system, but also on the quality, quantity and content of the measurement data used. In the case of a household battery storage already a simple physical model with parameters identified from measurement data of state of charge and battery power provides useful results. The example of a milk cooling tank provides a situation where external forcing has an important influence on the system's state of charge, its temperature. The cleaning of the tank generates a large heat influx, and raises the temperature, while the filling and emptying of milk influences the heat capacity. While these influences are shown to also be representable by equations based on the physical processes, parameter identification becomes difficult when they are not included in the measurement data. Thus, different approaches to derive these external forcings from the available data are outlined.  相似文献   
86.
Localized period-doubling waves arise in circularly shaken granular beds contained in an annular channel. These solitary wave packets are accompanied by a locally increased particle density. The width and velocity of the granular wave pulse are measured as a function of the bed height. A continuum model for the material distribution, based on the measured granular transport velocity as a function of the bed thickness, captures the essence of the experimental findings.  相似文献   
87.
We consider a general class of disordered mean-field models where both the spin variables and disorder variables η take finitely many values. To investigate the size-dependence in the phase-transition regime we construct the metastate describing the probabilities to find a large system close to a particular convex combination of the pure infinite-volume states. We show that, under a non-degeneracy assumption, only pure states j are seen, with non-random probability weights w j for which we derive explicit expressions in terms of interactions and distributions of the disorder variables. We provide a geometric construction distinguishing invisible states (having w j =0) from visible ones. As a further consequence we show that, in the case where precisely two pure states are available, these must necessarily occur with the same weight, even if the model has no obvious symmetry relating the two.  相似文献   
88.
In crystal optics and quantum electrodynamics in gravitational vacua, the propagation of light is not described by a metric, but an area metric geometry. In this article, this prompts us to study conditions for linear electrodynamics on area metric manifolds to be well-posed. This includes an identification of the timelike future cones and their duals associated to an area metric geometry, and thus paves the ground for a discussion of the related local and global causal structures in standard fashion. In order to provide simple algebraic criteria for an area metric manifold to present a consistent spacetime structure, we develop a complete algebraic classification of area metric tensors up to general transformations of frame. This classification, valuable in its own right, is then employed to prove a theorem excluding the majority of algebraic classes of area metrics as viable spacetimes. Physically, these results classify and drastically restrict the viable constitutive tensors of non-dissipative linear optical media.  相似文献   
89.
Based on detailed theoretical analyses, we present, for the first time, direct evidence that the significant interface dipole commonly observed for atoms and molecules physisorbed on metal surfaces originates from exchangelike effects. In the case of Xe, previously proposed contributions from chemical interactions do not play a significant role.  相似文献   
90.
A high‐repetition‐rate pump–probe experiment is presented, based on the asynchronous sampling approach. The low‐α mode at the synchrotron ANKA can be used for a time resolution down to the picosecond limit for the time‐domain sampling of the coherent THz emission as well as for hard X‐ray pump–probe experiments, which probe structural dynamics in the condensed phase. It is shown that a synchronization of better than 1 ps is achieved, and examples of phonon dynamics of semiconductors are presented.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号