Visual measurements of droplet size in gas–liquid annular flow

Drop size distributions have been measured for nitrogen–water annular flow in a 9.67 mm hydraulic diameter duct, at system pressures of 3.4 and 17 bar and a temperature of 38 °C. These new data extend the range of conditions represented by existing data in the literature, primarily through an increase in system pressure. Since most existing correlations were developed from data obtained at lower pressures, it should be expected that the higher-pressure data presented in this paper would not necessarily follow those correlations. For two volume median correlations tested, one does not predict the new data very well, while the other only predicts those data taken at the lower pressure of 3.4 atm. An existing maximum drop size correlation predicts the current data to a reasonable approximation. Similarly, a related correlation for the Sauter mean diameter can predict the new data, provided the coefficient in the equation is adjusted.     

Stochastic non-linear flutter of a panel subjected to random in-plane forces

—An analysis of non-linear flutter of a simply-supported panel exposed to supersonic gas flow and random in-plane forces is presented for two- and three-mode interactions. A first order quasi-steady state aerodynamic piston theory is used to model the aerodynamic loading. The Fokker-Planck equation is used to derive a general moment equation for two- and three-mode interactions. For stability analysis the moment equation is consistent and the mean square stability boundaries of the equilibrium are obtained in terms of the system parameters. The stability boundaries reveal common features to those predicted by the deterministic theory of panel nutter. For the non-linear response the moment equation is found inconsistent and a cumulant-neglect closure is used by setting cumulants of fifth and sixth orders to zero. This first order non-Gaussian closure is carried out to solve for the response statistics in terms of the air-to-plate mass ratio, aerodynamic pressure, modal damping, and in-plane random force spectral density. It is found that the non-Gaussian solution yields higher levels for the response statistics than those obtained by the Gaussian solution. The inclusion of more modes results in a reduction of the response levels and expands the stability region.     

Forced Convection Heat Transfer on a Flat Plate Embedded in Porous Media for Power-Law Fluids

The effect of the presence of an isotropic solid matrix on the forced convection heat transfer rate from a flat plate to power-law non- Newtonian fluid-saturated porous medium, has been investigated. Numerical results are presented for the distribution of velocity and temperature profiles within the boundary layer. The effects of the flow index, first-order and second-order resistance on the velocity, and temperature profiles are discussed. The missing wall values of the velocity and thermal functions are tabulated.     

STUDIES ON THE INTERACTION OF EPOXY POLYMERS WITH HOMOPOLYUREAS

INTRODUCTION Epoxy resins are reactive polymers which when cured with a variety of chemicals lead to a host of useful thermosets. Since the epoxide is a strained ring, it readily undergoes addition and homopolymerization. The homopolymerization is a process catalysed by acids, bases, Lewis acids, t-amines as well as by inorganic salts.     

All-Solid-State PVC Membrane Ag+-Selective Electrodes Based on Diaza-18-Crown-6 Compounds

Two diaza-crown ether compounds were synthesized and evaluated as Ag⁺-selective carriers in polyvinylchloride (PVC) membrane electrodes of solid-state type. The all-solid-state PVC membrane electrode based on N,N-Dibenzyl-dibenzo-diaza-18-crown-6 exhibited a super-Nernstian response (75±10mV per decade) over the concentration range of 1×10^–1 to 7×10^–6M of Ag⁺ ion and a detection limit of 3×10^–6M, at a wide range of pH (pH 4–7). The response time of the electrode was fast (less than 10s), and it can be used for three months without any significant deviation in potential. The proposed all-solid-state PVC membrane electrodes revealed high selectivity toward Ag⁺ ion with respect to alkali, alkaline earth, heavy and transition metal ions. A flow-through cell of all-solid-state PVC membrane Ag⁺-selective electrode based on N,N-Dibenzyl-dibenzo-diaza-18-crown-6 has also been prepared and applied for flow-injection analysis of Ag⁺ ion in solution.     

Estimation of Lyapunov exponents from a time series for n-dimensional state space using nonlinear mapping

It has been demonstrated that when estimating Lyapunov exponents using a time series, nonlinear mapping used for characterizing the evolution of the neighbors leads to more accurate negative exponents and is more robust to noise in the times series. However, the number of unknown elements of the matrices associated with nonlinear mapping increases significantly with the embedding dimensions of the state space where the dynamics is reconstructed. Such unknown coefficients are solved from a set of linear algebraic equations based on the least square-root fit method. Derivation of such linear equations and computer programming are tedious and error prone especially for the systems with high embedding dimensions. In this work, we develop a general form of the linear algebraic equations and the corresponding computer program in terms of arbitrary embedding dimensions. A stable robotic system with all negative Lyapunov exponents and the Lorenz system with positive, zero, and negative exponents are used to demonstrate the efficacy of the proposed method. The work can contribute significantly to estimating Lyapunov exponents for systems with large embedding dimensions.     

Modeling a neutron-rich nuclei source

The deuteron break-up process in a suitable converter gives rise to intense neutron beams. A source of neutron-rich nuclei based on the neutron-induced fission can be realised using these beams. A theoretical optimization of such a facility as a function of the incident deuteron energy is reported. The model used to determine the fission products takes into account the excitation energy of the target nucleus and the evaporation of prompt neutrons. Results are presented in connection with a converter-target specific geometry. Received: 1 December 2000 / Accepted: 12 May 2001     

Mg-LDH Nanoclays Intercalated Fennel and Green Tea Active Ingredient: Field and Laboratory Evaluation of Insecticidal Activities against Culex pipiens and Their Non-Target Organisms

(1) Background: Mosquito control with essential oils is a growing demand. This work evaluated the novel larvicidal and adulticidal activity of fennel and green tea oils and their Layered double hydroxides (LDHs) nanohybrid against Culex pipiens (Cx. pipiens) in both laboratory and field conditions and evaluated their effect against non-target organisms; (2) Methods: Two types of nanoclays, MgAl-LDH and NiAl-LDH were synthesized and characterized using PXRD, TEM and SEM, whereas their elemental analysis was accomplished by SEM-EDX; (3) Results: Mg and Ni LDHs were synthesized by the co-precipitation method. The adsorption and desorption of active ingredients were conducted using LC MS/MS, with reference to the SEM-EXD analysis. The desorption process of MgAl-LDH intercalated green tea oil was conducted using ethanol, and reveled significant peaks related to polyphenols and flavonoids like Vanillin, Catechin, Daidzein, Ellagic acid, Naringenin, Myricetin and Syringic acid with concentrations of 0.76, 0.73, 0.67, 0.59, 0.52, 0.44 and 0.42 μg/g, respectively. The larvicidal LC₅₀ values of fennel oil, Mg-LDH-F, and Ni-LDH-F were 843.88, 451.95, 550.12 ppm, respectively, whereas the corresponding values of green tea were 938.93, 530.46, and 769.94 ppm. The larval reduction percentage of fennel oil and Mg-LDH-F reached 90.1 and 96.2%, 24 h PT and their persistence reached five and seven days PT, respectively. The reduction percentage of green tea oil and Mg-LDH-GT reached 88.00 and 92.01%, 24 h PT and their persistence reached five and six days PT, respectively. Against adults, Mg-LDH-GT and Ni-LDH-GT were less effective than green tea oil as their LC₉₅ values were 5.45, 25.90, and 35.39%, respectively. The reduction in adult density PT with fennel oil, Mg-LDH-F, green tea oil, and Mg-LDH-GT reached 83.1, 100, 77.0, and 99.0%, respectively, 24 h PT and were effective for three days. Mg-LDH-GT and Mg-LDH-F increased the predation Cybister tripunctatus (71% and 69%), respectively; (4) Conclusions: For the first time, Mg-LDH-GT and Mg-LDH-F was the best system loaded with relatively good desorption release to its active ingredients and significantly affected Cx. pipiens larvae and adults in both laboratory and field circumstances, and it could be included in mosquito control.     

Investigation of the Mechanism of Colloidal Silicalite‐1 Crystallization by Using DLS,SAXS, and 29Si NMR Spectroscopy

Colloidal silicalite‐1 zeolite was crystallized from a concentrated clear sol prepared from tetraethylorthosilicate (TEOS) and aqueous tetrapropylammonium hydroxide (TPAOH) solution at 95 °C. The silicate speciation was monitored by using dynamic light scattering (DLS), synchrotron small‐angle X‐ray scattering (SAXS), and quantitative liquid‐state ²⁹Si NMR spectroscopy. The silicon atoms were present in dissolved oligomers, two discrete nanoparticle populations approximately 2 and 6 nm in size, and crystals. On the basis of new insight into the evolution of the different nanoparticle populations and of the silicate connectivity in the nanoparticles, a refined crystallization mechanism was derived. Upon combining the reagents, different types of nanoparticles (ca. 2 nm) are formed. A fraction of these nanoparticles with the least condensed silicate structure does not participate in the crystallization process. After completion of the crystallization, they represent the residual silicon atoms. Nanoparticles with a more condensed silicate network grow until approximately 6 nm and evolve into building blocks for nucleation and growth of the silicalite‐1 crystals. The silicate network connectivity of nanoparticles suitable for nucleation and growth increasingly resembles that of the final zeolite. This new insight into the two classes of nanoparticles will be useful to tune the syntheses of silicalite‐1 for maximum yield.     

Synthesis and reactions of 3-thioxo[1,2,4]-triazino[3,2-b]quinazolin-10-ones

Thiation of [1,2,4]triazino[3,2-b]quinazoline-3,10-dione 1 proceeds selectively to give the 3-thioxo-analog 3 . The latter was converted to the corresponding 3-methylthio derivative 4 which was reacted with aniline and hydrazine to give the corresponding anilino- and hydrazino derivatives 5 and 7 . Compound 7 was converted to the hydrazones 8a,b and into the novel heterocyclic ring systems [1,2,4]triazolo[4′,3′:4,5][1,2,4]triazino-[3,2-b]quinazolin-7-ones 9, 10a,b and tetrazolo[1′,5′:4,5][1,2,4]triazino[3,2-b]quinazolin-7-one 11 .